Polyamine-decorated mesocellular silica foam nanocomposites: Effect of the reaction parameters on the grafted polymer content and silica mesostructure
Polyvinylamine-coated mesocellular silica foam (MCF) was synthesized by grafting poly(n-vinylformamide) (PNVF) followed by the acid hydrolysis of the formamide groups with hydrochloric acid (HCl) and subsequent neutralization with sodium hydroxide (NaOH). In order to graft PNVF, MCF silica was previ...
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creator | Meléndez-Ortiz, H. Iván Puente-Urbina, Bertha Castruita-de León, Griselda Saucedo-Salazar, Esmeralda Mercado-Silva, Jesús Alfonso García-Cerda, Luis Alfonso |
description | Polyvinylamine-coated mesocellular silica foam (MCF) was synthesized by grafting poly(n-vinylformamide) (PNVF) followed by the acid hydrolysis of the formamide groups with hydrochloric acid (HCl) and subsequent neutralization with sodium hydroxide (NaOH). In order to graft PNVF, MCF silica was previously functionalized with the coupling agent vinyltrimehtoxysilane (VTMS). The PNVF content in the hybrid material was tailored by varying some reaction parameters such as monomer concentration, reaction time, and temperature. The grafted polymer content was determined by thermogravimetric analysis (TGA) and ranged from 27% to 50%. Additionally, small-angle X-ray scattering (SAXS), infrared spectroscopy (FT-IR), nitrogen adsorption–desorption analyses, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques confirmed the grafting of PNVF onto MCF. The N
2
adsorption–desorption studies showed that the textural properties of the pristine MCF decreased as the amount of grafted PNVF increased confirming the deposition of polymer into silica. However, according to SAXS, SEM, and TEM studies, the mesostructure of MCF was maintained even after acid hydrolysis of PNVF and its subsequent neutralization to obtain PVAm.
Highlights
Amine polymer/silica foam hybrid material was obtained.
Covalent grafting of PNVF onto mesocellular silica foam (MCF).
The content of the grafted PNVF was tailored by varying polymerization conditions.
Grafted PNVF turns into PVAm by acid-catalyzed hydrolysis.
Acid hydrolysis of PNVF does not affect the morphology of MCF. |
doi_str_mv | 10.1007/s10971-019-05070-8 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2255243984</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2255243984</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-45b00190d08e68dc2bb6711e8c5b0455e2136d327ea9b772b0935e64f2f136a33</originalsourceid><addsrcrecordid>eNp9UM1O3DAQthBILAsvwMlSz27Hdhwn3CpEoRJSe2jPluOMISixU9s58CI8b71dqt56Go2-v5mPkGsOHzmA_pQ59Joz4D0DBRpYd0J2XGnJmq5pT8kOetGxCuhzcpHzCwCohusdefse51e7TAHZiC4mW3CkC-bocJ632Saap3lylvpoFxpsiC4ua8xTwXxD77xHV2j0tDwjTWhdmWKgq012wYIp07odoKdk_cF5rWkLJupiKBgKtWH8G3AIzSVtrmwJL8mZt3PGq_e5Jz-_3P24fWCP3-6_3n5-ZE6qtrBGDVB_hhE6bLvRiWFoNefYuQo0SqHgsh2l0Gj7QWsxQC8Vto0XvgJWyj35cPRdU_y1YS7mJW4p1EgjhFKikX3XVJY4slyKOSf0Zk3TYtOr4WAO_Ztj_6beYv70b7oqkkdRruTwhOmf9X9UvwHY6Iug</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2255243984</pqid></control><display><type>article</type><title>Polyamine-decorated mesocellular silica foam nanocomposites: Effect of the reaction parameters on the grafted polymer content and silica mesostructure</title><source>SpringerNature Journals</source><creator>Meléndez-Ortiz, H. Iván ; Puente-Urbina, Bertha ; Castruita-de León, Griselda ; Saucedo-Salazar, Esmeralda ; Mercado-Silva, Jesús Alfonso ; García-Cerda, Luis Alfonso</creator><creatorcontrib>Meléndez-Ortiz, H. Iván ; Puente-Urbina, Bertha ; Castruita-de León, Griselda ; Saucedo-Salazar, Esmeralda ; Mercado-Silva, Jesús Alfonso ; García-Cerda, Luis Alfonso</creatorcontrib><description>Polyvinylamine-coated mesocellular silica foam (MCF) was synthesized by grafting poly(n-vinylformamide) (PNVF) followed by the acid hydrolysis of the formamide groups with hydrochloric acid (HCl) and subsequent neutralization with sodium hydroxide (NaOH). In order to graft PNVF, MCF silica was previously functionalized with the coupling agent vinyltrimehtoxysilane (VTMS). The PNVF content in the hybrid material was tailored by varying some reaction parameters such as monomer concentration, reaction time, and temperature. The grafted polymer content was determined by thermogravimetric analysis (TGA) and ranged from 27% to 50%. Additionally, small-angle X-ray scattering (SAXS), infrared spectroscopy (FT-IR), nitrogen adsorption–desorption analyses, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques confirmed the grafting of PNVF onto MCF. The N
2
adsorption–desorption studies showed that the textural properties of the pristine MCF decreased as the amount of grafted PNVF increased confirming the deposition of polymer into silica. However, according to SAXS, SEM, and TEM studies, the mesostructure of MCF was maintained even after acid hydrolysis of PNVF and its subsequent neutralization to obtain PVAm.
Highlights
Amine polymer/silica foam hybrid material was obtained.
Covalent grafting of PNVF onto mesocellular silica foam (MCF).
The content of the grafted PNVF was tailored by varying polymerization conditions.
Grafted PNVF turns into PVAm by acid-catalyzed hydrolysis.
Acid hydrolysis of PNVF does not affect the morphology of MCF.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-019-05070-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Ceramics ; Chemistry and Materials Science ; Composites ; Coupling agents ; Desorption ; Glass ; Grafting ; Hydrochloric acid ; Hydrolysis ; Infrared analysis ; Infrared spectroscopy ; Inorganic Chemistry ; Materials Science ; Morphology ; Nanocomposites ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Original Paper: Sol-gel and hybrid materials with surface modification for applications ; Parameters ; Polymers ; Reaction time ; Scanning electron microscopy ; Silicon dioxide ; Small angle X ray scattering ; Sodium hydroxide ; Thermogravimetric analysis ; Transmission electron microscopy</subject><ispartof>Journal of sol-gel science and technology, 2020-04, Vol.94 (1), p.118-126</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-45b00190d08e68dc2bb6711e8c5b0455e2136d327ea9b772b0935e64f2f136a33</citedby><cites>FETCH-LOGICAL-c356t-45b00190d08e68dc2bb6711e8c5b0455e2136d327ea9b772b0935e64f2f136a33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-019-05070-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-019-05070-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Meléndez-Ortiz, H. Iván</creatorcontrib><creatorcontrib>Puente-Urbina, Bertha</creatorcontrib><creatorcontrib>Castruita-de León, Griselda</creatorcontrib><creatorcontrib>Saucedo-Salazar, Esmeralda</creatorcontrib><creatorcontrib>Mercado-Silva, Jesús Alfonso</creatorcontrib><creatorcontrib>García-Cerda, Luis Alfonso</creatorcontrib><title>Polyamine-decorated mesocellular silica foam nanocomposites: Effect of the reaction parameters on the grafted polymer content and silica mesostructure</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>Polyvinylamine-coated mesocellular silica foam (MCF) was synthesized by grafting poly(n-vinylformamide) (PNVF) followed by the acid hydrolysis of the formamide groups with hydrochloric acid (HCl) and subsequent neutralization with sodium hydroxide (NaOH). In order to graft PNVF, MCF silica was previously functionalized with the coupling agent vinyltrimehtoxysilane (VTMS). The PNVF content in the hybrid material was tailored by varying some reaction parameters such as monomer concentration, reaction time, and temperature. The grafted polymer content was determined by thermogravimetric analysis (TGA) and ranged from 27% to 50%. Additionally, small-angle X-ray scattering (SAXS), infrared spectroscopy (FT-IR), nitrogen adsorption–desorption analyses, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques confirmed the grafting of PNVF onto MCF. The N
2
adsorption–desorption studies showed that the textural properties of the pristine MCF decreased as the amount of grafted PNVF increased confirming the deposition of polymer into silica. However, according to SAXS, SEM, and TEM studies, the mesostructure of MCF was maintained even after acid hydrolysis of PNVF and its subsequent neutralization to obtain PVAm.
Highlights
Amine polymer/silica foam hybrid material was obtained.
Covalent grafting of PNVF onto mesocellular silica foam (MCF).
The content of the grafted PNVF was tailored by varying polymerization conditions.
Grafted PNVF turns into PVAm by acid-catalyzed hydrolysis.
Acid hydrolysis of PNVF does not affect the morphology of MCF.</description><subject>Adsorption</subject><subject>Ceramics</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Coupling agents</subject><subject>Desorption</subject><subject>Glass</subject><subject>Grafting</subject><subject>Hydrochloric acid</subject><subject>Hydrolysis</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper: Sol-gel and hybrid materials with surface modification for applications</subject><subject>Parameters</subject><subject>Polymers</subject><subject>Reaction time</subject><subject>Scanning electron microscopy</subject><subject>Silicon dioxide</subject><subject>Small angle X ray scattering</subject><subject>Sodium hydroxide</subject><subject>Thermogravimetric analysis</subject><subject>Transmission electron microscopy</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9UM1O3DAQthBILAsvwMlSz27Hdhwn3CpEoRJSe2jPluOMISixU9s58CI8b71dqt56Go2-v5mPkGsOHzmA_pQ59Joz4D0DBRpYd0J2XGnJmq5pT8kOetGxCuhzcpHzCwCohusdefse51e7TAHZiC4mW3CkC-bocJ632Saap3lylvpoFxpsiC4ua8xTwXxD77xHV2j0tDwjTWhdmWKgq012wYIp07odoKdk_cF5rWkLJupiKBgKtWH8G3AIzSVtrmwJL8mZt3PGq_e5Jz-_3P24fWCP3-6_3n5-ZE6qtrBGDVB_hhE6bLvRiWFoNefYuQo0SqHgsh2l0Gj7QWsxQC8Vto0XvgJWyj35cPRdU_y1YS7mJW4p1EgjhFKikX3XVJY4slyKOSf0Zk3TYtOr4WAO_Ztj_6beYv70b7oqkkdRruTwhOmf9X9UvwHY6Iug</recordid><startdate>20200401</startdate><enddate>20200401</enddate><creator>Meléndez-Ortiz, H. Iván</creator><creator>Puente-Urbina, Bertha</creator><creator>Castruita-de León, Griselda</creator><creator>Saucedo-Salazar, Esmeralda</creator><creator>Mercado-Silva, Jesús Alfonso</creator><creator>García-Cerda, Luis Alfonso</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20200401</creationdate><title>Polyamine-decorated mesocellular silica foam nanocomposites: Effect of the reaction parameters on the grafted polymer content and silica mesostructure</title><author>Meléndez-Ortiz, H. Iván ; Puente-Urbina, Bertha ; Castruita-de León, Griselda ; Saucedo-Salazar, Esmeralda ; Mercado-Silva, Jesús Alfonso ; García-Cerda, Luis Alfonso</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-45b00190d08e68dc2bb6711e8c5b0455e2136d327ea9b772b0935e64f2f136a33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Ceramics</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Coupling agents</topic><topic>Desorption</topic><topic>Glass</topic><topic>Grafting</topic><topic>Hydrochloric acid</topic><topic>Hydrolysis</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper: Sol-gel and hybrid materials with surface modification for applications</topic><topic>Parameters</topic><topic>Polymers</topic><topic>Reaction time</topic><topic>Scanning electron microscopy</topic><topic>Silicon dioxide</topic><topic>Small angle X ray scattering</topic><topic>Sodium hydroxide</topic><topic>Thermogravimetric analysis</topic><topic>Transmission electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Meléndez-Ortiz, H. Iván</creatorcontrib><creatorcontrib>Puente-Urbina, Bertha</creatorcontrib><creatorcontrib>Castruita-de León, Griselda</creatorcontrib><creatorcontrib>Saucedo-Salazar, Esmeralda</creatorcontrib><creatorcontrib>Mercado-Silva, Jesús Alfonso</creatorcontrib><creatorcontrib>García-Cerda, Luis Alfonso</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Meléndez-Ortiz, H. Iván</au><au>Puente-Urbina, Bertha</au><au>Castruita-de León, Griselda</au><au>Saucedo-Salazar, Esmeralda</au><au>Mercado-Silva, Jesús Alfonso</au><au>García-Cerda, Luis Alfonso</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polyamine-decorated mesocellular silica foam nanocomposites: Effect of the reaction parameters on the grafted polymer content and silica mesostructure</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2020-04-01</date><risdate>2020</risdate><volume>94</volume><issue>1</issue><spage>118</spage><epage>126</epage><pages>118-126</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>Polyvinylamine-coated mesocellular silica foam (MCF) was synthesized by grafting poly(n-vinylformamide) (PNVF) followed by the acid hydrolysis of the formamide groups with hydrochloric acid (HCl) and subsequent neutralization with sodium hydroxide (NaOH). In order to graft PNVF, MCF silica was previously functionalized with the coupling agent vinyltrimehtoxysilane (VTMS). The PNVF content in the hybrid material was tailored by varying some reaction parameters such as monomer concentration, reaction time, and temperature. The grafted polymer content was determined by thermogravimetric analysis (TGA) and ranged from 27% to 50%. Additionally, small-angle X-ray scattering (SAXS), infrared spectroscopy (FT-IR), nitrogen adsorption–desorption analyses, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques confirmed the grafting of PNVF onto MCF. The N
2
adsorption–desorption studies showed that the textural properties of the pristine MCF decreased as the amount of grafted PNVF increased confirming the deposition of polymer into silica. However, according to SAXS, SEM, and TEM studies, the mesostructure of MCF was maintained even after acid hydrolysis of PNVF and its subsequent neutralization to obtain PVAm.
Highlights
Amine polymer/silica foam hybrid material was obtained.
Covalent grafting of PNVF onto mesocellular silica foam (MCF).
The content of the grafted PNVF was tailored by varying polymerization conditions.
Grafted PNVF turns into PVAm by acid-catalyzed hydrolysis.
Acid hydrolysis of PNVF does not affect the morphology of MCF.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-019-05070-8</doi><tpages>9</tpages></addata></record> |
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subjects | Adsorption Ceramics Chemistry and Materials Science Composites Coupling agents Desorption Glass Grafting Hydrochloric acid Hydrolysis Infrared analysis Infrared spectroscopy Inorganic Chemistry Materials Science Morphology Nanocomposites Nanotechnology Natural Materials Optical and Electronic Materials Original Paper: Sol-gel and hybrid materials with surface modification for applications Parameters Polymers Reaction time Scanning electron microscopy Silicon dioxide Small angle X ray scattering Sodium hydroxide Thermogravimetric analysis Transmission electron microscopy |
title | Polyamine-decorated mesocellular silica foam nanocomposites: Effect of the reaction parameters on the grafted polymer content and silica mesostructure |
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