Polyaromatic Products of Three-Component Coupling of Aryl Halide with Two Molecules of Arylacetylene and Arylboronic Acid under Ligand-Free Catalysis Conditions
The aryl halide-arylacetylene-arylboronic acid three-component coupling in the presence of a Pd catalyst containing no organic ligands is described. The reaction routes that take place in the reaction system are shown to include the consecutive carbopalladation of two arylacetylene molecules, leadin...
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| Veröffentlicht in: | Russian journal of organic chemistry 2019-05, Vol.55 (5), p.678-681 |
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| container_end_page | 681 |
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| container_issue | 5 |
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| container_title | Russian journal of organic chemistry |
| container_volume | 55 |
| creator | Yarosh, E. V. Larina, E. V. Lagoda, N. A. Kurokhtina, A. A. Schmidt, A. F. |
| description | The aryl halide-arylacetylene-arylboronic acid three-component coupling in the presence of a Pd catalyst containing no organic ligands is described. The reaction routes that take place in the reaction system are shown to include the consecutive carbopalladation of two arylacetylene molecules, leading to unsaturated polyaromatic compounds. The possibility of controlling the alternative reaction routes is demonstrated. |
| doi_str_mv | 10.1134/S1070428019050154 |
| format | Article |
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The possibility of controlling the alternative reaction routes is demonstrated.</description><subject>Aromatic compounds</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coupling (molecular)</subject><subject>Ligands</subject><subject>Organic Chemistry</subject><issn>1070-4280</issn><issn>1608-3393</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kc1qHDEQhIeQQBwnD5CbIOdxukeaHx2XIbYDa2zI5jxo9bOW0UobSYOZt_GjWpuN8cHk1E1_VV2HqqqvCBeIlH3_hdADawZADi1gy95VZ9jBUFPK6fuyF1wf-cfqU0oPAMCQ0bPq6S64RcSwF9lKcheDmmVOJBiyuY9a12PYH4LXPpMxzAdn_e7IVnFx5Fo4qzR5tPmebB4DuQlOy9np9KIQUufFaa-J8OrvZRti8CVnJa0is1c6krXdFVpfljAyiizckmwqYV7ZbINPn6sPRrikv_yb59Xvyx-b8bpe3179HFfrWlLsct0O0KtOGtajkUJSJQENNnTQLUMYtrLljMMWesaVAsMlZ8CHDqUxgrKO0_Pq2-nvIYY_s055eghz9CVyapq264e26bCo8KSSMaQUtZkO0e5FXCaE6VjE9KaI4mlOnlS0fqfj6-f_m54BgXOL-w</recordid><startdate>20190501</startdate><enddate>20190501</enddate><creator>Yarosh, E. 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| subjects | Aromatic compounds Catalysis Chemistry Chemistry and Materials Science Coupling (molecular) Ligands Organic Chemistry |
| title | Polyaromatic Products of Three-Component Coupling of Aryl Halide with Two Molecules of Arylacetylene and Arylboronic Acid under Ligand-Free Catalysis Conditions |
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