Mont-K10 Supported Fe(II) Schiff-Base Complex as an Efficient Catalyst for Hydrogenation of Ketones
A new Fe(II) Schiff base complex anchored on mont-K10 (Fe@imine-mont-K10) was synthesized and extensively characterized by FTIR, powder X-ray diffraction, SEM–EDX, TEM, ESR, X-ray photoelectron spectroscopy (XPS), BET surface area measurement, solid state 29 Si NMR and ICP-AES analysis. The catalyti...
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| Veröffentlicht in: | Catalysis letters 2019-08, Vol.149 (8), p.2142-2157 |
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| creator | Sultana, Samim Borah, Geetika Gogoi, Pradip. K. |
| description | A new Fe(II) Schiff base complex anchored on mont-K10 (Fe@imine-mont-K10) was synthesized and extensively characterized by FTIR, powder X-ray diffraction, SEM–EDX, TEM, ESR, X-ray photoelectron spectroscopy (XPS), BET surface area measurement, solid state
29
Si NMR and ICP-AES analysis. The catalytic activity of the complex was investigated for hydrogenation of ketones. The results indicated that it exhibited good catalytic activity for hydrogenation of aromatic as well as aliphatic ketones in
i
-PrOH/CH
3
CN (1:1) using Na-
i
-OPr as base at 80 °C resulting in moderate to excellent isolated yields (51–99%) of their corresponding products. The catalyst shows good reusability.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-019-02810-x |
| format | Article |
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29
Si NMR and ICP-AES analysis. The catalytic activity of the complex was investigated for hydrogenation of ketones. The results indicated that it exhibited good catalytic activity for hydrogenation of aromatic as well as aliphatic ketones in
i
-PrOH/CH
3
CN (1:1) using Na-
i
-OPr as base at 80 °C resulting in moderate to excellent isolated yields (51–99%) of their corresponding products. The catalyst shows good reusability.
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29
Si NMR and ICP-AES analysis. The catalytic activity of the complex was investigated for hydrogenation of ketones. The results indicated that it exhibited good catalytic activity for hydrogenation of aromatic as well as aliphatic ketones in
i
-PrOH/CH
3
CN (1:1) using Na-
i
-OPr as base at 80 °C resulting in moderate to excellent isolated yields (51–99%) of their corresponding products. The catalyst shows good reusability.
Graphical Abstract</description><subject>Acetone</subject><subject>Aliphatic compounds</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Emission analysis</subject><subject>Hydrogenation</subject><subject>Imines</subject><subject>Inductively coupled plasma</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ketones</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organometallic Chemistry</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Schiff bases</subject><subject>X ray photoelectron spectroscopy</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><subject>X-ray spectroscopy</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kD1PwzAQhiMEEuXjDzBZYoHBxXbiOB6haqECxECHbpaTnEuq1g62K7X_HkOQ2NANdzq9z328WXZFyZgSIu4CJbxkmFCJCasowfujbES5YLgScnmcakIpzgVbnmZnIawJIVJQOcqaV2cjfqYEve_63vkILZrBzXx-i96bj84Y_KADoInb9hvYIx2QtmhqTNd0YCOa6Kg3hxCRcR49HVrvVmB17JxFzqBniM5CuMhOjN4EuPzN59liNl1MnvDL2-N8cv-Cm1zyiGUrBBO8Zq3hoOuSllJSAyCqvCmMZAW0tS5rXhCq24ILyfIE6JZyzVmt8_Psehjbe_e5gxDV2u28TRsVY5wXMv1cJdV4UK30BlRnjYteNyla2HZNOtd0qX_Pq4qQKpdlAtgANN6F4MGo3ndb7Q-KEvVtvhrMV8l89WO-2icoH6CQxHYF_u-Wf6gvApOGnw</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Sultana, Samim</creator><creator>Borah, Geetika</creator><creator>Gogoi, Pradip. 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K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c395t-9d77275b2df5eab616991fee783c4f924edba6b5401ad457923772ad15a52ba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acetone</topic><topic>Aliphatic compounds</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Emission analysis</topic><topic>Hydrogenation</topic><topic>Imines</topic><topic>Inductively coupled plasma</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ketones</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organometallic Chemistry</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Schiff bases</topic><topic>X ray photoelectron spectroscopy</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><topic>X-ray spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sultana, Samim</creatorcontrib><creatorcontrib>Borah, Geetika</creatorcontrib><creatorcontrib>Gogoi, Pradip. K.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sultana, Samim</au><au>Borah, Geetika</au><au>Gogoi, Pradip. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mont-K10 Supported Fe(II) Schiff-Base Complex as an Efficient Catalyst for Hydrogenation of Ketones</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2019-08-01</date><risdate>2019</risdate><volume>149</volume><issue>8</issue><spage>2142</spage><epage>2157</epage><pages>2142-2157</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>A new Fe(II) Schiff base complex anchored on mont-K10 (Fe@imine-mont-K10) was synthesized and extensively characterized by FTIR, powder X-ray diffraction, SEM–EDX, TEM, ESR, X-ray photoelectron spectroscopy (XPS), BET surface area measurement, solid state
29
Si NMR and ICP-AES analysis. The catalytic activity of the complex was investigated for hydrogenation of ketones. The results indicated that it exhibited good catalytic activity for hydrogenation of aromatic as well as aliphatic ketones in
i
-PrOH/CH
3
CN (1:1) using Na-
i
-OPr as base at 80 °C resulting in moderate to excellent isolated yields (51–99%) of their corresponding products. The catalyst shows good reusability.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-019-02810-x</doi><tpages>16</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Acetone Aliphatic compounds Catalysis Catalysts Catalytic activity Chemistry Chemistry and Materials Science Emission analysis Hydrogenation Imines Inductively coupled plasma Industrial Chemistry/Chemical Engineering Ketones NMR Nuclear magnetic resonance Organometallic Chemistry Photoelectrons Physical Chemistry Schiff bases X ray photoelectron spectroscopy X ray powder diffraction X-ray diffraction X-ray spectroscopy |
| title | Mont-K10 Supported Fe(II) Schiff-Base Complex as an Efficient Catalyst for Hydrogenation of Ketones |
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