N-Alkylation of Alkylolamines with Alcohols Over Mesoporous Solid Acid–Base Cs–B–Zr Catalyst
The mesoporous solid acid–base Cs–B–Zr mixed oxides were synthesized using the co-precipitation method followed by a subsequent thermal treatment. The catalytic activity of solid Cs–B–Zr mixed oxide was tested for solvent free acid–base catalysed direct alkylolamines with alcohols as green alkylatin...
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| Veröffentlicht in: | Catalysis letters 2016-07, Vol.146 (7), p.1182-1193 |
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| creator | Chen, Aimin Wang, Houyong Liu, Rui Bo, Yingying Hu, Jun |
| description | The mesoporous solid acid–base Cs–B–Zr mixed oxides were synthesized using the co-precipitation method followed by a subsequent thermal treatment. The catalytic activity of solid Cs–B–Zr mixed oxide was tested for solvent free acid–base catalysed direct alkylolamines with alcohols as green alkylating agent. The effects of Cs/B/Zr ratio, calcination temperature, reaction conditions, and reaction substrate on the catalytic performance of the catalysts were investigated. The XRD, N
2
adsorption–desorption, ICP-OES, FT-IR and NH
3
/CO
2
-TPD results showed that the mesoporous structure and acid–base properties of the catalysts play important roles in the reaction. A suitable number of acid and basic sites on the catalyst lead to a high activity for the
N
-alkylation reaction.
Graphical Abstract
A direct
N
-alkylation of amino alcohol with alcohols has been developed using mixed oxide Cs–B–Zr as an acid–base bifunctionalized catalyst. |
| doi_str_mv | 10.1007/s10562-016-1737-2 |
| format | Article |
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2
adsorption–desorption, ICP-OES, FT-IR and NH
3
/CO
2
-TPD results showed that the mesoporous structure and acid–base properties of the catalysts play important roles in the reaction. A suitable number of acid and basic sites on the catalyst lead to a high activity for the
N
-alkylation reaction.
Graphical Abstract
A direct
N
-alkylation of amino alcohol with alcohols has been developed using mixed oxide Cs–B–Zr as an acid–base bifunctionalized catalyst.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-016-1737-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acids ; Alcohol ; Alcohols ; Alkylation ; Ammonia ; Catalysis ; Catalysts ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Heat treatment ; Industrial Chemistry/Chemical Engineering ; Mixed oxides ; Organometallic Chemistry ; Physical Chemistry ; Substrates ; Zirconium oxides</subject><ispartof>Catalysis letters, 2016-07, Vol.146 (7), p.1182-1193</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>Catalysis Letters is a copyright of Springer, (2016). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-f018034bb473dacf4bbd9a53b2b73ce10df714b4f5cdebea6764d59591aac9513</citedby><cites>FETCH-LOGICAL-c353t-f018034bb473dacf4bbd9a53b2b73ce10df714b4f5cdebea6764d59591aac9513</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-016-1737-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-016-1737-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Chen, Aimin</creatorcontrib><creatorcontrib>Wang, Houyong</creatorcontrib><creatorcontrib>Liu, Rui</creatorcontrib><creatorcontrib>Bo, Yingying</creatorcontrib><creatorcontrib>Hu, Jun</creatorcontrib><title>N-Alkylation of Alkylolamines with Alcohols Over Mesoporous Solid Acid–Base Cs–B–Zr Catalyst</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>The mesoporous solid acid–base Cs–B–Zr mixed oxides were synthesized using the co-precipitation method followed by a subsequent thermal treatment. The catalytic activity of solid Cs–B–Zr mixed oxide was tested for solvent free acid–base catalysed direct alkylolamines with alcohols as green alkylating agent. The effects of Cs/B/Zr ratio, calcination temperature, reaction conditions, and reaction substrate on the catalytic performance of the catalysts were investigated. The XRD, N
2
adsorption–desorption, ICP-OES, FT-IR and NH
3
/CO
2
-TPD results showed that the mesoporous structure and acid–base properties of the catalysts play important roles in the reaction. A suitable number of acid and basic sites on the catalyst lead to a high activity for the
N
-alkylation reaction.
Graphical Abstract
A direct
N
-alkylation of amino alcohol with alcohols has been developed using mixed oxide Cs–B–Zr as an acid–base bifunctionalized catalyst.</description><subject>Acids</subject><subject>Alcohol</subject><subject>Alcohols</subject><subject>Alkylation</subject><subject>Ammonia</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Heat treatment</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Mixed oxides</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Substrates</subject><subject>Zirconium oxides</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kE1OwzAQhS0EEqVwAHaWWBv8E8fxskT8SYUuAKliYzmOQ1PSuNgpqDvuwA05CQ5BYsViNG9G781IHwDHBJ8SjMVZIJinFGGSIiKYQHQHjAgXFGVCznejxoQgJuh8HxyEsMQYS0HkCBR3aNK8bBvd1a6FroI_k2v0qm5tgO91t4gr4xauCXD2Zj28tcGtnXebAO9dU5dwYury6-PzXAcL89CrWE8e5rrTzTZ0h2Cv0k2wR799DB4vLx7yazSdXd3kkykyjLMOVZhkmCVFkQhWalNFVUrNWUELwYwluKwESYqk4qa0hdWpSJOSSy6J1kZywsbgZLi79u51Y0Onlm7j2_hSUcqzTArKehcZXMa7ELyt1NrXK-23imDVo1QDShVRqh6lojFDh0yI3vbZ-r_L_4e-AZrDeic</recordid><startdate>20160701</startdate><enddate>20160701</enddate><creator>Chen, Aimin</creator><creator>Wang, Houyong</creator><creator>Liu, Rui</creator><creator>Bo, Yingying</creator><creator>Hu, Jun</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20160701</creationdate><title>N-Alkylation of Alkylolamines with Alcohols Over Mesoporous Solid Acid–Base Cs–B–Zr Catalyst</title><author>Chen, Aimin ; Wang, Houyong ; Liu, Rui ; Bo, Yingying ; Hu, Jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-f018034bb473dacf4bbd9a53b2b73ce10df714b4f5cdebea6764d59591aac9513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acids</topic><topic>Alcohol</topic><topic>Alcohols</topic><topic>Alkylation</topic><topic>Ammonia</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Heat treatment</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Mixed oxides</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Substrates</topic><topic>Zirconium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Aimin</creatorcontrib><creatorcontrib>Wang, Houyong</creatorcontrib><creatorcontrib>Liu, Rui</creatorcontrib><creatorcontrib>Bo, Yingying</creatorcontrib><creatorcontrib>Hu, Jun</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied & Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Aimin</au><au>Wang, Houyong</au><au>Liu, Rui</au><au>Bo, Yingying</au><au>Hu, Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>N-Alkylation of Alkylolamines with Alcohols Over Mesoporous Solid Acid–Base Cs–B–Zr Catalyst</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2016-07-01</date><risdate>2016</risdate><volume>146</volume><issue>7</issue><spage>1182</spage><epage>1193</epage><pages>1182-1193</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>The mesoporous solid acid–base Cs–B–Zr mixed oxides were synthesized using the co-precipitation method followed by a subsequent thermal treatment. The catalytic activity of solid Cs–B–Zr mixed oxide was tested for solvent free acid–base catalysed direct alkylolamines with alcohols as green alkylating agent. The effects of Cs/B/Zr ratio, calcination temperature, reaction conditions, and reaction substrate on the catalytic performance of the catalysts were investigated. The XRD, N
2
adsorption–desorption, ICP-OES, FT-IR and NH
3
/CO
2
-TPD results showed that the mesoporous structure and acid–base properties of the catalysts play important roles in the reaction. A suitable number of acid and basic sites on the catalyst lead to a high activity for the
N
-alkylation reaction.
Graphical Abstract
A direct
N
-alkylation of amino alcohol with alcohols has been developed using mixed oxide Cs–B–Zr as an acid–base bifunctionalized catalyst.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-016-1737-2</doi><tpages>12</tpages></addata></record> |
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| issn | 1011-372X 1572-879X |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Acids Alcohol Alcohols Alkylation Ammonia Catalysis Catalysts Catalytic activity Chemistry Chemistry and Materials Science Heat treatment Industrial Chemistry/Chemical Engineering Mixed oxides Organometallic Chemistry Physical Chemistry Substrates Zirconium oxides |
| title | N-Alkylation of Alkylolamines with Alcohols Over Mesoporous Solid Acid–Base Cs–B–Zr Catalyst |
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