Investigation of Acidic and Coordination Properties of Octabromo-Substituted Porphyrins in the System of 1,8-Diazabicyclo[5,4,0]unde-7-ene-Acetonitrile

Acidity and metal ion coordination are described for three porphyrin derivatives, different in their macrocycle conformation and electronic substitution effects due to bromine substitution in pyrrole rings and trifluorometyl or phenyl groups in meso -positions. Combination of these facts allows modu...

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Veröffentlicht in:	Russian journal of general chemistry 2019-06, Vol.89 (6), p.1286-1296
Hauptverfasser:	Pukhovskaya, S. G., Ivanova, Yu. B., Semeikin, A. S., Syrbu, S. A., Kruk, N. N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Bromine Chemistry Chemistry and Materials Science Chemistry/Food Science Complex formation Configuration interaction Coordination compounds Metal ions Molecular structure Porphyrins Single electrons Substitution reactions
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