Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Production
Described are new solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production. These were prepared by substituting Fe3+ ions substitute for a fraction of the Al3+ ions in the Mg/Al layered double hydroxide lattices of hydrota...
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| Veröffentlicht in: | Catalysis letters 2008-05, Vol.122 (3-4), p.205-209 |
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| creator | Macala, Gerald S. Robertson, Andrew W. Johnson, Charles L. Day, Zachary B. Lewis, Robert S. White, Mark G. Iretskii, Alexei V. Ford, Peter C. |
| description | Described are new solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production. These were prepared by substituting Fe3+ ions substitute for a fraction of the Al3+ ions in the Mg/Al layered double hydroxide lattices of hydrotalcites (HTC) and calcining to give porous metal oxides (PMOs). These iron-doped PMOs are much stronger bases than those derived from undoped or Ga3+ doped HTCs and are effective catalysts for the methanol transesterification of triacetin (glycerol triacetate) and of soybean oil.
Graphical Abstract
New solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production, were prepared by substituting Fe
3+
for Al
3+
cations in hydrotalcite (HTC) structures and calcining to give porous metal oxides. |
| doi_str_mv | 10.1007/s10562-008-9480-y |
| format | Article |
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Graphical Abstract
New solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production, were prepared by substituting Fe
3+
for Al
3+
cations in hydrotalcite (HTC) structures and calcining to give porous metal oxides.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-008-9480-y</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Aluminum ; Biodiesel fuels ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Esters ; Exact sciences and technology ; Fatty acids ; Ferric ions ; General and physical chemistry ; Industrial Chemistry/Chemical Engineering ; Iron ; Lattices ; Magnesium ; Metal oxides ; Organometallic Chemistry ; Physical Chemistry ; Roasting ; Soybean oil ; Soybeans ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Transesterification ; Triacetin ; Triglycerides</subject><ispartof>Catalysis letters, 2008-05, Vol.122 (3-4), p.205-209</ispartof><rights>Springer Science+Business Media, LLC 2008</rights><rights>2008 INIST-CNRS</rights><rights>Catalysis Letters is a copyright of Springer, (2008). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c412t-b6857369c37f9242a7fbc466bfb845943e7753af358a246ee3d3e064e3a42c833</citedby><cites>FETCH-LOGICAL-c412t-b6857369c37f9242a7fbc466bfb845943e7753af358a246ee3d3e064e3a42c833</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-008-9480-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-008-9480-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20365754$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Macala, Gerald S.</creatorcontrib><creatorcontrib>Robertson, Andrew W.</creatorcontrib><creatorcontrib>Johnson, Charles L.</creatorcontrib><creatorcontrib>Day, Zachary B.</creatorcontrib><creatorcontrib>Lewis, Robert S.</creatorcontrib><creatorcontrib>White, Mark G.</creatorcontrib><creatorcontrib>Iretskii, Alexei V.</creatorcontrib><creatorcontrib>Ford, Peter C.</creatorcontrib><title>Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Production</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Described are new solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production. These were prepared by substituting Fe3+ ions substitute for a fraction of the Al3+ ions in the Mg/Al layered double hydroxide lattices of hydrotalcites (HTC) and calcining to give porous metal oxides (PMOs). These iron-doped PMOs are much stronger bases than those derived from undoped or Ga3+ doped HTCs and are effective catalysts for the methanol transesterification of triacetin (glycerol triacetate) and of soybean oil.
Graphical Abstract
New solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production, were prepared by substituting Fe
3+
for Al
3+
cations in hydrotalcite (HTC) structures and calcining to give porous metal oxides.</description><subject>Aluminum</subject><subject>Biodiesel fuels</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Esters</subject><subject>Exact sciences and technology</subject><subject>Fatty acids</subject><subject>Ferric ions</subject><subject>General and physical chemistry</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Iron</subject><subject>Lattices</subject><subject>Magnesium</subject><subject>Metal oxides</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Roasting</subject><subject>Soybean oil</subject><subject>Soybeans</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Transesterification</subject><subject>Triacetin</subject><subject>Triglycerides</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kMtKAzEUhgdRsFYfwF1AXEZznUzcab20UFCwQnchk0kkddrUZLqYtzdliq5c5ZDzny85X1FcYnSDERK3CSNeEohQBSWrEOyPihHmgsBKyOVxrhHGkAqyPC3OUlohhKTAclRsF1Fvkk2djd55ozsfNmCiO932qUvAxbAGs5jvHsPWNmDaNzHkpvGdha3_suAtWrOLKcR0B95D6xvwoDMPuBDBgw-Nt8m2ORWandnDz4sTp9tkLw7nuPh4flpMpnD--jKb3M-hYZh0sC4rLmgpDRVOEka0cLVhZVm7umJcMmqF4FQ7yitNWGktbahFJbNUM2IqSsfF1cDdxvC9ywuqVdjFTX5SEcIryZDELKfwkDIxpBStU9vo1zr2CiO1F6sGsSqLVXuxqs8z1weyTka3Lgs0Pv0OEkRLLvieTYZcyq3Np41_P_gf_gN7Q4oj</recordid><startdate>20080501</startdate><enddate>20080501</enddate><creator>Macala, Gerald S.</creator><creator>Robertson, Andrew W.</creator><creator>Johnson, Charles L.</creator><creator>Day, Zachary B.</creator><creator>Lewis, Robert S.</creator><creator>White, Mark G.</creator><creator>Iretskii, Alexei V.</creator><creator>Ford, Peter C.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20080501</creationdate><title>Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Production</title><author>Macala, Gerald S. ; Robertson, Andrew W. ; Johnson, Charles L. ; Day, Zachary B. ; Lewis, Robert S. ; White, Mark G. ; Iretskii, Alexei V. ; Ford, Peter C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c412t-b6857369c37f9242a7fbc466bfb845943e7753af358a246ee3d3e064e3a42c833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Aluminum</topic><topic>Biodiesel fuels</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Esters</topic><topic>Exact sciences and technology</topic><topic>Fatty acids</topic><topic>Ferric ions</topic><topic>General and physical chemistry</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Iron</topic><topic>Lattices</topic><topic>Magnesium</topic><topic>Metal oxides</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Roasting</topic><topic>Soybean oil</topic><topic>Soybeans</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Transesterification</topic><topic>Triacetin</topic><topic>Triglycerides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Macala, Gerald S.</creatorcontrib><creatorcontrib>Robertson, Andrew W.</creatorcontrib><creatorcontrib>Johnson, Charles L.</creatorcontrib><creatorcontrib>Day, Zachary B.</creatorcontrib><creatorcontrib>Lewis, Robert S.</creatorcontrib><creatorcontrib>White, Mark G.</creatorcontrib><creatorcontrib>Iretskii, Alexei V.</creatorcontrib><creatorcontrib>Ford, Peter C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Macala, Gerald S.</au><au>Robertson, Andrew W.</au><au>Johnson, Charles L.</au><au>Day, Zachary B.</au><au>Lewis, Robert S.</au><au>White, Mark G.</au><au>Iretskii, Alexei V.</au><au>Ford, Peter C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Production</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2008-05-01</date><risdate>2008</risdate><volume>122</volume><issue>3-4</issue><spage>205</spage><epage>209</epage><pages>205-209</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Described are new solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production. These were prepared by substituting Fe3+ ions substitute for a fraction of the Al3+ ions in the Mg/Al layered double hydroxide lattices of hydrotalcites (HTC) and calcining to give porous metal oxides (PMOs). These iron-doped PMOs are much stronger bases than those derived from undoped or Ga3+ doped HTCs and are effective catalysts for the methanol transesterification of triacetin (glycerol triacetate) and of soybean oil.
Graphical Abstract
New solid base catalysts for transesterification of seed oil triglycerides to fatty acid methyl esters, a key step in biodiesel production, were prepared by substituting Fe
3+
for Al
3+
cations in hydrotalcite (HTC) structures and calcining to give porous metal oxides.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10562-008-9480-y</doi><tpages>5</tpages></addata></record> |
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| subjects | Aluminum Biodiesel fuels Catalysis Catalysts Chemistry Chemistry and Materials Science Esters Exact sciences and technology Fatty acids Ferric ions General and physical chemistry Industrial Chemistry/Chemical Engineering Iron Lattices Magnesium Metal oxides Organometallic Chemistry Physical Chemistry Roasting Soybean oil Soybeans Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Transesterification Triacetin Triglycerides |
| title | Transesterification Catalysts from Iron Doped Hydrotalcite-like Precursors: Solid Bases for Biodiesel Production |
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