V2O5 Anchored RuO2: An Efficient Nanocatalyst for Aerial Oxidation of Alcohols
RuO 2 /V 2 O 5 nanocatalyst has been prepared from Ru(acac) 3 and V 2 O 5 by a simple dry synthesis for the first time. The formation of RuO 2 /V 2 O 5 nanocatalyst was confirmed by XRD and FT-IR analyses. Morphology and size of the nanocatalyst were found using SEM and TEM respectively. SEM–EDS ana...
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| Veröffentlicht in: | Catalysis letters 2014-07, Vol.144 (7), p.1245-1252 |
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| creator | Ganesh Babu, S. Krishnamoorthi, S. Thiruneelakandan, R. Karvembu, R. |
| description | RuO
2
/V
2
O
5
nanocatalyst has been prepared from Ru(acac)
3
and V
2
O
5
by a simple dry synthesis for the first time. The formation of RuO
2
/V
2
O
5
nanocatalyst was confirmed by XRD and FT-IR analyses. Morphology and size of the nanocatalyst were found using SEM and TEM respectively. SEM–EDS analysis was carried out to know the weight percentage of Ru in the catalyst. Thermal stability of the catalyst was found using TG/DTA analysis. Further, RuO
2
/V
2
O
5
was found to be an efficient catalyst for the aerial oxidation of alcohols to their corresponding carbonyl compounds. Moreover, very low Ru content (0.36 mol%) was exploited for this conversion, nevertheless very high turnover number was observed. The use of recyclable nanocatalyst and atmospheric oxygen as oxidant made the system interesting from the green chemistry point of view.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-014-1262-0 |
| format | Article |
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2
/V
2
O
5
nanocatalyst has been prepared from Ru(acac)
3
and V
2
O
5
by a simple dry synthesis for the first time. The formation of RuO
2
/V
2
O
5
nanocatalyst was confirmed by XRD and FT-IR analyses. Morphology and size of the nanocatalyst were found using SEM and TEM respectively. SEM–EDS analysis was carried out to know the weight percentage of Ru in the catalyst. Thermal stability of the catalyst was found using TG/DTA analysis. Further, RuO
2
/V
2
O
5
was found to be an efficient catalyst for the aerial oxidation of alcohols to their corresponding carbonyl compounds. Moreover, very low Ru content (0.36 mol%) was exploited for this conversion, nevertheless very high turnover number was observed. The use of recyclable nanocatalyst and atmospheric oxygen as oxidant made the system interesting from the green chemistry point of view.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-014-1262-0</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alcohol ; Alcohols ; Carbonyl compounds ; Carbonyls ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Differential thermal analysis ; Exact sciences and technology ; General and physical chemistry ; Industrial Chemistry/Chemical Engineering ; Morphology ; Organic chemistry ; Organometallic Chemistry ; Oxidation ; Physical Chemistry ; Ruthenium oxide ; Stability analysis ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Thermal stability ; Vanadium pentoxide</subject><ispartof>Catalysis letters, 2014-07, Vol.144 (7), p.1245-1252</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>2015 INIST-CNRS</rights><rights>Catalysis Letters is a copyright of Springer, (2014). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c416t-f88324a4676c697048f255174b20e5bed1c4a38336f9f821bbb7c14b8030b673</citedby><cites>FETCH-LOGICAL-c416t-f88324a4676c697048f255174b20e5bed1c4a38336f9f821bbb7c14b8030b673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-014-1262-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-014-1262-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28614485$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ganesh Babu, S.</creatorcontrib><creatorcontrib>Krishnamoorthi, S.</creatorcontrib><creatorcontrib>Thiruneelakandan, R.</creatorcontrib><creatorcontrib>Karvembu, R.</creatorcontrib><title>V2O5 Anchored RuO2: An Efficient Nanocatalyst for Aerial Oxidation of Alcohols</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>RuO
2
/V
2
O
5
nanocatalyst has been prepared from Ru(acac)
3
and V
2
O
5
by a simple dry synthesis for the first time. The formation of RuO
2
/V
2
O
5
nanocatalyst was confirmed by XRD and FT-IR analyses. Morphology and size of the nanocatalyst were found using SEM and TEM respectively. SEM–EDS analysis was carried out to know the weight percentage of Ru in the catalyst. Thermal stability of the catalyst was found using TG/DTA analysis. Further, RuO
2
/V
2
O
5
was found to be an efficient catalyst for the aerial oxidation of alcohols to their corresponding carbonyl compounds. Moreover, very low Ru content (0.36 mol%) was exploited for this conversion, nevertheless very high turnover number was observed. The use of recyclable nanocatalyst and atmospheric oxygen as oxidant made the system interesting from the green chemistry point of view.
Graphical Abstract</description><subject>Alcohol</subject><subject>Alcohols</subject><subject>Carbonyl compounds</subject><subject>Carbonyls</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Differential thermal analysis</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Morphology</subject><subject>Organic chemistry</subject><subject>Organometallic Chemistry</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Ruthenium oxide</subject><subject>Stability analysis</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Thermal stability</subject><subject>Vanadium pentoxide</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1UE1LAzEQDaJgrf4AbwHxuJrJJpust1LqB5QuSJHeQjZN7JZ1U5Mt2H9vyoqenMu8Yd57MzyEroHcASHiPgLhBc0IsAzoEZygEXBBMynK1WnCBCDLBV2do4sYt4SQUkA5Qos3WnE86czGB7vGr_uKPqQRz5xrTGO7Hi90543udXuIPXY-4IkNjW5x9dWsdd_4DnuHJ63xG9_GS3TmdBvt1U8fo-XjbDl9zubV08t0Ms8Mg6LPnJQ5ZZoVojBFKQiTjnIOgtWUWF7bNRimc5nnhSudpFDXtTDAaklyUhciH6ObwXYX_Ofexl5t_T506aKilMtUlJeJBQPLBB9jsE7tQvOhw0EBUcfU1JCaSqmpY2qKJM3tj7OORrcu6M408VdIZQGMSZ54dODFtOrebfj74H_zbyWbeY8</recordid><startdate>20140701</startdate><enddate>20140701</enddate><creator>Ganesh Babu, S.</creator><creator>Krishnamoorthi, S.</creator><creator>Thiruneelakandan, R.</creator><creator>Karvembu, R.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20140701</creationdate><title>V2O5 Anchored RuO2: An Efficient Nanocatalyst for Aerial Oxidation of Alcohols</title><author>Ganesh Babu, S. ; Krishnamoorthi, S. ; Thiruneelakandan, R. ; Karvembu, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c416t-f88324a4676c697048f255174b20e5bed1c4a38336f9f821bbb7c14b8030b673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Alcohol</topic><topic>Alcohols</topic><topic>Carbonyl compounds</topic><topic>Carbonyls</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Differential thermal analysis</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Morphology</topic><topic>Organic chemistry</topic><topic>Organometallic Chemistry</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Ruthenium oxide</topic><topic>Stability analysis</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Thermal stability</topic><topic>Vanadium pentoxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ganesh Babu, S.</creatorcontrib><creatorcontrib>Krishnamoorthi, S.</creatorcontrib><creatorcontrib>Thiruneelakandan, R.</creatorcontrib><creatorcontrib>Karvembu, R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ganesh Babu, S.</au><au>Krishnamoorthi, S.</au><au>Thiruneelakandan, R.</au><au>Karvembu, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>V2O5 Anchored RuO2: An Efficient Nanocatalyst for Aerial Oxidation of Alcohols</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2014-07-01</date><risdate>2014</risdate><volume>144</volume><issue>7</issue><spage>1245</spage><epage>1252</epage><pages>1245-1252</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>RuO
2
/V
2
O
5
nanocatalyst has been prepared from Ru(acac)
3
and V
2
O
5
by a simple dry synthesis for the first time. The formation of RuO
2
/V
2
O
5
nanocatalyst was confirmed by XRD and FT-IR analyses. Morphology and size of the nanocatalyst were found using SEM and TEM respectively. SEM–EDS analysis was carried out to know the weight percentage of Ru in the catalyst. Thermal stability of the catalyst was found using TG/DTA analysis. Further, RuO
2
/V
2
O
5
was found to be an efficient catalyst for the aerial oxidation of alcohols to their corresponding carbonyl compounds. Moreover, very low Ru content (0.36 mol%) was exploited for this conversion, nevertheless very high turnover number was observed. The use of recyclable nanocatalyst and atmospheric oxygen as oxidant made the system interesting from the green chemistry point of view.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-014-1262-0</doi><tpages>8</tpages></addata></record> |
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| issn | 1011-372X 1572-879X |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Alcohol Alcohols Carbonyl compounds Carbonyls Catalysis Catalysts Chemistry Chemistry and Materials Science Differential thermal analysis Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering Morphology Organic chemistry Organometallic Chemistry Oxidation Physical Chemistry Ruthenium oxide Stability analysis Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Thermal stability Vanadium pentoxide |
| title | V2O5 Anchored RuO2: An Efficient Nanocatalyst for Aerial Oxidation of Alcohols |
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