AC3B Technology for Direct Liquefaction of Lignocellulosic Biomass: New Concepts of Coupling and Decoupling of Catalytic/Chemical Reactions for Obtaining a Very High Overall Performance
The acid-catalyzed conversion of lignocellulosic biomass (AC3B) process has been developed for the direct liquefaction of lignocellulosic biomass. In the original version, the main products, ethyl esters, are produced in acidic medium containing ethanol, using a one-pot conversion system. Our resear...
Gespeichert in:
| Veröffentlicht in: | Catalysis letters 2012-06, Vol.142 (6), p.667-675 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 675 |
|---|---|
| container_issue | 6 |
| container_start_page | 667 |
| container_title | Catalysis letters |
| container_volume | 142 |
| creator | Le Van Mao, R. Muntasar, A. Petraccone, D. Yan, H. T. |
| description | The acid-catalyzed conversion of lignocellulosic biomass (AC3B) process has been developed for the direct liquefaction of lignocellulosic biomass. In the original version, the main products, ethyl esters, are produced in acidic medium containing ethanol, using a one-pot conversion system. Our research strategy for obtaining a high overall performance is based on two general concepts: (a) coupling of catalytic/chemical reactions that lead to desired products and (b) decoupling of reactions that produce unwanted products, by decreasing the effectiveness of these reactions. Concept (a) is realized by using oxidizers (hydrogen peroxide and Fenton’s reagent) that promote a higher production of carboxylic acids as main intermediates, while concept (b) contributes to a significant decrease of undesired formation of polymeric products. As result of these reaction coupling and decoupling, the overall yield of liquid products has been multiplied by a factor of 2.5 (from 27 to over 70 wt%). Not only the yields of products from cellulose and hemicellulose components experience considerable increases, but also the lignin component starts undergoing a noticeable conversion. Essentially, the AC3B process, in the most recent version, consumes ethanol that is partly used to produce liquid fuels and chemicals from lignocellulosic biomass. The other amount of feed ethanol is converted—via diethyl ether and over ZSM-5-based catalysts—into aromatics-rich gasoline and liquefied petroleum gas—grade hydrocarbons.
Graphical Abstract
Sequence of actions that have significantly improved the total product yield (RP): AC = acidic medium, HP = addition of hydrogen peroxide, DL-st = use of a delignification step, FR = use of a Fenton-type reagent, PIn = use of a polymerization inhibitor |
| doi_str_mv | 10.1007/s10562-012-0825-1 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2258925551</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A356808908</galeid><sourcerecordid>A356808908</sourcerecordid><originalsourceid>FETCH-LOGICAL-c484t-463224426a2ca33fd127693a49d29809368e3db8cd55a90d33df3eab822770d73</originalsourceid><addsrcrecordid>eNp1kt1uFCEUxydGE2v1AbwjMV54MS0fwwDebadqm2xcU6vpHWEZZpaGhRVYdR_Nt5PpVptNNITA4fzOOXD4V9VLBE8QhOw0IUhbXENUJse0Ro-qI0QZrjkTN4_LHiJUE4ZvnlbPUrqFEAqGxFH1a9aRM3Bt9MoHF8YdGEIE5zYancHcftuaQelsgwdhKPbogzbObV1IVoMzG9Yqpbfgo_kBuuC12eQ0gV3Ybpz1I1C-B-dG_zEnl8rK7bLVp93KrK1WDlyZfYl0V3uxzMr6u2Dw1cQduLDjCiy-m6icA59MLNBalVrPqyeDcsm8uF-Pqy_v3113F_V88eGym81r3fAm101LMG4a3CqsFSFDjzBrBVGN6LHgUJCWG9Ivue4pVQL2hPQDMWrJMWYM9owcV6_2eTcxlH6kLG_DNvpSUmJMucCUUvRAjcoZaf0QclR6bZOWM0JbDrmAvFAn_6DK6KdeBG8GW84PAt4cBBQmm595VNuU5OXnq0MW7VkdQ0rRDHIT7VrFnURQTiKRe5HIIhI5iURO1359_ziVyl8MsXTWpr-BmArWUAYLh_dcKi4_mvjQhP8n_w0OcMtL</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2258925551</pqid></control><display><type>article</type><title>AC3B Technology for Direct Liquefaction of Lignocellulosic Biomass: New Concepts of Coupling and Decoupling of Catalytic/Chemical Reactions for Obtaining a Very High Overall Performance</title><source>SpringerNature Journals</source><creator>Le Van Mao, R. ; Muntasar, A. ; Petraccone, D. ; Yan, H. T.</creator><creatorcontrib>Le Van Mao, R. ; Muntasar, A. ; Petraccone, D. ; Yan, H. T.</creatorcontrib><description>The acid-catalyzed conversion of lignocellulosic biomass (AC3B) process has been developed for the direct liquefaction of lignocellulosic biomass. In the original version, the main products, ethyl esters, are produced in acidic medium containing ethanol, using a one-pot conversion system. Our research strategy for obtaining a high overall performance is based on two general concepts: (a) coupling of catalytic/chemical reactions that lead to desired products and (b) decoupling of reactions that produce unwanted products, by decreasing the effectiveness of these reactions. Concept (a) is realized by using oxidizers (hydrogen peroxide and Fenton’s reagent) that promote a higher production of carboxylic acids as main intermediates, while concept (b) contributes to a significant decrease of undesired formation of polymeric products. As result of these reaction coupling and decoupling, the overall yield of liquid products has been multiplied by a factor of 2.5 (from 27 to over 70 wt%). Not only the yields of products from cellulose and hemicellulose components experience considerable increases, but also the lignin component starts undergoing a noticeable conversion. Essentially, the AC3B process, in the most recent version, consumes ethanol that is partly used to produce liquid fuels and chemicals from lignocellulosic biomass. The other amount of feed ethanol is converted—via diethyl ether and over ZSM-5-based catalysts—into aromatics-rich gasoline and liquefied petroleum gas—grade hydrocarbons.
Graphical Abstract
Sequence of actions that have significantly improved the total product yield (RP): AC = acidic medium, HP = addition of hydrogen peroxide, DL-st = use of a delignification step, FR = use of a Fenton-type reagent, PIn = use of a polymerization inhibitor</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-012-0825-1</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Biomass ; Biomass energy ; Carboxylic acids ; Catalysis ; Cellulose ; Chemical industry ; Chemical reactions ; Chemical tests and reagents ; Chemistry ; Chemistry and Materials Science ; Conversion ; Coupling ; Decoupling ; Diethyl ether ; Esters ; Ethanol ; Ethyl esters ; Exact sciences and technology ; Gasoline ; General and physical chemistry ; Hydrogen peroxide ; Industrial Chemistry/Chemical Engineering ; Ion-exchange ; Lignin ; Lignocellulose ; Liquefaction ; Liquefied petroleum gas ; Liquid fuels ; Organic acids ; Organic chemistry ; Organometallic Chemistry ; Oxidizing agents ; Physical Chemistry ; Reagents ; Surface physical chemistry ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Zeolites: preparations and properties</subject><ispartof>Catalysis letters, 2012-06, Vol.142 (6), p.667-675</ispartof><rights>Springer Science+Business Media, LLC 2012</rights><rights>2015 INIST-CNRS</rights><rights>COPYRIGHT 2012 Springer</rights><rights>Catalysis Letters is a copyright of Springer, (2012). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c484t-463224426a2ca33fd127693a49d29809368e3db8cd55a90d33df3eab822770d73</citedby><cites>FETCH-LOGICAL-c484t-463224426a2ca33fd127693a49d29809368e3db8cd55a90d33df3eab822770d73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-012-0825-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-012-0825-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,41495,42564,51326</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25974570$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Le Van Mao, R.</creatorcontrib><creatorcontrib>Muntasar, A.</creatorcontrib><creatorcontrib>Petraccone, D.</creatorcontrib><creatorcontrib>Yan, H. T.</creatorcontrib><title>AC3B Technology for Direct Liquefaction of Lignocellulosic Biomass: New Concepts of Coupling and Decoupling of Catalytic/Chemical Reactions for Obtaining a Very High Overall Performance</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>The acid-catalyzed conversion of lignocellulosic biomass (AC3B) process has been developed for the direct liquefaction of lignocellulosic biomass. In the original version, the main products, ethyl esters, are produced in acidic medium containing ethanol, using a one-pot conversion system. Our research strategy for obtaining a high overall performance is based on two general concepts: (a) coupling of catalytic/chemical reactions that lead to desired products and (b) decoupling of reactions that produce unwanted products, by decreasing the effectiveness of these reactions. Concept (a) is realized by using oxidizers (hydrogen peroxide and Fenton’s reagent) that promote a higher production of carboxylic acids as main intermediates, while concept (b) contributes to a significant decrease of undesired formation of polymeric products. As result of these reaction coupling and decoupling, the overall yield of liquid products has been multiplied by a factor of 2.5 (from 27 to over 70 wt%). Not only the yields of products from cellulose and hemicellulose components experience considerable increases, but also the lignin component starts undergoing a noticeable conversion. Essentially, the AC3B process, in the most recent version, consumes ethanol that is partly used to produce liquid fuels and chemicals from lignocellulosic biomass. The other amount of feed ethanol is converted—via diethyl ether and over ZSM-5-based catalysts—into aromatics-rich gasoline and liquefied petroleum gas—grade hydrocarbons.
Graphical Abstract
Sequence of actions that have significantly improved the total product yield (RP): AC = acidic medium, HP = addition of hydrogen peroxide, DL-st = use of a delignification step, FR = use of a Fenton-type reagent, PIn = use of a polymerization inhibitor</description><subject>Biomass</subject><subject>Biomass energy</subject><subject>Carboxylic acids</subject><subject>Catalysis</subject><subject>Cellulose</subject><subject>Chemical industry</subject><subject>Chemical reactions</subject><subject>Chemical tests and reagents</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Conversion</subject><subject>Coupling</subject><subject>Decoupling</subject><subject>Diethyl ether</subject><subject>Esters</subject><subject>Ethanol</subject><subject>Ethyl esters</subject><subject>Exact sciences and technology</subject><subject>Gasoline</subject><subject>General and physical chemistry</subject><subject>Hydrogen peroxide</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ion-exchange</subject><subject>Lignin</subject><subject>Lignocellulose</subject><subject>Liquefaction</subject><subject>Liquefied petroleum gas</subject><subject>Liquid fuels</subject><subject>Organic acids</subject><subject>Organic chemistry</subject><subject>Organometallic Chemistry</subject><subject>Oxidizing agents</subject><subject>Physical Chemistry</subject><subject>Reagents</subject><subject>Surface physical chemistry</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Zeolites: preparations and properties</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kt1uFCEUxydGE2v1AbwjMV54MS0fwwDebadqm2xcU6vpHWEZZpaGhRVYdR_Nt5PpVptNNITA4fzOOXD4V9VLBE8QhOw0IUhbXENUJse0Ro-qI0QZrjkTN4_LHiJUE4ZvnlbPUrqFEAqGxFH1a9aRM3Bt9MoHF8YdGEIE5zYancHcftuaQelsgwdhKPbogzbObV1IVoMzG9Yqpbfgo_kBuuC12eQ0gV3Ybpz1I1C-B-dG_zEnl8rK7bLVp93KrK1WDlyZfYl0V3uxzMr6u2Dw1cQduLDjCiy-m6icA59MLNBalVrPqyeDcsm8uF-Pqy_v3113F_V88eGym81r3fAm101LMG4a3CqsFSFDjzBrBVGN6LHgUJCWG9Ivue4pVQL2hPQDMWrJMWYM9owcV6_2eTcxlH6kLG_DNvpSUmJMucCUUvRAjcoZaf0QclR6bZOWM0JbDrmAvFAn_6DK6KdeBG8GW84PAt4cBBQmm595VNuU5OXnq0MW7VkdQ0rRDHIT7VrFnURQTiKRe5HIIhI5iURO1359_ziVyl8MsXTWpr-BmArWUAYLh_dcKi4_mvjQhP8n_w0OcMtL</recordid><startdate>20120601</startdate><enddate>20120601</enddate><creator>Le Van Mao, R.</creator><creator>Muntasar, A.</creator><creator>Petraccone, D.</creator><creator>Yan, H. T.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20120601</creationdate><title>AC3B Technology for Direct Liquefaction of Lignocellulosic Biomass: New Concepts of Coupling and Decoupling of Catalytic/Chemical Reactions for Obtaining a Very High Overall Performance</title><author>Le Van Mao, R. ; Muntasar, A. ; Petraccone, D. ; Yan, H. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c484t-463224426a2ca33fd127693a49d29809368e3db8cd55a90d33df3eab822770d73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Biomass</topic><topic>Biomass energy</topic><topic>Carboxylic acids</topic><topic>Catalysis</topic><topic>Cellulose</topic><topic>Chemical industry</topic><topic>Chemical reactions</topic><topic>Chemical tests and reagents</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Conversion</topic><topic>Coupling</topic><topic>Decoupling</topic><topic>Diethyl ether</topic><topic>Esters</topic><topic>Ethanol</topic><topic>Ethyl esters</topic><topic>Exact sciences and technology</topic><topic>Gasoline</topic><topic>General and physical chemistry</topic><topic>Hydrogen peroxide</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ion-exchange</topic><topic>Lignin</topic><topic>Lignocellulose</topic><topic>Liquefaction</topic><topic>Liquefied petroleum gas</topic><topic>Liquid fuels</topic><topic>Organic acids</topic><topic>Organic chemistry</topic><topic>Organometallic Chemistry</topic><topic>Oxidizing agents</topic><topic>Physical Chemistry</topic><topic>Reagents</topic><topic>Surface physical chemistry</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Zeolites: preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Le Van Mao, R.</creatorcontrib><creatorcontrib>Muntasar, A.</creatorcontrib><creatorcontrib>Petraccone, D.</creatorcontrib><creatorcontrib>Yan, H. T.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Le Van Mao, R.</au><au>Muntasar, A.</au><au>Petraccone, D.</au><au>Yan, H. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>AC3B Technology for Direct Liquefaction of Lignocellulosic Biomass: New Concepts of Coupling and Decoupling of Catalytic/Chemical Reactions for Obtaining a Very High Overall Performance</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2012-06-01</date><risdate>2012</risdate><volume>142</volume><issue>6</issue><spage>667</spage><epage>675</epage><pages>667-675</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>The acid-catalyzed conversion of lignocellulosic biomass (AC3B) process has been developed for the direct liquefaction of lignocellulosic biomass. In the original version, the main products, ethyl esters, are produced in acidic medium containing ethanol, using a one-pot conversion system. Our research strategy for obtaining a high overall performance is based on two general concepts: (a) coupling of catalytic/chemical reactions that lead to desired products and (b) decoupling of reactions that produce unwanted products, by decreasing the effectiveness of these reactions. Concept (a) is realized by using oxidizers (hydrogen peroxide and Fenton’s reagent) that promote a higher production of carboxylic acids as main intermediates, while concept (b) contributes to a significant decrease of undesired formation of polymeric products. As result of these reaction coupling and decoupling, the overall yield of liquid products has been multiplied by a factor of 2.5 (from 27 to over 70 wt%). Not only the yields of products from cellulose and hemicellulose components experience considerable increases, but also the lignin component starts undergoing a noticeable conversion. Essentially, the AC3B process, in the most recent version, consumes ethanol that is partly used to produce liquid fuels and chemicals from lignocellulosic biomass. The other amount of feed ethanol is converted—via diethyl ether and over ZSM-5-based catalysts—into aromatics-rich gasoline and liquefied petroleum gas—grade hydrocarbons.
Graphical Abstract
Sequence of actions that have significantly improved the total product yield (RP): AC = acidic medium, HP = addition of hydrogen peroxide, DL-st = use of a delignification step, FR = use of a Fenton-type reagent, PIn = use of a polymerization inhibitor</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10562-012-0825-1</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2012-06, Vol.142 (6), p.667-675 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2258925551 |
| source | SpringerNature Journals |
| subjects | Biomass Biomass energy Carboxylic acids Catalysis Cellulose Chemical industry Chemical reactions Chemical tests and reagents Chemistry Chemistry and Materials Science Conversion Coupling Decoupling Diethyl ether Esters Ethanol Ethyl esters Exact sciences and technology Gasoline General and physical chemistry Hydrogen peroxide Industrial Chemistry/Chemical Engineering Ion-exchange Lignin Lignocellulose Liquefaction Liquefied petroleum gas Liquid fuels Organic acids Organic chemistry Organometallic Chemistry Oxidizing agents Physical Chemistry Reagents Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Zeolites: preparations and properties |
| title | AC3B Technology for Direct Liquefaction of Lignocellulosic Biomass: New Concepts of Coupling and Decoupling of Catalytic/Chemical Reactions for Obtaining a Very High Overall Performance |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-05T00%3A40%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=AC3B%20Technology%20for%20Direct%20Liquefaction%20of%20Lignocellulosic%20Biomass:%20New%20Concepts%20of%20Coupling%20and%20Decoupling%20of%20Catalytic/Chemical%20Reactions%20for%20Obtaining%20a%20Very%20High%20Overall%20Performance&rft.jtitle=Catalysis%20letters&rft.au=Le%20Van%20Mao,%20R.&rft.date=2012-06-01&rft.volume=142&rft.issue=6&rft.spage=667&rft.epage=675&rft.pages=667-675&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-012-0825-1&rft_dat=%3Cgale_proqu%3EA356808908%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2258925551&rft_id=info:pmid/&rft_galeid=A356808908&rfr_iscdi=true |