Acetone Condensation Over Sulfated Zirconia Catalysts
The aldol condensation reaction over sulfated zirconia led to the production of diacetone alcohol, which was further dehydrated forming mesityl oxide. The sulfated zirconia was obtained from zirconium acetate ethane sulfonate as a single source precursor. Oxides were obtained by calcinations of the...
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| Veröffentlicht in: | Catalysis letters 2013-07, Vol.143 (7), p.705-716 |
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| creator | Al-Hazmi, Mohammed H. Choi, YongMan Apblett, Allen W. |
| description | The aldol condensation reaction over sulfated zirconia led to the production of diacetone alcohol, which was further dehydrated forming mesityl oxide. The sulfated zirconia was obtained from zirconium acetate ethane sulfonate as a single source precursor. Oxides were obtained by calcinations of the precursors at 550–650 °C, while the self-condensation reaction of acetone was carried out at 150 °C. The precursor and the produced oxides were characterized using various characterization techniques. The precursors were synthesized with different acetate to ethane sulfonate ratio, ranging from 1 to 3. The major products obtained from the condensation reaction over the resulted oxide were mesityl oxide, mesitylene isophorone, naphthalene, and pentamers. The selectivity of mesityl oxide was approximately 100 % at the initial time-on-stream.
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| doi_str_mv | 10.1007/s10562-013-1020-8 |
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Graphical Abstract</description><subject>Acetone</subject><subject>Aldehydes</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensates</subject><subject>Dehydration</subject><subject>Ethane</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mesitylene</subject><subject>Naphthalene</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Precursors</subject><subject>Selectivity</subject><subject>Sulfates</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Zirconium</subject><subject>Zirconium dioxide</subject><subject>Zirconium oxide</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kMtLxDAQxoso-PwDvBXEg4fqZNI27XFZfIEg-IDFS5jNY6nUVJOsuP-9WbooHiSHCZnfN_nmy7JjBucMQFwEBlWNBTBeMEAomq1sj1UCi0a0s-10B8YKLnC2m-2H8AoArWDtXlZNlImDM_l0cNq4QLEbXH7_aXz-uOwtRaPzl86rwXWUTylSvwoxHGY7lvpgjjb1IHu-unya3hR399e308ldocqqjoVVGlsjqroVHGsQcwOqrkox56jIkgCeGnNVEzJkWmtsSkFWg9W2wVoBP8hOxrnvfvhYmhDl67D0Ln0pEaumReSwps5HakG9kZ2zQ_Sk0tHmrUvOje3S-4SXZYOiLXkSnP0RJCaar7igZQjy9vHhL8tGVvkhBG-sfPfdG_mVZCDX0csxepmil-voZZM0pxvbFBT11pNTXfgRoqhEWTdr4zhyIbXcwvjf9f4f_g01K5Dk</recordid><startdate>20130701</startdate><enddate>20130701</enddate><creator>Al-Hazmi, Mohammed H.</creator><creator>Choi, YongMan</creator><creator>Apblett, Allen W.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20130701</creationdate><title>Acetone Condensation Over Sulfated Zirconia Catalysts</title><author>Al-Hazmi, Mohammed H. ; Choi, YongMan ; Apblett, Allen W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c456t-fcd29e7569732607be0c6547b32cafa703973bc6a2121ddd2847afd0fdf826c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Acetone</topic><topic>Aldehydes</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensates</topic><topic>Dehydration</topic><topic>Ethane</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Mesitylene</topic><topic>Naphthalene</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Precursors</topic><topic>Selectivity</topic><topic>Sulfates</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Zirconium</topic><topic>Zirconium dioxide</topic><topic>Zirconium oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Hazmi, Mohammed H.</creatorcontrib><creatorcontrib>Choi, YongMan</creatorcontrib><creatorcontrib>Apblett, Allen W.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Databases</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Hazmi, Mohammed H.</au><au>Choi, YongMan</au><au>Apblett, Allen W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acetone Condensation Over Sulfated Zirconia Catalysts</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2013-07-01</date><risdate>2013</risdate><volume>143</volume><issue>7</issue><spage>705</spage><epage>716</epage><pages>705-716</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>The aldol condensation reaction over sulfated zirconia led to the production of diacetone alcohol, which was further dehydrated forming mesityl oxide. The sulfated zirconia was obtained from zirconium acetate ethane sulfonate as a single source precursor. Oxides were obtained by calcinations of the precursors at 550–650 °C, while the self-condensation reaction of acetone was carried out at 150 °C. The precursor and the produced oxides were characterized using various characterization techniques. The precursors were synthesized with different acetate to ethane sulfonate ratio, ranging from 1 to 3. The major products obtained from the condensation reaction over the resulted oxide were mesityl oxide, mesitylene isophorone, naphthalene, and pentamers. The selectivity of mesityl oxide was approximately 100 % at the initial time-on-stream.
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| ispartof | Catalysis letters, 2013-07, Vol.143 (7), p.705-716 |
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| subjects | Acetone Aldehydes Catalysis Catalysts Chemistry Chemistry and Materials Science Condensates Dehydration Ethane Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering Mesitylene Naphthalene Organometallic Chemistry Physical Chemistry Precursors Selectivity Sulfates Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Zirconium Zirconium dioxide Zirconium oxide |
| title | Acetone Condensation Over Sulfated Zirconia Catalysts |
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