Selective Reduction of Nitroarenes Catalyzed by Sustainable and Reusable DNA-supported Nickel Nanoparticles in Water at Room Temperature
In this research, a novel, biodegradable and environmentally friendly catalyst composed of nickel nanoparticles supported on DNA was prepared and fully characterized by Fourier transform infrared spectroscopy, high resolution transmission electron microscopy, energy-dispersive X-ray analysis, X-ray...
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| Veröffentlicht in: | Catalysis letters 2019-08, Vol.149 (8), p.2234-2246 |
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| creator | Niakan, Mahsa Asadi, Zahra |
| description | In this research, a novel, biodegradable and environmentally friendly catalyst composed of nickel nanoparticles supported on DNA was prepared and fully characterized by Fourier transform infrared spectroscopy, high resolution transmission electron microscopy, energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, UV–vis spectroscopy, inductively coupled plasma optical emission spectroscopy, and elemental analysis. The catalyst exhibited remarkable catalytic activity and chemoselectivity for the reduction of various substituted nitroarenes with sodium borohydride (NaBH
4
) as the source of inexpensive hydride in water at room temperature. High turnover frequency and selectivity were observed for the reduction of all tested substrates. Interestingly, the catalyst could be recovered conveniently for multiple recycling reactions with sustained activity. Furthermore, nearly no nickel species was leached out from the catalyst during the course of reaction, proving the true heterogeneity in the present catalytic protocol.
Graphical Abstract
The reduction of various nitroaromatic compounds into their corresponding amines is achieved by DNA supported nickel nanoparticles with the sodium borohydride as the reducing agent in water at room temperature. |
| doi_str_mv | 10.1007/s10562-019-02741-7 |
| format | Article |
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4
) as the source of inexpensive hydride in water at room temperature. High turnover frequency and selectivity were observed for the reduction of all tested substrates. Interestingly, the catalyst could be recovered conveniently for multiple recycling reactions with sustained activity. Furthermore, nearly no nickel species was leached out from the catalyst during the course of reaction, proving the true heterogeneity in the present catalytic protocol.
Graphical Abstract
The reduction of various nitroaromatic compounds into their corresponding amines is achieved by DNA supported nickel nanoparticles with the sodium borohydride as the reducing agent in water at room temperature.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-019-02741-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Amines ; Biodegradability ; Borohydrides ; Catalysis ; Catalysts ; Catalytic activity ; Chemical tests and reagents ; Chemistry ; Chemistry and Materials Science ; Deoxyribonucleic acid ; DNA ; Emission analysis ; Energy transmission ; Fourier transforms ; Green market ; Inductively coupled plasma ; Industrial Chemistry/Chemical Engineering ; Infrared analysis ; Nanoparticles ; Nickel ; Optical emission spectroscopy ; Organometallic Chemistry ; Photoelectrons ; Physical Chemistry ; Reducing agents ; Reduction ; Room temperature ; Selectivity ; Spectroscopic analysis ; Spectrum analysis ; Substrates ; Transmission electron microscopy ; X ray analysis</subject><ispartof>Catalysis letters, 2019-08, Vol.149 (8), p.2234-2246</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Catalysis Letters is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-62b17edf26f1e24676a30e3fa59ceb0b797b88592fbbd5958eda589b11a85b653</citedby><cites>FETCH-LOGICAL-c429t-62b17edf26f1e24676a30e3fa59ceb0b797b88592fbbd5958eda589b11a85b653</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-019-02741-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-019-02741-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids></links><search><creatorcontrib>Niakan, Mahsa</creatorcontrib><creatorcontrib>Asadi, Zahra</creatorcontrib><title>Selective Reduction of Nitroarenes Catalyzed by Sustainable and Reusable DNA-supported Nickel Nanoparticles in Water at Room Temperature</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>In this research, a novel, biodegradable and environmentally friendly catalyst composed of nickel nanoparticles supported on DNA was prepared and fully characterized by Fourier transform infrared spectroscopy, high resolution transmission electron microscopy, energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, UV–vis spectroscopy, inductively coupled plasma optical emission spectroscopy, and elemental analysis. The catalyst exhibited remarkable catalytic activity and chemoselectivity for the reduction of various substituted nitroarenes with sodium borohydride (NaBH
4
) as the source of inexpensive hydride in water at room temperature. High turnover frequency and selectivity were observed for the reduction of all tested substrates. Interestingly, the catalyst could be recovered conveniently for multiple recycling reactions with sustained activity. Furthermore, nearly no nickel species was leached out from the catalyst during the course of reaction, proving the true heterogeneity in the present catalytic protocol.
Graphical Abstract
The reduction of various nitroaromatic compounds into their corresponding amines is achieved by DNA supported nickel nanoparticles with the sodium borohydride as the reducing agent in water at room temperature.</description><subject>Amines</subject><subject>Biodegradability</subject><subject>Borohydrides</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical tests and reagents</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Deoxyribonucleic acid</subject><subject>DNA</subject><subject>Emission analysis</subject><subject>Energy transmission</subject><subject>Fourier transforms</subject><subject>Green market</subject><subject>Inductively coupled plasma</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared analysis</subject><subject>Nanoparticles</subject><subject>Nickel</subject><subject>Optical emission spectroscopy</subject><subject>Organometallic Chemistry</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Reducing agents</subject><subject>Reduction</subject><subject>Room temperature</subject><subject>Selectivity</subject><subject>Spectroscopic analysis</subject><subject>Spectrum analysis</subject><subject>Substrates</subject><subject>Transmission electron microscopy</subject><subject>X ray analysis</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kcFu1DAQhiMEEqXwApwsceKQYjvr2D6uFgqVqkXaLaI3a5xMVi5ZO9gOYnkCHhu3QUK9IB88tr5vZqS_ql4zesEole8So6LlNWW6plyuWC2fVGdMSF4rqW-flpoyVjeS3z6vXqR0RynVkumz6vceR-yy-4Fkh_1cquBJGMjW5RggosdENpBhPP3CntgT2c8pg_NgRyTg-2LN6eHxfruu0zxNIeZCbl33DUeyBR8miNl1Y2nkPPkKGSOBTHYhHMkNHieMkOeIL6tnA4wJX_29z6svlx9uNp_q688frzbr67pbcZ3rllsmsR94OzDkq1a20FBsBhC6Q0ut1NIqJTQfrO2FFgp7EEpbxkAJ24rmvHqz9J1i-D5jyuYuzNGXkYZzIVaaN1QW6mKhDjCicX4IOUJXTo9H1wWPgyv_a6EUparRqghvHwmFyfgzH2BOyVztd49ZvrBdDClFHMwU3RHiyTBq7uM0S5ymxGke4jT3GzWLlArsDxj_7f0f6w-7ZaPP</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Niakan, Mahsa</creator><creator>Asadi, Zahra</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20190801</creationdate><title>Selective Reduction of Nitroarenes Catalyzed by Sustainable and Reusable DNA-supported Nickel Nanoparticles in Water at Room Temperature</title><author>Niakan, Mahsa ; Asadi, Zahra</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-62b17edf26f1e24676a30e3fa59ceb0b797b88592fbbd5958eda589b11a85b653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Amines</topic><topic>Biodegradability</topic><topic>Borohydrides</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical tests and reagents</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Deoxyribonucleic acid</topic><topic>DNA</topic><topic>Emission analysis</topic><topic>Energy transmission</topic><topic>Fourier transforms</topic><topic>Green market</topic><topic>Inductively coupled plasma</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared analysis</topic><topic>Nanoparticles</topic><topic>Nickel</topic><topic>Optical emission spectroscopy</topic><topic>Organometallic Chemistry</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Reducing agents</topic><topic>Reduction</topic><topic>Room temperature</topic><topic>Selectivity</topic><topic>Spectroscopic analysis</topic><topic>Spectrum analysis</topic><topic>Substrates</topic><topic>Transmission electron microscopy</topic><topic>X ray analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Niakan, Mahsa</creatorcontrib><creatorcontrib>Asadi, Zahra</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Niakan, Mahsa</au><au>Asadi, Zahra</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective Reduction of Nitroarenes Catalyzed by Sustainable and Reusable DNA-supported Nickel Nanoparticles in Water at Room Temperature</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2019-08-01</date><risdate>2019</risdate><volume>149</volume><issue>8</issue><spage>2234</spage><epage>2246</epage><pages>2234-2246</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>In this research, a novel, biodegradable and environmentally friendly catalyst composed of nickel nanoparticles supported on DNA was prepared and fully characterized by Fourier transform infrared spectroscopy, high resolution transmission electron microscopy, energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, UV–vis spectroscopy, inductively coupled plasma optical emission spectroscopy, and elemental analysis. The catalyst exhibited remarkable catalytic activity and chemoselectivity for the reduction of various substituted nitroarenes with sodium borohydride (NaBH
4
) as the source of inexpensive hydride in water at room temperature. High turnover frequency and selectivity were observed for the reduction of all tested substrates. Interestingly, the catalyst could be recovered conveniently for multiple recycling reactions with sustained activity. Furthermore, nearly no nickel species was leached out from the catalyst during the course of reaction, proving the true heterogeneity in the present catalytic protocol.
Graphical Abstract
The reduction of various nitroaromatic compounds into their corresponding amines is achieved by DNA supported nickel nanoparticles with the sodium borohydride as the reducing agent in water at room temperature.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-019-02741-7</doi><tpages>13</tpages></addata></record> |
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| subjects | Amines Biodegradability Borohydrides Catalysis Catalysts Catalytic activity Chemical tests and reagents Chemistry Chemistry and Materials Science Deoxyribonucleic acid DNA Emission analysis Energy transmission Fourier transforms Green market Inductively coupled plasma Industrial Chemistry/Chemical Engineering Infrared analysis Nanoparticles Nickel Optical emission spectroscopy Organometallic Chemistry Photoelectrons Physical Chemistry Reducing agents Reduction Room temperature Selectivity Spectroscopic analysis Spectrum analysis Substrates Transmission electron microscopy X ray analysis |
| title | Selective Reduction of Nitroarenes Catalyzed by Sustainable and Reusable DNA-supported Nickel Nanoparticles in Water at Room Temperature |
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