Nitrosylsulfuric acid as a tandem reagent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes

It was demonstrated that nitrosylsulfuric acid can be successfully used as a tandem nitrosating and oxidizing agent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes. The reaction proceeds highly regioselectively in the case of symmetric diarylcyclopropanes. The mixtures of regio...

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Veröffentlicht in:	Russian chemical bulletin 2019-06, Vol.68 (6), p.1200-1203
Hauptverfasser:	Bondarenko, O. B., Komarov, A. I., Karetnikov, G. L., Nikolaeva, S. N., Zyk, N. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Full Article Inorganic Chemistry Organic Chemistry Oxidation Oxidizing agents Reagents
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description	It was demonstrated that nitrosylsulfuric acid can be successfully used as a tandem nitrosating and oxidizing agent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes. The reaction proceeds highly regioselectively in the case of symmetric diarylcyclopropanes. The mixtures of regioisomeric 3,5-diarylisoxazoles were obtained from non-symmetric 1,2-diarylcyclopropanes.
doi_str_mv	10.1007/s11172-019-2540-1
format	Article
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title	Nitrosylsulfuric acid as a tandem reagent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes
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