Preparation of UV-curable hybrid films via sol–gel synthesis for hydrophobic surface applications
This study defines the preparation and characterization of organic–inorganic hybrid films that contain fluorine. Diurethane dimethacrylate (DUDMA) was used as the organic portion, and 1 H , 1 H , 2 H , 2 H -perfluorooctyltriethoxysilane (FTS) and 3-(trimethoxysilyl) propyl methacrylate (MEMO) were u...
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| description | This study defines the preparation and characterization of organic–inorganic hybrid films that contain fluorine. Diurethane dimethacrylate (DUDMA) was used as the organic portion, and 1
H
, 1
H
, 2
H
, 2
H
-perfluorooctyltriethoxysilane (FTS) and 3-(trimethoxysilyl) propyl methacrylate (MEMO) were used as the inorganically rich portion. MEMO, found in the organic portion, is bonded to FTS by means of Si–O–Si bonds in the hybrid formulation and, on the other hand, is added to the polymerization together with DUDMA during the ultraviolet (UV)-curing process. Primarily hydrolysis and condensation reactions were formed between the sol–gel primers FTS and MEMO, and film solutions were then acquired by adding the organic portion to this mixture. The UV curing was done by applying these solutions to the polycarbonate (PC) surfaces. The degree of polymerization of the obtained films was monitored with the Fourier-transform infrared spectroscopy analysis. The thermogravimetric analysis as the thermal test was conducted over the free films. Mechanical tests such as cross-cut, pencil, and Newton hardness; scanning electron microscopy examinations; and optical characterizations and contact angle measurements were conducted over the film on the PC surface. With the hybrid films created on the PC surfaces, mechanical, highly durable, hydrophobic, and easy to clean films were acquired only with UV curing without requiring any thermal curing, and these films do not change the optical and visual properties of the PC surface in a significant scale. The conclusion was reached maximum at 112° water contact angle (WCA) and 4 N hardness value, and had almost the same visual properties as the uncoated PC surface.
Highlights
Highly transparent organic–inorganic hybrid films were prepared by UV-curing process.
The influence of the amount of hydrophobic agent in hybrids has been discussed.
Optimal amounts of hydrophobic agent enhance the optical, mechanical, and easy to clean properties.
Hybrid films have been proposed protecting the original appearance of the PC layers. |
| doi_str_mv | 10.1007/s10971-019-05027-x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2255741243</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2255741243</sourcerecordid><originalsourceid>FETCH-LOGICAL-c384t-62fbd31582a4738086d8e36f12ab8f510a26a5273b165d07f5458bb60e22b8dd3</originalsourceid><addsrcrecordid>eNp9kL1OwzAURi0EEqXwAkyWmA3Xdhy7I6r4kyrBQFktO7HbVGkd7AS1G-_AG_IkhAaJrdNdzneudBC6pHBNAeRNojCRlACdEBDAJNkeoREVkpNMZfkxGsGEKQIS5Ck6S2kFACKjcoSKl-gaE01bhQ0OHs_fSNFFY2uHlzsbqxL7ql4n_FEZnEL9_fm1cDVOu027dKlK2IfYg2UMzTLYqsCpi94UDpumqatir03n6MSbOrmLvztG8_u71-kjmT0_PE1vZ6TgKmtJzrwtORWKmUxyBSovleO5p8xY5QUFw3IjmOSW5qIE6UUmlLU5OMasKks-RleDt4nhvXOp1avQxU3_UjMmhMwoy_hhiucMZF-pp9hAFTGkFJ3XTazWJu40Bf2bXA_JdZ9c75PrbT_iwyj18Gbh4r_6wOoHNbOFZw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2255741243</pqid></control><display><type>article</type><title>Preparation of UV-curable hybrid films via sol–gel synthesis for hydrophobic surface applications</title><source>Springer Nature - Complete Springer Journals</source><creator>Kesmez, Ömer</creator><creatorcontrib>Kesmez, Ömer</creatorcontrib><description>This study defines the preparation and characterization of organic–inorganic hybrid films that contain fluorine. Diurethane dimethacrylate (DUDMA) was used as the organic portion, and 1
H
, 1
H
, 2
H
, 2
H
-perfluorooctyltriethoxysilane (FTS) and 3-(trimethoxysilyl) propyl methacrylate (MEMO) were used as the inorganically rich portion. MEMO, found in the organic portion, is bonded to FTS by means of Si–O–Si bonds in the hybrid formulation and, on the other hand, is added to the polymerization together with DUDMA during the ultraviolet (UV)-curing process. Primarily hydrolysis and condensation reactions were formed between the sol–gel primers FTS and MEMO, and film solutions were then acquired by adding the organic portion to this mixture. The UV curing was done by applying these solutions to the polycarbonate (PC) surfaces. The degree of polymerization of the obtained films was monitored with the Fourier-transform infrared spectroscopy analysis. The thermogravimetric analysis as the thermal test was conducted over the free films. Mechanical tests such as cross-cut, pencil, and Newton hardness; scanning electron microscopy examinations; and optical characterizations and contact angle measurements were conducted over the film on the PC surface. With the hybrid films created on the PC surfaces, mechanical, highly durable, hydrophobic, and easy to clean films were acquired only with UV curing without requiring any thermal curing, and these films do not change the optical and visual properties of the PC surface in a significant scale. The conclusion was reached maximum at 112° water contact angle (WCA) and 4 N hardness value, and had almost the same visual properties as the uncoated PC surface.
Highlights
Highly transparent organic–inorganic hybrid films were prepared by UV-curing process.
The influence of the amount of hydrophobic agent in hybrids has been discussed.
Optimal amounts of hydrophobic agent enhance the optical, mechanical, and easy to clean properties.
Hybrid films have been proposed protecting the original appearance of the PC layers.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-019-05027-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Ceramics ; Chemistry and Materials Science ; Composites ; Contact angle ; Curing ; Curing agents ; Degree of polymerization ; Fluorine ; Fourier transforms ; Glass ; Hydrophobicity ; Infrared analysis ; Inorganic Chemistry ; Materials Science ; Mechanical tests ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Optical properties ; Original Paper: Characterization methods of sol-gel and hybrid materials ; Polycarbonate resins ; Polymerization ; Protective coatings ; Scanning electron microscopy ; Sol-gel processes ; Thermogravimetric analysis ; Ultraviolet radiation ; Water hardness</subject><ispartof>Journal of sol-gel science and technology, 2019-07, Vol.91 (1), p.1-10</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-62fbd31582a4738086d8e36f12ab8f510a26a5273b165d07f5458bb60e22b8dd3</citedby><cites>FETCH-LOGICAL-c384t-62fbd31582a4738086d8e36f12ab8f510a26a5273b165d07f5458bb60e22b8dd3</cites><orcidid>0000-0003-0107-8558</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-019-05027-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-019-05027-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kesmez, Ömer</creatorcontrib><title>Preparation of UV-curable hybrid films via sol–gel synthesis for hydrophobic surface applications</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>This study defines the preparation and characterization of organic–inorganic hybrid films that contain fluorine. Diurethane dimethacrylate (DUDMA) was used as the organic portion, and 1
H
, 1
H
, 2
H
, 2
H
-perfluorooctyltriethoxysilane (FTS) and 3-(trimethoxysilyl) propyl methacrylate (MEMO) were used as the inorganically rich portion. MEMO, found in the organic portion, is bonded to FTS by means of Si–O–Si bonds in the hybrid formulation and, on the other hand, is added to the polymerization together with DUDMA during the ultraviolet (UV)-curing process. Primarily hydrolysis and condensation reactions were formed between the sol–gel primers FTS and MEMO, and film solutions were then acquired by adding the organic portion to this mixture. The UV curing was done by applying these solutions to the polycarbonate (PC) surfaces. The degree of polymerization of the obtained films was monitored with the Fourier-transform infrared spectroscopy analysis. The thermogravimetric analysis as the thermal test was conducted over the free films. Mechanical tests such as cross-cut, pencil, and Newton hardness; scanning electron microscopy examinations; and optical characterizations and contact angle measurements were conducted over the film on the PC surface. With the hybrid films created on the PC surfaces, mechanical, highly durable, hydrophobic, and easy to clean films were acquired only with UV curing without requiring any thermal curing, and these films do not change the optical and visual properties of the PC surface in a significant scale. The conclusion was reached maximum at 112° water contact angle (WCA) and 4 N hardness value, and had almost the same visual properties as the uncoated PC surface.
Highlights
Highly transparent organic–inorganic hybrid films were prepared by UV-curing process.
The influence of the amount of hydrophobic agent in hybrids has been discussed.
Optimal amounts of hydrophobic agent enhance the optical, mechanical, and easy to clean properties.
Hybrid films have been proposed protecting the original appearance of the PC layers.</description><subject>Ceramics</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Contact angle</subject><subject>Curing</subject><subject>Curing agents</subject><subject>Degree of polymerization</subject><subject>Fluorine</subject><subject>Fourier transforms</subject><subject>Glass</subject><subject>Hydrophobicity</subject><subject>Infrared analysis</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Mechanical tests</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Original Paper: Characterization methods of sol-gel and hybrid materials</subject><subject>Polycarbonate resins</subject><subject>Polymerization</subject><subject>Protective coatings</subject><subject>Scanning electron microscopy</subject><subject>Sol-gel processes</subject><subject>Thermogravimetric analysis</subject><subject>Ultraviolet radiation</subject><subject>Water hardness</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kL1OwzAURi0EEqXwAkyWmA3Xdhy7I6r4kyrBQFktO7HbVGkd7AS1G-_AG_IkhAaJrdNdzneudBC6pHBNAeRNojCRlACdEBDAJNkeoREVkpNMZfkxGsGEKQIS5Ck6S2kFACKjcoSKl-gaE01bhQ0OHs_fSNFFY2uHlzsbqxL7ql4n_FEZnEL9_fm1cDVOu027dKlK2IfYg2UMzTLYqsCpi94UDpumqatir03n6MSbOrmLvztG8_u71-kjmT0_PE1vZ6TgKmtJzrwtORWKmUxyBSovleO5p8xY5QUFw3IjmOSW5qIE6UUmlLU5OMasKks-RleDt4nhvXOp1avQxU3_UjMmhMwoy_hhiucMZF-pp9hAFTGkFJ3XTazWJu40Bf2bXA_JdZ9c75PrbT_iwyj18Gbh4r_6wOoHNbOFZw</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Kesmez, Ömer</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0003-0107-8558</orcidid></search><sort><creationdate>20190701</creationdate><title>Preparation of UV-curable hybrid films via sol–gel synthesis for hydrophobic surface applications</title><author>Kesmez, Ömer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-62fbd31582a4738086d8e36f12ab8f510a26a5273b165d07f5458bb60e22b8dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Ceramics</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Contact angle</topic><topic>Curing</topic><topic>Curing agents</topic><topic>Degree of polymerization</topic><topic>Fluorine</topic><topic>Fourier transforms</topic><topic>Glass</topic><topic>Hydrophobicity</topic><topic>Infrared analysis</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Mechanical tests</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Original Paper: Characterization methods of sol-gel and hybrid materials</topic><topic>Polycarbonate resins</topic><topic>Polymerization</topic><topic>Protective coatings</topic><topic>Scanning electron microscopy</topic><topic>Sol-gel processes</topic><topic>Thermogravimetric analysis</topic><topic>Ultraviolet radiation</topic><topic>Water hardness</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kesmez, Ömer</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kesmez, Ömer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of UV-curable hybrid films via sol–gel synthesis for hydrophobic surface applications</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2019-07-01</date><risdate>2019</risdate><volume>91</volume><issue>1</issue><spage>1</spage><epage>10</epage><pages>1-10</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>This study defines the preparation and characterization of organic–inorganic hybrid films that contain fluorine. Diurethane dimethacrylate (DUDMA) was used as the organic portion, and 1
H
, 1
H
, 2
H
, 2
H
-perfluorooctyltriethoxysilane (FTS) and 3-(trimethoxysilyl) propyl methacrylate (MEMO) were used as the inorganically rich portion. MEMO, found in the organic portion, is bonded to FTS by means of Si–O–Si bonds in the hybrid formulation and, on the other hand, is added to the polymerization together with DUDMA during the ultraviolet (UV)-curing process. Primarily hydrolysis and condensation reactions were formed between the sol–gel primers FTS and MEMO, and film solutions were then acquired by adding the organic portion to this mixture. The UV curing was done by applying these solutions to the polycarbonate (PC) surfaces. The degree of polymerization of the obtained films was monitored with the Fourier-transform infrared spectroscopy analysis. The thermogravimetric analysis as the thermal test was conducted over the free films. Mechanical tests such as cross-cut, pencil, and Newton hardness; scanning electron microscopy examinations; and optical characterizations and contact angle measurements were conducted over the film on the PC surface. With the hybrid films created on the PC surfaces, mechanical, highly durable, hydrophobic, and easy to clean films were acquired only with UV curing without requiring any thermal curing, and these films do not change the optical and visual properties of the PC surface in a significant scale. The conclusion was reached maximum at 112° water contact angle (WCA) and 4 N hardness value, and had almost the same visual properties as the uncoated PC surface.
Highlights
Highly transparent organic–inorganic hybrid films were prepared by UV-curing process.
The influence of the amount of hydrophobic agent in hybrids has been discussed.
Optimal amounts of hydrophobic agent enhance the optical, mechanical, and easy to clean properties.
Hybrid films have been proposed protecting the original appearance of the PC layers.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-019-05027-x</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-0107-8558</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0928-0707 |
| ispartof | Journal of sol-gel science and technology, 2019-07, Vol.91 (1), p.1-10 |
| issn | 0928-0707 1573-4846 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Ceramics Chemistry and Materials Science Composites Contact angle Curing Curing agents Degree of polymerization Fluorine Fourier transforms Glass Hydrophobicity Infrared analysis Inorganic Chemistry Materials Science Mechanical tests Nanotechnology Natural Materials Optical and Electronic Materials Optical properties Original Paper: Characterization methods of sol-gel and hybrid materials Polycarbonate resins Polymerization Protective coatings Scanning electron microscopy Sol-gel processes Thermogravimetric analysis Ultraviolet radiation Water hardness |
| title | Preparation of UV-curable hybrid films via sol–gel synthesis for hydrophobic surface applications |
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