Molecular Understanding of Sorption in Mesoscale Organized Zeolites with MFI Structure
We report herein the adsorption of light hydrocarbons in small crystal ZSM-5 monitored by infrared spectroscopy including a direct monitoring of the individual concentrations (surface and intracrystalline). Accessing the individual rates reveals that the sorption enhancement upon surface modificatio...
Gespeichert in:
| Veröffentlicht in: | Catalysis letters 2013-11, Vol.143 (11), p.1116-1122 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1122 |
|---|---|
| container_issue | 11 |
| container_start_page | 1116 |
| container_title | Catalysis letters |
| container_volume | 143 |
| creator | Kolvenbach, Robin Gonzalez-Peňa, Luis Francisco Jentys, Andreas Lercher, Johannes A. |
| description | We report herein the adsorption of light hydrocarbons in small crystal ZSM-5 monitored by infrared spectroscopy including a direct monitoring of the individual concentrations (surface and intracrystalline). Accessing the individual rates reveals that the sorption enhancement upon surface modification with TEOS is selective towards molecules with a small steric demand and a high heat of adsorption within the silica overlayer.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-013-1118-z |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2258923306</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A352231963</galeid><sourcerecordid>A352231963</sourcerecordid><originalsourceid>FETCH-LOGICAL-c456t-c2806b659f7d491202eb5e93c5624b88bb61f795d0f8c5793e013144ac6cf1183</originalsourceid><addsrcrecordid>eNp1kU9rFTEUxQdRsFY_gLuAuHAxNX8myWRZitUHfRR8VoqbkMncjCnT5JlkUN-nN48pSheSRULyO_fek9M0rwk-IxjL95lgLmiLCWsJIX17eNKcEC5p20t1-7SeMSEtk_T2efMi5zuMsZJEnTRft3EGu8wmoZswQsrFhNGHCUWHdjHti48B-YC2kGO2ZgZ0nSYT_AFG9A3i7Atk9NOX72h7uUG7khZblgQvm2fOzBlePeynzc3lhy8Xn9qr64-bi_Or1nZclNbSHotBcOXk2ClCMYWBg2K2eumGvh8GQZxUfMSut1wqBtUg6TpjhXXVJjtt3qx19yn-WCAXfReXFGpLTSnvFWUMi0qdrdRUDWgfXCzJ2LpGuPc2BnC-3p8zTikjSrAqePdIUJkCv8pklpz1Zvf5MUtW1qaYcwKn98nfm_RbE6yP2eg1G11H18ds9KFq3j6MbY6f6pIJ1ue_QiqVwEx0laMrl-tTmCD9s_f_4n8AITWdIA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2258923306</pqid></control><display><type>article</type><title>Molecular Understanding of Sorption in Mesoscale Organized Zeolites with MFI Structure</title><source>SpringerLink Journals - AutoHoldings</source><creator>Kolvenbach, Robin ; Gonzalez-Peňa, Luis Francisco ; Jentys, Andreas ; Lercher, Johannes A.</creator><creatorcontrib>Kolvenbach, Robin ; Gonzalez-Peňa, Luis Francisco ; Jentys, Andreas ; Lercher, Johannes A.</creatorcontrib><description>We report herein the adsorption of light hydrocarbons in small crystal ZSM-5 monitored by infrared spectroscopy including a direct monitoring of the individual concentrations (surface and intracrystalline). Accessing the individual rates reveals that the sorption enhancement upon surface modification with TEOS is selective towards molecules with a small steric demand and a high heat of adsorption within the silica overlayer.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-013-1118-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Catalysis ; Chemistry ; Chemistry and Materials Science ; Exact sciences and technology ; General and physical chemistry ; Heat of adsorption ; Industrial Chemistry/Chemical Engineering ; Ion-exchange ; Organometallic Chemistry ; Physical Chemistry ; Silicon dioxide ; Sorption ; Surface chemistry ; Surface physical chemistry ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Zeolites ; Zeolites: preparations and properties</subject><ispartof>Catalysis letters, 2013-11, Vol.143 (11), p.1116-1122</ispartof><rights>Springer Science+Business Media New York 2013</rights><rights>2015 INIST-CNRS</rights><rights>COPYRIGHT 2013 Springer</rights><rights>Catalysis Letters is a copyright of Springer, (2013). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c456t-c2806b659f7d491202eb5e93c5624b88bb61f795d0f8c5793e013144ac6cf1183</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-013-1118-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-013-1118-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27960364$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kolvenbach, Robin</creatorcontrib><creatorcontrib>Gonzalez-Peňa, Luis Francisco</creatorcontrib><creatorcontrib>Jentys, Andreas</creatorcontrib><creatorcontrib>Lercher, Johannes A.</creatorcontrib><title>Molecular Understanding of Sorption in Mesoscale Organized Zeolites with MFI Structure</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>We report herein the adsorption of light hydrocarbons in small crystal ZSM-5 monitored by infrared spectroscopy including a direct monitoring of the individual concentrations (surface and intracrystalline). Accessing the individual rates reveals that the sorption enhancement upon surface modification with TEOS is selective towards molecules with a small steric demand and a high heat of adsorption within the silica overlayer.
Graphical Abstract</description><subject>Adsorption</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Heat of adsorption</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ion-exchange</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Silicon dioxide</subject><subject>Sorption</subject><subject>Surface chemistry</subject><subject>Surface physical chemistry</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Zeolites</subject><subject>Zeolites: preparations and properties</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kU9rFTEUxQdRsFY_gLuAuHAxNX8myWRZitUHfRR8VoqbkMncjCnT5JlkUN-nN48pSheSRULyO_fek9M0rwk-IxjL95lgLmiLCWsJIX17eNKcEC5p20t1-7SeMSEtk_T2efMi5zuMsZJEnTRft3EGu8wmoZswQsrFhNGHCUWHdjHti48B-YC2kGO2ZgZ0nSYT_AFG9A3i7Atk9NOX72h7uUG7khZblgQvm2fOzBlePeynzc3lhy8Xn9qr64-bi_Or1nZclNbSHotBcOXk2ClCMYWBg2K2eumGvh8GQZxUfMSut1wqBtUg6TpjhXXVJjtt3qx19yn-WCAXfReXFGpLTSnvFWUMi0qdrdRUDWgfXCzJ2LpGuPc2BnC-3p8zTikjSrAqePdIUJkCv8pklpz1Zvf5MUtW1qaYcwKn98nfm_RbE6yP2eg1G11H18ds9KFq3j6MbY6f6pIJ1ue_QiqVwEx0laMrl-tTmCD9s_f_4n8AITWdIA</recordid><startdate>20131101</startdate><enddate>20131101</enddate><creator>Kolvenbach, Robin</creator><creator>Gonzalez-Peňa, Luis Francisco</creator><creator>Jentys, Andreas</creator><creator>Lercher, Johannes A.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20131101</creationdate><title>Molecular Understanding of Sorption in Mesoscale Organized Zeolites with MFI Structure</title><author>Kolvenbach, Robin ; Gonzalez-Peňa, Luis Francisco ; Jentys, Andreas ; Lercher, Johannes A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c456t-c2806b659f7d491202eb5e93c5624b88bb61f795d0f8c5793e013144ac6cf1183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Adsorption</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Heat of adsorption</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ion-exchange</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Silicon dioxide</topic><topic>Sorption</topic><topic>Surface chemistry</topic><topic>Surface physical chemistry</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Zeolites</topic><topic>Zeolites: preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kolvenbach, Robin</creatorcontrib><creatorcontrib>Gonzalez-Peňa, Luis Francisco</creatorcontrib><creatorcontrib>Jentys, Andreas</creatorcontrib><creatorcontrib>Lercher, Johannes A.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kolvenbach, Robin</au><au>Gonzalez-Peňa, Luis Francisco</au><au>Jentys, Andreas</au><au>Lercher, Johannes A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular Understanding of Sorption in Mesoscale Organized Zeolites with MFI Structure</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2013-11-01</date><risdate>2013</risdate><volume>143</volume><issue>11</issue><spage>1116</spage><epage>1122</epage><pages>1116-1122</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>We report herein the adsorption of light hydrocarbons in small crystal ZSM-5 monitored by infrared spectroscopy including a direct monitoring of the individual concentrations (surface and intracrystalline). Accessing the individual rates reveals that the sorption enhancement upon surface modification with TEOS is selective towards molecules with a small steric demand and a high heat of adsorption within the silica overlayer.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-013-1118-z</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2013-11, Vol.143 (11), p.1116-1122 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_journals_2258923306 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Adsorption Catalysis Chemistry Chemistry and Materials Science Exact sciences and technology General and physical chemistry Heat of adsorption Industrial Chemistry/Chemical Engineering Ion-exchange Organometallic Chemistry Physical Chemistry Silicon dioxide Sorption Surface chemistry Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Zeolites Zeolites: preparations and properties |
| title | Molecular Understanding of Sorption in Mesoscale Organized Zeolites with MFI Structure |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T20%3A07%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Molecular%20Understanding%20of%20Sorption%20in%20Mesoscale%20Organized%20Zeolites%20with%20MFI%20Structure&rft.jtitle=Catalysis%20letters&rft.au=Kolvenbach,%20Robin&rft.date=2013-11-01&rft.volume=143&rft.issue=11&rft.spage=1116&rft.epage=1122&rft.pages=1116-1122&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-013-1118-z&rft_dat=%3Cgale_proqu%3EA352231963%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2258923306&rft_id=info:pmid/&rft_galeid=A352231963&rfr_iscdi=true |