Effect of Sulfation on the Selective Catalytic Reduction of NO with NH3 Over γ-Fe2O3

Because the site for NH 3 adsorption and the active site for NH 3 oxidization were separated after the sulfation, both the SCR reaction and the catalytic oxidization of NH 3 to NO over γ-Fe 2 O 3 were restrained after the sulfation. As a result, the operation temperature window of γ-Fe 2 O 3 for the...

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Veröffentlicht in:Catalysis letters 2014-04, Vol.144 (4), p.578-584
Hauptverfasser: Huang, Haili, Lan, Yi, Shan, Wenpo, Qi, Feihong, Xiong, Shangcao, Liao, Yong, Fu, Yuwu, Yang, Shijian
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container_end_page 584
container_issue 4
container_start_page 578
container_title Catalysis letters
container_volume 144
creator Huang, Haili
Lan, Yi
Shan, Wenpo
Qi, Feihong
Xiong, Shangcao
Liao, Yong
Fu, Yuwu
Yang, Shijian
description Because the site for NH 3 adsorption and the active site for NH 3 oxidization were separated after the sulfation, both the SCR reaction and the catalytic oxidization of NH 3 to NO over γ-Fe 2 O 3 were restrained after the sulfation. As a result, the operation temperature window of γ-Fe 2 O 3 for the SCR reaction shifted about 100 °C to higher temperature after the sulfation. Graphical Abstract
doi_str_mv 10.1007/s10562-013-1174-4
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subjects Ammonia
Catalysis
Chemistry
Chemistry and Materials Science
Exact sciences and technology
General and physical chemistry
Industrial Chemistry/Chemical Engineering
Organometallic Chemistry
Physical Chemistry
Selective catalytic reduction
Sulfation
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title Effect of Sulfation on the Selective Catalytic Reduction of NO with NH3 Over γ-Fe2O3
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