Conversion of Guaiacol over Supported Ru Catalysts
The vapor phase conversion of guaiacol over Ru catalysts supported on C, SiO 2 , Al 2 O 3 , and TiO 2 at 400 °C in flowing atmospheric hydrogen is reported. Results indicate a strong synergy between Ru and TiO 2 when compared with other catalysts studied as evidenced by enhanced activity for deoxyge...
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| Veröffentlicht in: | Catalysis letters 2013-08, Vol.143 (8), p.783-791 |
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| creator | Boonyasuwat, Sunya Omotoso, Taiwo Resasco, Daniel E. Crossley, Steven P. |
| description | The vapor phase conversion of guaiacol over Ru catalysts supported on C, SiO
2
, Al
2
O
3
, and TiO
2
at 400 °C in flowing atmospheric hydrogen is reported. Results indicate a strong synergy between Ru and TiO
2
when compared with other catalysts studied as evidenced by enhanced activity for deoxygenation, transalkylation, and decreased deactivation rates. These results are attributed to the enhanced activity of the support brought about by the ability of Ru to reduce TiO
2
and create highly active sites for the conversion of guaiacol.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-013-1033-3 |
| format | Article |
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2
, Al
2
O
3
, and TiO
2
at 400 °C in flowing atmospheric hydrogen is reported. Results indicate a strong synergy between Ru and TiO
2
when compared with other catalysts studied as evidenced by enhanced activity for deoxygenation, transalkylation, and decreased deactivation rates. These results are attributed to the enhanced activity of the support brought about by the ability of Ru to reduce TiO
2
and create highly active sites for the conversion of guaiacol.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-013-1033-3</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Aluminum oxide ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Conversion ; Deactivation ; Deoxygenation ; Exact sciences and technology ; General and physical chemistry ; Industrial Chemistry/Chemical Engineering ; Organometallic Chemistry ; Phenols ; Physical Chemistry ; Production processes ; Pyrolysis ; Silicon dioxide ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Titanium dioxide ; Transalkylation ; Vapor phases</subject><ispartof>Catalysis letters, 2013-08, Vol.143 (8), p.783-791</ispartof><rights>Springer Science+Business Media New York 2013</rights><rights>2014 INIST-CNRS</rights><rights>COPYRIGHT 2013 Springer</rights><rights>Catalysis Letters is a copyright of Springer, (2013). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c555t-4351702b332b4b04866f89d56378bb13c410d9e1cf0bdcd12ac026fb8fc700dd3</citedby><cites>FETCH-LOGICAL-c555t-4351702b332b4b04866f89d56378bb13c410d9e1cf0bdcd12ac026fb8fc700dd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-013-1033-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-013-1033-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27583660$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Boonyasuwat, Sunya</creatorcontrib><creatorcontrib>Omotoso, Taiwo</creatorcontrib><creatorcontrib>Resasco, Daniel E.</creatorcontrib><creatorcontrib>Crossley, Steven P.</creatorcontrib><title>Conversion of Guaiacol over Supported Ru Catalysts</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>The vapor phase conversion of guaiacol over Ru catalysts supported on C, SiO
2
, Al
2
O
3
, and TiO
2
at 400 °C in flowing atmospheric hydrogen is reported. Results indicate a strong synergy between Ru and TiO
2
when compared with other catalysts studied as evidenced by enhanced activity for deoxygenation, transalkylation, and decreased deactivation rates. These results are attributed to the enhanced activity of the support brought about by the ability of Ru to reduce TiO
2
and create highly active sites for the conversion of guaiacol.
Graphical Abstract</description><subject>Aluminum oxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Conversion</subject><subject>Deactivation</subject><subject>Deoxygenation</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Organometallic Chemistry</subject><subject>Phenols</subject><subject>Physical Chemistry</subject><subject>Production processes</subject><subject>Pyrolysis</subject><subject>Silicon dioxide</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Titanium dioxide</subject><subject>Transalkylation</subject><subject>Vapor phases</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kFFLwzAUhYsoOKc_wLeC-OBD5k3SNO3jGDoHA2FT2FtI02R0dE1NWnH_3owOxQcJl4Sb75zcnCi6xTDBAPzRY2ApQYApwkApomfRCDNOUMbzzXk4A8aIcrK5jK683wFAznE-isjMNp_a-co2sTXxvJeVVLaObWjG675tret0Ga_6eCY7WR9856-jCyNrr29O-zh6f356m72g5et8MZsukWKMdSihDHMgBaWkSApIsjQ1WV6ylPKsKDBVCYYy11gZKEpVYiIVkNQUmVEcoCzpOLobfFtnP3rtO7GzvWvCk4IQluWhkjxQk4HaylqLqjG2c1KFVep9pWyjTRX6U5okHBKWQRA8_BEEptNf3Vb23ovFevWXxQOrnPXeaSNaV-2lOwgM4pi7GHIXIXdxzF3QoLk_jS29krVxslGV_xESzjKapkdvMnA-XDVb7X6_97_5N6asj2g</recordid><startdate>20130801</startdate><enddate>20130801</enddate><creator>Boonyasuwat, Sunya</creator><creator>Omotoso, Taiwo</creator><creator>Resasco, Daniel E.</creator><creator>Crossley, Steven P.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20130801</creationdate><title>Conversion of Guaiacol over Supported Ru Catalysts</title><author>Boonyasuwat, Sunya ; Omotoso, Taiwo ; Resasco, Daniel E. ; Crossley, Steven P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c555t-4351702b332b4b04866f89d56378bb13c410d9e1cf0bdcd12ac026fb8fc700dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Aluminum oxide</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Conversion</topic><topic>Deactivation</topic><topic>Deoxygenation</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Organometallic Chemistry</topic><topic>Phenols</topic><topic>Physical Chemistry</topic><topic>Production processes</topic><topic>Pyrolysis</topic><topic>Silicon dioxide</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Titanium dioxide</topic><topic>Transalkylation</topic><topic>Vapor phases</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Boonyasuwat, Sunya</creatorcontrib><creatorcontrib>Omotoso, Taiwo</creatorcontrib><creatorcontrib>Resasco, Daniel E.</creatorcontrib><creatorcontrib>Crossley, Steven P.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Boonyasuwat, Sunya</au><au>Omotoso, Taiwo</au><au>Resasco, Daniel E.</au><au>Crossley, Steven P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Conversion of Guaiacol over Supported Ru Catalysts</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2013-08-01</date><risdate>2013</risdate><volume>143</volume><issue>8</issue><spage>783</spage><epage>791</epage><pages>783-791</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>The vapor phase conversion of guaiacol over Ru catalysts supported on C, SiO
2
, Al
2
O
3
, and TiO
2
at 400 °C in flowing atmospheric hydrogen is reported. Results indicate a strong synergy between Ru and TiO
2
when compared with other catalysts studied as evidenced by enhanced activity for deoxygenation, transalkylation, and decreased deactivation rates. These results are attributed to the enhanced activity of the support brought about by the ability of Ru to reduce TiO
2
and create highly active sites for the conversion of guaiacol.
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| ispartof | Catalysis letters, 2013-08, Vol.143 (8), p.783-791 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2258925849 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Aluminum oxide Catalysis Catalysts Chemistry Chemistry and Materials Science Conversion Deactivation Deoxygenation Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering Organometallic Chemistry Phenols Physical Chemistry Production processes Pyrolysis Silicon dioxide Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Titanium dioxide Transalkylation Vapor phases |
| title | Conversion of Guaiacol over Supported Ru Catalysts |
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