A novel method to improve phase transition of VO2 thermochromic films by Cs0.32WO3 nanoparticles

•The VO2/Cs0.32WO3 composite film were firstly prepared.•The Cs0.32WO3 shortened the phase transition response time of VO2 film.•The Cs0.32WO3 improves the solar-heat shielding ability of VO2 film.•The composite film can occur phase transition at 30 °C.•The composite film maintained good thermochrom...

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Veröffentlicht in:Materials letters 2019-08, Vol.249, p.95-98
Hauptverfasser: Xiao, Xiudi, Huan, Changmeng, Cheng, Haoliang, Lu, Yuan, Qi, Shuai, Zhan, Yongjun, Liu, Hongsha, Xu, Gang
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container_end_page 98
container_issue
container_start_page 95
container_title Materials letters
container_volume 249
creator Xiao, Xiudi
Huan, Changmeng
Cheng, Haoliang
Lu, Yuan
Qi, Shuai
Zhan, Yongjun
Liu, Hongsha
Xu, Gang
description •The VO2/Cs0.32WO3 composite film were firstly prepared.•The Cs0.32WO3 shortened the phase transition response time of VO2 film.•The Cs0.32WO3 improves the solar-heat shielding ability of VO2 film.•The composite film can occur phase transition at 30 °C.•The composite film maintained good thermochromic properties. The VO2/Cs0.32WO3 composite thermochromic films were designed to promote the practical application of the VO2-based smart windows. The addition of 0.9 wt% Cs0.32WO3 can significantly shorten the phase transition response time and improve the solar heat shielding capacity of VO2, while maintaining high visible light transmittance (49.6%) and good solar modulation ability (10.4%). Furthermore, the phase transition of the composite film can occur at indoor temperature of 30 °C, and the indoor temperature can be greatly reduced by 7.7 °C under the simulated solar irradiation. These excellent properties make the VO2/Cs0.32WO3 films promising as smart energy-saving windows.
doi_str_mv 10.1016/j.matlet.2019.04.066
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The VO2/Cs0.32WO3 composite thermochromic films were designed to promote the practical application of the VO2-based smart windows. The addition of 0.9 wt% Cs0.32WO3 can significantly shorten the phase transition response time and improve the solar heat shielding capacity of VO2, while maintaining high visible light transmittance (49.6%) and good solar modulation ability (10.4%). Furthermore, the phase transition of the composite film can occur at indoor temperature of 30 °C, and the indoor temperature can be greatly reduced by 7.7 °C under the simulated solar irradiation. 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subjects Composite materials
Energy conservation
Heat shielding
Light transmittance
Materials science
Nanoparticles
Phase transformation
Phase transitions
Response time
Smart materials
Solar energy materials
Vanadium oxides
title A novel method to improve phase transition of VO2 thermochromic films by Cs0.32WO3 nanoparticles
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