Synthesis of aluminophosphate xerogels by non-hydrolytic sol–gel condensation of EtAlCl2 with trialkylphosphates

We have investigated the preparation of high-surface-area mesoporous aluminophosphates by non-hydrolytic sol–gel method based on reactions of EtAlCl 2 with trialkylesters of phosphoric acid (OP(OR) 3 , R = Me, Et, i Pr, n Bu, in dry organic solvents. The condensations proceed by alkylchloride elimin...

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Veröffentlicht in:	Journal of sol-gel science and technology 2019-08, Vol.91 (2), p.385-398
Hauptverfasser:	Podhorsky, Jan, Chyba, Jan, Pinkas, Jiri, Moravec, Zdenek
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum phosphate Ceramics Chemistry and Materials Science Composites Gels Glass hybrids and solution chemistries Inorganic Chemistry Materials Science Nanotechnology Natural Materials NMR spectroscopy Optical and Electronic Materials Original Paper: Sol–gel Phosphoric acid Porosity Roasting Sol-gel processes Xerogels
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