Study of the Adsorption Activity of Skeletal Nickel with Respect to Reactive Hydrogen by Simultaneous Thermal Analysis Mass Spectrometry
A method for the determination of the total amounts and physical parameters of adsorbed individual hydrogen species on the surface and in the bulk of metal catalysts of liquid-phase hydrogenation reactions by simultaneous thermal analysis mass spectrometry was proposed. The adsorptions of reactive h...
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| Veröffentlicht in: | Russian journal of general chemistry 2019-06, Vol.89 (6), p.1332-1337 |
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| container_end_page | 1337 |
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| container_issue | 6 |
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| container_title | Russian journal of general chemistry |
| container_volume | 89 |
| creator | Prozorov, D. A. Afineevskii, A. V. Smirnov, N. N. Sukhachev, Y. P. Chelysheva, M. D. |
| description | A method for the determination of the total amounts and physical parameters of adsorbed individual hydrogen species on the surface and in the bulk of metal catalysts of liquid-phase hydrogenation reactions by simultaneous thermal analysis mass spectrometry was proposed. The adsorptions of reactive hydrogen on a skeletal nickel catalyst in an aqueous medium were estimated. The concentrations of metal-hydrogen complexes with different binding energies on the surface of the catalyst in the liquid phase were determined by a direct experimental method. |
| doi_str_mv | 10.1134/S1070363219060318 |
| format | Article |
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The concentrations of metal-hydrogen complexes with different binding energies on the surface of the catalyst in the liquid phase were determined by a direct experimental method.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363219060318</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adsorption ; Analysis ; Aqueous solutions ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination compounds ; Force and energy ; Hydrogen ; Hydrogen storage ; Hydrogenation ; Liquid phases ; Mass spectrometry ; Metal catalysts ; Nickel ; Physical properties ; Scientific imaging ; Spectroscopy ; Surface chemistry ; Thermal analysis ; Transition metal compounds</subject><ispartof>Russian journal of general chemistry, 2019-06, Vol.89 (6), p.1332-1337</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c307t-9163c927cd645ee1c83b3c996aa5d5114abb6b210acbb9aa6b4e57d1c6c804b03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363219060318$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363219060318$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Prozorov, D. 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| source | SpringerNature Journals |
| subjects | Adsorption Analysis Aqueous solutions Catalysis Catalysts Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Force and energy Hydrogen Hydrogen storage Hydrogenation Liquid phases Mass spectrometry Metal catalysts Nickel Physical properties Scientific imaging Spectroscopy Surface chemistry Thermal analysis Transition metal compounds |
| title | Study of the Adsorption Activity of Skeletal Nickel with Respect to Reactive Hydrogen by Simultaneous Thermal Analysis Mass Spectrometry |
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