Metal/metal oxide@carbon composites derived from bimetallic Cu/Ni-based MOF and their electrocatalytic performance for glucose sensing
A metal/metal oxide@carbon composite(M/MO@C) was prepared by the direct carbonization of bimetallic Cu/Ni-based MOF (Cu/Ni-MOF) to make M/MO nanoparticles distributed well over the porous carbon matrix. The results of XRD and XPS corroborated the existence of Cu2O, CuO, Ni and NiO in M/MO nanopartic...
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| Veröffentlicht in: | Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2019-05, Vol.841, p.94-100 |
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| container_title | Journal of electroanalytical chemistry (Lausanne, Switzerland) |
| container_volume | 841 |
| creator | Xiao, Xuelian Peng, Sihui Wang, Chen Cheng, Dan Li, Na Dong, Yulin Li, Quanhua Wei, Denggui Liu, Peng Xie, Zhizhong Qu, Deyu Li, Xi |
| description | A metal/metal oxide@carbon composite(M/MO@C) was prepared by the direct carbonization of bimetallic Cu/Ni-based MOF (Cu/Ni-MOF) to make M/MO nanoparticles distributed well over the porous carbon matrix. The results of XRD and XPS corroborated the existence of Cu2O, CuO, Ni and NiO in M/MO nanoparticles. Due to a synergistic advantage from Cu2O/CuO, Ni/NiO and porous carbon, M/MO@C-800 exhibited an excellent sensing performance to glucose with a wider linear range from 0.1μM to 2.2mM and a lower detection limit of 0.06μM. Moreover, M/MO@C-800 also possessed an impressive reproducibility, excellent stability and high selectivity. The satisfactory detection of the glucose in the real samples demonstrated that M/MO@C had a perspective application as a high-performance glucose sensor.
[Display omitted]
•M/MO@C was prepared by the facile and direct carbonization of bimetallic Cu/Ni-MOF.•M/MO@C exhibited a high sensitivity in the detection of glucose.•The linear range was wider from 0.1μM to 2.2mM and the detection limit was as low as 0.06μM. |
| doi_str_mv | 10.1016/j.jelechem.2019.04.038 |
| format | Article |
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[Display omitted]
•M/MO@C was prepared by the facile and direct carbonization of bimetallic Cu/Ni-MOF.•M/MO@C exhibited a high sensitivity in the detection of glucose.•The linear range was wider from 0.1μM to 2.2mM and the detection limit was as low as 0.06μM.</description><identifier>ISSN: 1572-6657</identifier><identifier>EISSN: 1873-2569</identifier><identifier>DOI: 10.1016/j.jelechem.2019.04.038</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Bimetals ; Carbon ; Carbonization ; Copper ; Copper oxides ; Electrochemical sensors ; Glucose ; Metal oxides ; Metal-organic frameworks ; Metal/metal oxide composite ; Nanoparticles ; Nickel oxides ; Porous media ; Selectivity ; X ray photoelectron spectroscopy</subject><ispartof>Journal of electroanalytical chemistry (Lausanne, Switzerland), 2019-05, Vol.841, p.94-100</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier Science Ltd. May 15, 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-b778c367cee3d69ee4e2cdca176069c1c72a879d82e96b6857dd04fcadc46bda3</citedby><cites>FETCH-LOGICAL-c340t-b778c367cee3d69ee4e2cdca176069c1c72a879d82e96b6857dd04fcadc46bda3</cites><orcidid>0000-0001-8514-2646</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jelechem.2019.04.038$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Xiao, Xuelian</creatorcontrib><creatorcontrib>Peng, Sihui</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Cheng, Dan</creatorcontrib><creatorcontrib>Li, Na</creatorcontrib><creatorcontrib>Dong, Yulin</creatorcontrib><creatorcontrib>Li, Quanhua</creatorcontrib><creatorcontrib>Wei, Denggui</creatorcontrib><creatorcontrib>Liu, Peng</creatorcontrib><creatorcontrib>Xie, Zhizhong</creatorcontrib><creatorcontrib>Qu, Deyu</creatorcontrib><creatorcontrib>Li, Xi</creatorcontrib><title>Metal/metal oxide@carbon composites derived from bimetallic Cu/Ni-based MOF and their electrocatalytic performance for glucose sensing</title><title>Journal of electroanalytical chemistry (Lausanne, Switzerland)</title><description>A metal/metal oxide@carbon composite(M/MO@C) was prepared by the direct carbonization of bimetallic Cu/Ni-based MOF (Cu/Ni-MOF) to make M/MO nanoparticles distributed well over the porous carbon matrix. The results of XRD and XPS corroborated the existence of Cu2O, CuO, Ni and NiO in M/MO nanoparticles. Due to a synergistic advantage from Cu2O/CuO, Ni/NiO and porous carbon, M/MO@C-800 exhibited an excellent sensing performance to glucose with a wider linear range from 0.1μM to 2.2mM and a lower detection limit of 0.06μM. Moreover, M/MO@C-800 also possessed an impressive reproducibility, excellent stability and high selectivity. The satisfactory detection of the glucose in the real samples demonstrated that M/MO@C had a perspective application as a high-performance glucose sensor.
[Display omitted]
•M/MO@C was prepared by the facile and direct carbonization of bimetallic Cu/Ni-MOF.•M/MO@C exhibited a high sensitivity in the detection of glucose.•The linear range was wider from 0.1μM to 2.2mM and the detection limit was as low as 0.06μM.</description><subject>Bimetals</subject><subject>Carbon</subject><subject>Carbonization</subject><subject>Copper</subject><subject>Copper oxides</subject><subject>Electrochemical sensors</subject><subject>Glucose</subject><subject>Metal oxides</subject><subject>Metal-organic frameworks</subject><subject>Metal/metal oxide composite</subject><subject>Nanoparticles</subject><subject>Nickel oxides</subject><subject>Porous media</subject><subject>Selectivity</subject><subject>X ray photoelectron spectroscopy</subject><issn>1572-6657</issn><issn>1873-2569</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPwzAMgCsEEs-_gCJxbpekWdLeQBMviccFzlHquFuqthlJh-AP8LvJGJy52Jby2Y6_LDtntGCUyVlXdNgjrHAoOGV1QUVBy2ovO2KVKnM-l_V-queK51LO1WF2HGNHKa8qxo-yr0ecTD8btpH4D2fxEkxo_EjAD2sf3YSRWAzuHS1pgx9I437g3gFZbGZPLm9MTG-PzzfEjJZMK3SBbD80BQ8mkZ9TQtcYWh8GMwKSVJBlvwEfkUQcoxuXp9lBa_qIZ7_5JHu9uX5Z3OUPz7f3i6uHHEpBp7xRqoJSKkAsrawRBXKwYJiSVNbAQHFTqdpWHGvZyGqurKWiBWNByMaa8iS72M1dB_-2wTjpzm_CmFZqzoWQgtWCJ0ruKAg-xoCtXgc3mPCpGdVb57rTf8711rmmQifnqfFy14jphneHQUdwmG62LiQh2nr334hv7VmRaQ</recordid><startdate>20190515</startdate><enddate>20190515</enddate><creator>Xiao, Xuelian</creator><creator>Peng, Sihui</creator><creator>Wang, Chen</creator><creator>Cheng, Dan</creator><creator>Li, Na</creator><creator>Dong, Yulin</creator><creator>Li, Quanhua</creator><creator>Wei, Denggui</creator><creator>Liu, Peng</creator><creator>Xie, Zhizhong</creator><creator>Qu, Deyu</creator><creator>Li, Xi</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-8514-2646</orcidid></search><sort><creationdate>20190515</creationdate><title>Metal/metal oxide@carbon composites derived from bimetallic Cu/Ni-based MOF and their electrocatalytic performance for glucose sensing</title><author>Xiao, Xuelian ; Peng, Sihui ; Wang, Chen ; Cheng, Dan ; Li, Na ; Dong, Yulin ; Li, Quanhua ; Wei, Denggui ; Liu, Peng ; Xie, Zhizhong ; Qu, Deyu ; Li, Xi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-b778c367cee3d69ee4e2cdca176069c1c72a879d82e96b6857dd04fcadc46bda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Bimetals</topic><topic>Carbon</topic><topic>Carbonization</topic><topic>Copper</topic><topic>Copper oxides</topic><topic>Electrochemical sensors</topic><topic>Glucose</topic><topic>Metal oxides</topic><topic>Metal-organic frameworks</topic><topic>Metal/metal oxide composite</topic><topic>Nanoparticles</topic><topic>Nickel oxides</topic><topic>Porous media</topic><topic>Selectivity</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiao, Xuelian</creatorcontrib><creatorcontrib>Peng, Sihui</creatorcontrib><creatorcontrib>Wang, Chen</creatorcontrib><creatorcontrib>Cheng, Dan</creatorcontrib><creatorcontrib>Li, Na</creatorcontrib><creatorcontrib>Dong, Yulin</creatorcontrib><creatorcontrib>Li, Quanhua</creatorcontrib><creatorcontrib>Wei, Denggui</creatorcontrib><creatorcontrib>Liu, Peng</creatorcontrib><creatorcontrib>Xie, Zhizhong</creatorcontrib><creatorcontrib>Qu, Deyu</creatorcontrib><creatorcontrib>Li, Xi</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of electroanalytical chemistry (Lausanne, Switzerland)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiao, Xuelian</au><au>Peng, Sihui</au><au>Wang, Chen</au><au>Cheng, Dan</au><au>Li, Na</au><au>Dong, Yulin</au><au>Li, Quanhua</au><au>Wei, Denggui</au><au>Liu, Peng</au><au>Xie, Zhizhong</au><au>Qu, Deyu</au><au>Li, Xi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal/metal oxide@carbon composites derived from bimetallic Cu/Ni-based MOF and their electrocatalytic performance for glucose sensing</atitle><jtitle>Journal of electroanalytical chemistry (Lausanne, Switzerland)</jtitle><date>2019-05-15</date><risdate>2019</risdate><volume>841</volume><spage>94</spage><epage>100</epage><pages>94-100</pages><issn>1572-6657</issn><eissn>1873-2569</eissn><abstract>A metal/metal oxide@carbon composite(M/MO@C) was prepared by the direct carbonization of bimetallic Cu/Ni-based MOF (Cu/Ni-MOF) to make M/MO nanoparticles distributed well over the porous carbon matrix. The results of XRD and XPS corroborated the existence of Cu2O, CuO, Ni and NiO in M/MO nanoparticles. Due to a synergistic advantage from Cu2O/CuO, Ni/NiO and porous carbon, M/MO@C-800 exhibited an excellent sensing performance to glucose with a wider linear range from 0.1μM to 2.2mM and a lower detection limit of 0.06μM. Moreover, M/MO@C-800 also possessed an impressive reproducibility, excellent stability and high selectivity. The satisfactory detection of the glucose in the real samples demonstrated that M/MO@C had a perspective application as a high-performance glucose sensor.
[Display omitted]
•M/MO@C was prepared by the facile and direct carbonization of bimetallic Cu/Ni-MOF.•M/MO@C exhibited a high sensitivity in the detection of glucose.•The linear range was wider from 0.1μM to 2.2mM and the detection limit was as low as 0.06μM.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jelechem.2019.04.038</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-8514-2646</orcidid></addata></record> |
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| subjects | Bimetals Carbon Carbonization Copper Copper oxides Electrochemical sensors Glucose Metal oxides Metal-organic frameworks Metal/metal oxide composite Nanoparticles Nickel oxides Porous media Selectivity X ray photoelectron spectroscopy |
| title | Metal/metal oxide@carbon composites derived from bimetallic Cu/Ni-based MOF and their electrocatalytic performance for glucose sensing |
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