Inhibition of the Corrosion of Carbon Steels by Trehalose Lipid Surfactants
By using corrosion-electrochemical and quantum-chemical methods, we investigate the inhibition of the process of corrosion of carbon steel by trehalose lipid surfactants. It is shown that this substance efficiently inhibits the corrosion processes in steel in a medium of artificial acid rain. Upon a...
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| Veröffentlicht in: | Materials science (New York, N.Y.) N.Y.), 2019-01, Vol.54 (4), p.477-484 |
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| container_title | Materials science (New York, N.Y.) |
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| creator | Zin’, І. М. Karpenko, О. V. Pokyn’broda, Т. Ya Korets’ka, N. І. Tymus’, M. B. Kwiatkowski, L. Kornii, S. А. |
| description | By using corrosion-electrochemical and quantum-chemical methods, we investigate the inhibition of the process of corrosion of carbon steel by trehalose lipid surfactants. It is shown that this substance efficiently inhibits the corrosion processes in steel in a medium of artificial acid rain. Upon attainment of the critical concentration of micelle formation equal to ≈ 0.3 g/liter, the subsequent increase in the micelle content in the corrosive medium does not lead to a noticeable increase in the protective anticorrosion effect. The mechanism of corrosion inhibition is realized by the adsorption of trehalose lipid surfactant (TLS) molecules on the surface of steel by hydrophilic carbonyl and hydroxyl groups according to the donor–acceptor mechanism accompanied by the formation of a barrier film. An additional introduction of small amounts of poorly soluble zinc phosphate in the medium inhibited by the TLS noticeably weakens the corrosion of carbon steel. The degree of its protection becomes as high as 93–96%. This composition guarantees a higher degree of protection of carbon steel in the medium of artificial acid rain than its separate components. |
| doi_str_mv | 10.1007/s11003-019-00207-0 |
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The mechanism of corrosion inhibition is realized by the adsorption of trehalose lipid surfactant (TLS) molecules on the surface of steel by hydrophilic carbonyl and hydroxyl groups according to the donor–acceptor mechanism accompanied by the formation of a barrier film. An additional introduction of small amounts of poorly soluble zinc phosphate in the medium inhibited by the TLS noticeably weakens the corrosion of carbon steel. The degree of its protection becomes as high as 93–96%. 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The mechanism of corrosion inhibition is realized by the adsorption of trehalose lipid surfactant (TLS) molecules on the surface of steel by hydrophilic carbonyl and hydroxyl groups according to the donor–acceptor mechanism accompanied by the formation of a barrier film. An additional introduction of small amounts of poorly soluble zinc phosphate in the medium inhibited by the TLS noticeably weakens the corrosion of carbon steel. The degree of its protection becomes as high as 93–96%. This composition guarantees a higher degree of protection of carbon steel in the medium of artificial acid rain than its separate components.</description><subject>Acid deposition</subject><subject>Acid rain</subject><subject>Adsorption</subject><subject>Air pollution</subject><subject>Carbon steel</subject><subject>Carbon steels</subject><subject>Carbonyls</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion</subject><subject>Corrosion effects</subject><subject>Corrosion inhibitors</subject><subject>Corrosion mechanisms</subject><subject>Corrosion prevention</subject><subject>Hydroxyl groups</subject><subject>Lipids</subject><subject>Materials Science</subject><subject>Micelles</subject><subject>Organic chemistry</subject><subject>Protective coatings</subject><subject>Quantum chemistry</subject><subject>Rain</subject><subject>Solid Mechanics</subject><subject>Steel</subject><subject>Structural Materials</subject><subject>Surface active agents</subject><subject>Surfactants</subject><subject>Trehalose</subject><subject>Zinc phosphate</subject><issn>1068-820X</issn><issn>1573-885X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kU1LAzEQhhdRUKt_wNOCJw9bZ5PNJnuU4kexINgKvYVsOmlT6qYmKdh_b3QL4kVymGF4nknIm2VXJQxLAH4bylRoAWVTABDgBRxlZyXjtBCCzY9TD7UoBIH5aXYewhqSxDg7y57H3cq2NlrX5c7kcYX5yHnvwmEwUr5N3TQibkLe7vOZx5XauID5xG7tIp_uvFE6qi6Gi-zEqE3Ay0MdZG8P97PRUzF5eRyP7iaFrgjEAglTJUWoeAVMC9UCF7ytVS041i1FUS0MJZqrBknTaEW1QYqtMpVolKYNHWTX_d6tdx87DFGu3c536UpJSEVrICWt_6coaURdE56oYU8t1Qal7YyLXul0FvhutevQ2DS_Y6IRjDL-vfbmj5CYiJ9xqXYhyPH09S9LelanDw0ejdx6-678XpYgv3OTfW4y5SZ_cpOQJNpLIcHdEv3vu_-xvgCH6pip</recordid><startdate>20190101</startdate><enddate>20190101</enddate><creator>Zin’, І. М.</creator><creator>Karpenko, О. V.</creator><creator>Pokyn’broda, Т. Ya</creator><creator>Korets’ka, N. І.</creator><creator>Tymus’, M. B.</creator><creator>Kwiatkowski, L.</creator><creator>Kornii, S. А.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20190101</creationdate><title>Inhibition of the Corrosion of Carbon Steels by Trehalose Lipid Surfactants</title><author>Zin’, І. М. ; Karpenko, О. V. ; Pokyn’broda, Т. Ya ; Korets’ka, N. І. ; Tymus’, M. B. ; Kwiatkowski, L. ; Kornii, S. 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| subjects | Acid deposition Acid rain Adsorption Air pollution Carbon steel Carbon steels Carbonyls Characterization and Evaluation of Materials Chemistry and Materials Science Corrosion Corrosion effects Corrosion inhibitors Corrosion mechanisms Corrosion prevention Hydroxyl groups Lipids Materials Science Micelles Organic chemistry Protective coatings Quantum chemistry Rain Solid Mechanics Steel Structural Materials Surface active agents Surfactants Trehalose Zinc phosphate |
| title | Inhibition of the Corrosion of Carbon Steels by Trehalose Lipid Surfactants |
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