Enhanced removal of prometryn using copper modified microcrystalline cellulose (Cu-MCC): optimization, isotherm, kinetics and regeneration studies
In this work, we incorporated Cu 2+ on to microcrystalline cellulose (MCC) powder by a simple synthesis method to produce a composite material (Cu-MCC) with its suitability in prometryn (Pr) adsorption tested from synthetic wastewater. Various characterization techniques were applied in studying the...
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| Veröffentlicht in: | Cellulose (London) 2019-07, Vol.26 (10), p.6241-6258 |
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| creator | Garba, Zaharaddeen N. Zhou, Weiming Lawan, Ibrahim Zhang, Mingxi Yuan, Zhanhui |
| description | In this work, we incorporated Cu
2+
on to microcrystalline cellulose (MCC) powder by a simple synthesis method to produce a composite material (Cu-MCC) with its suitability in prometryn (Pr) adsorption tested from synthetic wastewater. Various characterization techniques were applied in studying the prepared Cu-MCC with response surface methodology applied in order to study the influence of adsorbent dosage, solution pH and shaking speed, which suggested a quadratic model for the response (Pr percentage removal). The optimum adsorption conditions obtained were adsorbent dosage of 0.40 g, solution pH of 11 and shaking speed of 215 rpm with the model adequacy and significance validated by ANOVA. Langmuir and pseudo-second order were the most appropriate models in describing the generated equilibrium and kinetic data, giving rise to a monolayer adsorption capacity value of 97.80 mg/g at room temperature. The desorption of Pr on Cu-MCC was also probed depicting the adsorption capacity to be about 66.7% of its initial value after six sequential adsorption–desorption cycles. Overall, the prepared Cu-MCC was revealed to have great potential for being a good adsorbent in the removal of water contaminants such as Pr, based on the obtained results.
Graphic abstract |
| doi_str_mv | 10.1007/s10570-019-02531-9 |
| format | Article |
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2+
on to microcrystalline cellulose (MCC) powder by a simple synthesis method to produce a composite material (Cu-MCC) with its suitability in prometryn (Pr) adsorption tested from synthetic wastewater. Various characterization techniques were applied in studying the prepared Cu-MCC with response surface methodology applied in order to study the influence of adsorbent dosage, solution pH and shaking speed, which suggested a quadratic model for the response (Pr percentage removal). The optimum adsorption conditions obtained were adsorbent dosage of 0.40 g, solution pH of 11 and shaking speed of 215 rpm with the model adequacy and significance validated by ANOVA. Langmuir and pseudo-second order were the most appropriate models in describing the generated equilibrium and kinetic data, giving rise to a monolayer adsorption capacity value of 97.80 mg/g at room temperature. The desorption of Pr on Cu-MCC was also probed depicting the adsorption capacity to be about 66.7% of its initial value after six sequential adsorption–desorption cycles. Overall, the prepared Cu-MCC was revealed to have great potential for being a good adsorbent in the removal of water contaminants such as Pr, based on the obtained results.
Graphic abstract</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-019-02531-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Adequacy ; Adsorbents ; Adsorption ; Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composite materials ; Composites ; Contaminants ; Copper ; Crystalline cellulose ; Desorption ; Dosage ; Glass ; Natural Materials ; Optimization ; Organic Chemistry ; Original Research ; Physical Chemistry ; Polymer Sciences ; Regeneration ; Response surface methodology ; Shaking ; Sustainable Development ; Wastewater</subject><ispartof>Cellulose (London), 2019-07, Vol.26 (10), p.6241-6258</ispartof><rights>Springer Nature B.V. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><rights>Cellulose is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-8646bee667083a72ec08e65fcaeabb1031e5809b594ddf887586c8d6e1489dfb3</citedby><cites>FETCH-LOGICAL-c384t-8646bee667083a72ec08e65fcaeabb1031e5809b594ddf887586c8d6e1489dfb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-019-02531-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-019-02531-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Garba, Zaharaddeen N.</creatorcontrib><creatorcontrib>Zhou, Weiming</creatorcontrib><creatorcontrib>Lawan, Ibrahim</creatorcontrib><creatorcontrib>Zhang, Mingxi</creatorcontrib><creatorcontrib>Yuan, Zhanhui</creatorcontrib><title>Enhanced removal of prometryn using copper modified microcrystalline cellulose (Cu-MCC): optimization, isotherm, kinetics and regeneration studies</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>In this work, we incorporated Cu
2+
on to microcrystalline cellulose (MCC) powder by a simple synthesis method to produce a composite material (Cu-MCC) with its suitability in prometryn (Pr) adsorption tested from synthetic wastewater. Various characterization techniques were applied in studying the prepared Cu-MCC with response surface methodology applied in order to study the influence of adsorbent dosage, solution pH and shaking speed, which suggested a quadratic model for the response (Pr percentage removal). The optimum adsorption conditions obtained were adsorbent dosage of 0.40 g, solution pH of 11 and shaking speed of 215 rpm with the model adequacy and significance validated by ANOVA. Langmuir and pseudo-second order were the most appropriate models in describing the generated equilibrium and kinetic data, giving rise to a monolayer adsorption capacity value of 97.80 mg/g at room temperature. The desorption of Pr on Cu-MCC was also probed depicting the adsorption capacity to be about 66.7% of its initial value after six sequential adsorption–desorption cycles. Overall, the prepared Cu-MCC was revealed to have great potential for being a good adsorbent in the removal of water contaminants such as Pr, based on the obtained results.
Graphic abstract</description><subject>Adequacy</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composite materials</subject><subject>Composites</subject><subject>Contaminants</subject><subject>Copper</subject><subject>Crystalline cellulose</subject><subject>Desorption</subject><subject>Dosage</subject><subject>Glass</subject><subject>Natural Materials</subject><subject>Optimization</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Regeneration</subject><subject>Response surface methodology</subject><subject>Shaking</subject><subject>Sustainable Development</subject><subject>Wastewater</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kc1u1TAQhSMEEpfCC7CyxAakBsZ2HNvsUFR-pKJuisTOcpzJrUtiB9tBun2MPjG5vUjsuprFfOcczZyqek3hPQWQHzIFIaEGqmtggtNaP6l2VEhWK8V-Pq12oNvjiuvn1YucbwFAS0Z31f1FuLHB4UASzvGPnUgcyZLijCUdAlmzD3vi4rJgInMc_Og3dPYuRZcOudhp8gGJw2lap5iRvO3W-nvXvftI4lL87O9s8TGcE59jucE0n5Nfm6B4l4kNx9A9BkwPEMllHTzml9Wz0U4ZX_2bZ9WPzxfX3df68urLt-7TZe24akqt2qbtEdtWguJWMnSgsBWjs2j7ngKnKBToXuhmGEalpFCtU0OLtFF6GHt-Vr05-W7n_l4xF3Mb1xS2SMOYEI0GCvpximvZcMrkRrETtT0m54SjWZKfbToYCubYkDk1ZLaGzEND5mjNT6K8wWGP6b_1I6q_G-mWRQ</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Garba, Zaharaddeen N.</creator><creator>Zhou, Weiming</creator><creator>Lawan, Ibrahim</creator><creator>Zhang, Mingxi</creator><creator>Yuan, Zhanhui</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20190701</creationdate><title>Enhanced removal of prometryn using copper modified microcrystalline cellulose (Cu-MCC): optimization, isotherm, kinetics and regeneration studies</title><author>Garba, Zaharaddeen N. ; Zhou, Weiming ; Lawan, Ibrahim ; Zhang, Mingxi ; Yuan, Zhanhui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-8646bee667083a72ec08e65fcaeabb1031e5809b594ddf887586c8d6e1489dfb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Adequacy</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Bioorganic Chemistry</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composite materials</topic><topic>Composites</topic><topic>Contaminants</topic><topic>Copper</topic><topic>Crystalline cellulose</topic><topic>Desorption</topic><topic>Dosage</topic><topic>Glass</topic><topic>Natural Materials</topic><topic>Optimization</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Regeneration</topic><topic>Response surface methodology</topic><topic>Shaking</topic><topic>Sustainable Development</topic><topic>Wastewater</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Garba, Zaharaddeen N.</creatorcontrib><creatorcontrib>Zhou, Weiming</creatorcontrib><creatorcontrib>Lawan, Ibrahim</creatorcontrib><creatorcontrib>Zhang, Mingxi</creatorcontrib><creatorcontrib>Yuan, Zhanhui</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Garba, Zaharaddeen N.</au><au>Zhou, Weiming</au><au>Lawan, Ibrahim</au><au>Zhang, Mingxi</au><au>Yuan, Zhanhui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced removal of prometryn using copper modified microcrystalline cellulose (Cu-MCC): optimization, isotherm, kinetics and regeneration studies</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2019-07-01</date><risdate>2019</risdate><volume>26</volume><issue>10</issue><spage>6241</spage><epage>6258</epage><pages>6241-6258</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>In this work, we incorporated Cu
2+
on to microcrystalline cellulose (MCC) powder by a simple synthesis method to produce a composite material (Cu-MCC) with its suitability in prometryn (Pr) adsorption tested from synthetic wastewater. Various characterization techniques were applied in studying the prepared Cu-MCC with response surface methodology applied in order to study the influence of adsorbent dosage, solution pH and shaking speed, which suggested a quadratic model for the response (Pr percentage removal). The optimum adsorption conditions obtained were adsorbent dosage of 0.40 g, solution pH of 11 and shaking speed of 215 rpm with the model adequacy and significance validated by ANOVA. Langmuir and pseudo-second order were the most appropriate models in describing the generated equilibrium and kinetic data, giving rise to a monolayer adsorption capacity value of 97.80 mg/g at room temperature. The desorption of Pr on Cu-MCC was also probed depicting the adsorption capacity to be about 66.7% of its initial value after six sequential adsorption–desorption cycles. Overall, the prepared Cu-MCC was revealed to have great potential for being a good adsorbent in the removal of water contaminants such as Pr, based on the obtained results.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-019-02531-9</doi><tpages>18</tpages></addata></record> |
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| subjects | Adequacy Adsorbents Adsorption Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Composite materials Composites Contaminants Copper Crystalline cellulose Desorption Dosage Glass Natural Materials Optimization Organic Chemistry Original Research Physical Chemistry Polymer Sciences Regeneration Response surface methodology Shaking Sustainable Development Wastewater |
| title | Enhanced removal of prometryn using copper modified microcrystalline cellulose (Cu-MCC): optimization, isotherm, kinetics and regeneration studies |
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