Efficient, hysteresis free, inverted planar flexible perovskite solar cells via perovskite engineering and stability in cylindrical encapsulation
A p–i–n type flexible perovskite solar cell (PSC) employing PEDOT:PSS as a hole transport material was fabricated implementing a synergistic approach to tune the composition and morphology of perovskite films. This was accomplished by the optimization of methylammonium–formamidinium double-cation pe...
Gespeichert in:
| Veröffentlicht in: | Sustainable energy & fuels 2019, Vol.3 (7), p.1739-1748 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1748 |
|---|---|
| container_issue | 7 |
| container_start_page | 1739 |
| container_title | Sustainable energy & fuels |
| container_volume | 3 |
| creator | Pandey, Manish Kapil, Gaurav Sakamoto, Kazuhiko Hirotani, Daisuke Kamrudin, Muhammad Akmal Wang, Zhen Hamada, Kengo Nomura, Daishiro Kang, Hyo-Gyoung Nagayoshi, Hideaki Nakamura, Masaki Hayashi, Masahiro Nomura, Takatoshi Hayase, Shuzi |
| description | A p–i–n type flexible perovskite solar cell (PSC) employing PEDOT:PSS as a hole transport material was fabricated implementing a synergistic approach to tune the composition and morphology of perovskite films. This was accomplished by the optimization of methylammonium–formamidinium double-cation perovskite, Pb(SCN)
2
additive and different anti-solvents to make hysteresis-free flexible PSCs. The PSCs reported exhibit a power conversion efficiency (PCE) of 16.13% with excellent mechanical stability, retaining >90% of the PCE after 1000 bending cycles at a radius (
R
) of 6 mm. This PCE is amongst the highest reported values for flexible inverted PSCs fabricated on PEDOT:PSS. Although PSCs on rigid conducting glass substrates have been reported to exhibit >20% PCE, long-term stability is of great concern because of poor encapsulation. Solution processability of PSCs gives the freedom to develop them on flexible substrates, which is suitable for commercialization of PSCs. Herein, a novel encapsulation technology of sealing flexible PSCs inside cylindrical glass tubes (
R
= 8 mm) is being demonstrated. Encapsulated flexible devices retained 90% of the PCE after 6000 hours under ambient conditions. |
| doi_str_mv | 10.1039/C9SE00153K |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2246355168</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2246355168</sourcerecordid><originalsourceid>FETCH-LOGICAL-c259t-9bd904394db82a7431f5b51ac2338d77d38e43c0a01bef083e90136830d1b09e3</originalsourceid><addsrcrecordid>eNpNkM9KAzEYxIMoWGovPkHAm3T1S7Lbbo5S6h8seFDPSzb7pabG7JqkxX0M39iVCvY0A_NjBoaQcwZXDIS8XsjnJQArxOMRGXEhyyyXwI8P_CmZxLgBAM54zov5iHwvjbHaok9T-tbHhAGjjdQExCm1fochYUM7p7wK1Dj8srVD2mFod_HdJqSxdUOi0blId1YdRujX1iMG69dU-YbGpGrrbOqHYqp7Z30TrFZuALXq4tapZFt_Rk6MchEnfzomr7fLl8V9tnq6e1jcrDLNC5kyWTcSciHzpi65mueCmaIumNJciLKZzxtRYi40KGA1GigFSmBiVgpoWA0SxZhc7Hu70H5uMaZq026DHyYrzvOZKAo20GNyuad0aGMMaKou2A8V-opB9ft69f-6-AE6QndX</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2246355168</pqid></control><display><type>article</type><title>Efficient, hysteresis free, inverted planar flexible perovskite solar cells via perovskite engineering and stability in cylindrical encapsulation</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Pandey, Manish ; Kapil, Gaurav ; Sakamoto, Kazuhiko ; Hirotani, Daisuke ; Kamrudin, Muhammad Akmal ; Wang, Zhen ; Hamada, Kengo ; Nomura, Daishiro ; Kang, Hyo-Gyoung ; Nagayoshi, Hideaki ; Nakamura, Masaki ; Hayashi, Masahiro ; Nomura, Takatoshi ; Hayase, Shuzi</creator><creatorcontrib>Pandey, Manish ; Kapil, Gaurav ; Sakamoto, Kazuhiko ; Hirotani, Daisuke ; Kamrudin, Muhammad Akmal ; Wang, Zhen ; Hamada, Kengo ; Nomura, Daishiro ; Kang, Hyo-Gyoung ; Nagayoshi, Hideaki ; Nakamura, Masaki ; Hayashi, Masahiro ; Nomura, Takatoshi ; Hayase, Shuzi</creatorcontrib><description>A p–i–n type flexible perovskite solar cell (PSC) employing PEDOT:PSS as a hole transport material was fabricated implementing a synergistic approach to tune the composition and morphology of perovskite films. This was accomplished by the optimization of methylammonium–formamidinium double-cation perovskite, Pb(SCN)
2
additive and different anti-solvents to make hysteresis-free flexible PSCs. The PSCs reported exhibit a power conversion efficiency (PCE) of 16.13% with excellent mechanical stability, retaining >90% of the PCE after 1000 bending cycles at a radius (
R
) of 6 mm. This PCE is amongst the highest reported values for flexible inverted PSCs fabricated on PEDOT:PSS. Although PSCs on rigid conducting glass substrates have been reported to exhibit >20% PCE, long-term stability is of great concern because of poor encapsulation. Solution processability of PSCs gives the freedom to develop them on flexible substrates, which is suitable for commercialization of PSCs. Herein, a novel encapsulation technology of sealing flexible PSCs inside cylindrical glass tubes (
R
= 8 mm) is being demonstrated. Encapsulated flexible devices retained 90% of the PCE after 6000 hours under ambient conditions.</description><identifier>ISSN: 2398-4902</identifier><identifier>EISSN: 2398-4902</identifier><identifier>DOI: 10.1039/C9SE00153K</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Commercialization ; Encapsulation ; Energy conversion efficiency ; Glass substrates ; Hysteresis ; Morphology ; Optimization ; Perovskites ; Photovoltaic cells ; Solar cells ; Stability ; Substrates</subject><ispartof>Sustainable energy & fuels, 2019, Vol.3 (7), p.1739-1748</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-9bd904394db82a7431f5b51ac2338d77d38e43c0a01bef083e90136830d1b09e3</citedby><cites>FETCH-LOGICAL-c259t-9bd904394db82a7431f5b51ac2338d77d38e43c0a01bef083e90136830d1b09e3</cites><orcidid>0000-0003-0963-8097 ; 0000-0002-2256-5948</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,4010,27904,27905,27906</link.rule.ids></links><search><creatorcontrib>Pandey, Manish</creatorcontrib><creatorcontrib>Kapil, Gaurav</creatorcontrib><creatorcontrib>Sakamoto, Kazuhiko</creatorcontrib><creatorcontrib>Hirotani, Daisuke</creatorcontrib><creatorcontrib>Kamrudin, Muhammad Akmal</creatorcontrib><creatorcontrib>Wang, Zhen</creatorcontrib><creatorcontrib>Hamada, Kengo</creatorcontrib><creatorcontrib>Nomura, Daishiro</creatorcontrib><creatorcontrib>Kang, Hyo-Gyoung</creatorcontrib><creatorcontrib>Nagayoshi, Hideaki</creatorcontrib><creatorcontrib>Nakamura, Masaki</creatorcontrib><creatorcontrib>Hayashi, Masahiro</creatorcontrib><creatorcontrib>Nomura, Takatoshi</creatorcontrib><creatorcontrib>Hayase, Shuzi</creatorcontrib><title>Efficient, hysteresis free, inverted planar flexible perovskite solar cells via perovskite engineering and stability in cylindrical encapsulation</title><title>Sustainable energy & fuels</title><description>A p–i–n type flexible perovskite solar cell (PSC) employing PEDOT:PSS as a hole transport material was fabricated implementing a synergistic approach to tune the composition and morphology of perovskite films. This was accomplished by the optimization of methylammonium–formamidinium double-cation perovskite, Pb(SCN)
2
additive and different anti-solvents to make hysteresis-free flexible PSCs. The PSCs reported exhibit a power conversion efficiency (PCE) of 16.13% with excellent mechanical stability, retaining >90% of the PCE after 1000 bending cycles at a radius (
R
) of 6 mm. This PCE is amongst the highest reported values for flexible inverted PSCs fabricated on PEDOT:PSS. Although PSCs on rigid conducting glass substrates have been reported to exhibit >20% PCE, long-term stability is of great concern because of poor encapsulation. Solution processability of PSCs gives the freedom to develop them on flexible substrates, which is suitable for commercialization of PSCs. Herein, a novel encapsulation technology of sealing flexible PSCs inside cylindrical glass tubes (
R
= 8 mm) is being demonstrated. Encapsulated flexible devices retained 90% of the PCE after 6000 hours under ambient conditions.</description><subject>Commercialization</subject><subject>Encapsulation</subject><subject>Energy conversion efficiency</subject><subject>Glass substrates</subject><subject>Hysteresis</subject><subject>Morphology</subject><subject>Optimization</subject><subject>Perovskites</subject><subject>Photovoltaic cells</subject><subject>Solar cells</subject><subject>Stability</subject><subject>Substrates</subject><issn>2398-4902</issn><issn>2398-4902</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpNkM9KAzEYxIMoWGovPkHAm3T1S7Lbbo5S6h8seFDPSzb7pabG7JqkxX0M39iVCvY0A_NjBoaQcwZXDIS8XsjnJQArxOMRGXEhyyyXwI8P_CmZxLgBAM54zov5iHwvjbHaok9T-tbHhAGjjdQExCm1fochYUM7p7wK1Dj8srVD2mFod_HdJqSxdUOi0blId1YdRujX1iMG69dU-YbGpGrrbOqHYqp7Z30TrFZuALXq4tapZFt_Rk6MchEnfzomr7fLl8V9tnq6e1jcrDLNC5kyWTcSciHzpi65mueCmaIumNJciLKZzxtRYi40KGA1GigFSmBiVgpoWA0SxZhc7Hu70H5uMaZq026DHyYrzvOZKAo20GNyuad0aGMMaKou2A8V-opB9ft69f-6-AE6QndX</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Pandey, Manish</creator><creator>Kapil, Gaurav</creator><creator>Sakamoto, Kazuhiko</creator><creator>Hirotani, Daisuke</creator><creator>Kamrudin, Muhammad Akmal</creator><creator>Wang, Zhen</creator><creator>Hamada, Kengo</creator><creator>Nomura, Daishiro</creator><creator>Kang, Hyo-Gyoung</creator><creator>Nagayoshi, Hideaki</creator><creator>Nakamura, Masaki</creator><creator>Hayashi, Masahiro</creator><creator>Nomura, Takatoshi</creator><creator>Hayase, Shuzi</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7SP</scope><scope>7ST</scope><scope>7U6</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>L7M</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0003-0963-8097</orcidid><orcidid>https://orcid.org/0000-0002-2256-5948</orcidid></search><sort><creationdate>2019</creationdate><title>Efficient, hysteresis free, inverted planar flexible perovskite solar cells via perovskite engineering and stability in cylindrical encapsulation</title><author>Pandey, Manish ; Kapil, Gaurav ; Sakamoto, Kazuhiko ; Hirotani, Daisuke ; Kamrudin, Muhammad Akmal ; Wang, Zhen ; Hamada, Kengo ; Nomura, Daishiro ; Kang, Hyo-Gyoung ; Nagayoshi, Hideaki ; Nakamura, Masaki ; Hayashi, Masahiro ; Nomura, Takatoshi ; Hayase, Shuzi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-9bd904394db82a7431f5b51ac2338d77d38e43c0a01bef083e90136830d1b09e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Commercialization</topic><topic>Encapsulation</topic><topic>Energy conversion efficiency</topic><topic>Glass substrates</topic><topic>Hysteresis</topic><topic>Morphology</topic><topic>Optimization</topic><topic>Perovskites</topic><topic>Photovoltaic cells</topic><topic>Solar cells</topic><topic>Stability</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pandey, Manish</creatorcontrib><creatorcontrib>Kapil, Gaurav</creatorcontrib><creatorcontrib>Sakamoto, Kazuhiko</creatorcontrib><creatorcontrib>Hirotani, Daisuke</creatorcontrib><creatorcontrib>Kamrudin, Muhammad Akmal</creatorcontrib><creatorcontrib>Wang, Zhen</creatorcontrib><creatorcontrib>Hamada, Kengo</creatorcontrib><creatorcontrib>Nomura, Daishiro</creatorcontrib><creatorcontrib>Kang, Hyo-Gyoung</creatorcontrib><creatorcontrib>Nagayoshi, Hideaki</creatorcontrib><creatorcontrib>Nakamura, Masaki</creatorcontrib><creatorcontrib>Hayashi, Masahiro</creatorcontrib><creatorcontrib>Nomura, Takatoshi</creatorcontrib><creatorcontrib>Hayase, Shuzi</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Sustainable energy & fuels</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pandey, Manish</au><au>Kapil, Gaurav</au><au>Sakamoto, Kazuhiko</au><au>Hirotani, Daisuke</au><au>Kamrudin, Muhammad Akmal</au><au>Wang, Zhen</au><au>Hamada, Kengo</au><au>Nomura, Daishiro</au><au>Kang, Hyo-Gyoung</au><au>Nagayoshi, Hideaki</au><au>Nakamura, Masaki</au><au>Hayashi, Masahiro</au><au>Nomura, Takatoshi</au><au>Hayase, Shuzi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient, hysteresis free, inverted planar flexible perovskite solar cells via perovskite engineering and stability in cylindrical encapsulation</atitle><jtitle>Sustainable energy & fuels</jtitle><date>2019</date><risdate>2019</risdate><volume>3</volume><issue>7</issue><spage>1739</spage><epage>1748</epage><pages>1739-1748</pages><issn>2398-4902</issn><eissn>2398-4902</eissn><abstract>A p–i–n type flexible perovskite solar cell (PSC) employing PEDOT:PSS as a hole transport material was fabricated implementing a synergistic approach to tune the composition and morphology of perovskite films. This was accomplished by the optimization of methylammonium–formamidinium double-cation perovskite, Pb(SCN)
2
additive and different anti-solvents to make hysteresis-free flexible PSCs. The PSCs reported exhibit a power conversion efficiency (PCE) of 16.13% with excellent mechanical stability, retaining >90% of the PCE after 1000 bending cycles at a radius (
R
) of 6 mm. This PCE is amongst the highest reported values for flexible inverted PSCs fabricated on PEDOT:PSS. Although PSCs on rigid conducting glass substrates have been reported to exhibit >20% PCE, long-term stability is of great concern because of poor encapsulation. Solution processability of PSCs gives the freedom to develop them on flexible substrates, which is suitable for commercialization of PSCs. Herein, a novel encapsulation technology of sealing flexible PSCs inside cylindrical glass tubes (
R
= 8 mm) is being demonstrated. Encapsulated flexible devices retained 90% of the PCE after 6000 hours under ambient conditions.</abstract><cop>London</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C9SE00153K</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-0963-8097</orcidid><orcidid>https://orcid.org/0000-0002-2256-5948</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2398-4902 |
| ispartof | Sustainable energy & fuels, 2019, Vol.3 (7), p.1739-1748 |
| issn | 2398-4902 2398-4902 |
| language | eng |
| recordid | cdi_proquest_journals_2246355168 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Commercialization Encapsulation Energy conversion efficiency Glass substrates Hysteresis Morphology Optimization Perovskites Photovoltaic cells Solar cells Stability Substrates |
| title | Efficient, hysteresis free, inverted planar flexible perovskite solar cells via perovskite engineering and stability in cylindrical encapsulation |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T10%3A01%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Efficient,%20hysteresis%20free,%20inverted%20planar%20flexible%20perovskite%20solar%20cells%20via%20perovskite%20engineering%20and%20stability%20in%20cylindrical%20encapsulation&rft.jtitle=Sustainable%20energy%20&%20fuels&rft.au=Pandey,%20Manish&rft.date=2019&rft.volume=3&rft.issue=7&rft.spage=1739&rft.epage=1748&rft.pages=1739-1748&rft.issn=2398-4902&rft.eissn=2398-4902&rft_id=info:doi/10.1039/C9SE00153K&rft_dat=%3Cproquest_cross%3E2246355168%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2246355168&rft_id=info:pmid/&rfr_iscdi=true |