Enhanced Aggregation of Stimuli Responsive Surfactants by Esterolytic Reactions

Thioester surfactants, [C12H25N(CH3)2(CH2)mSCOCH3] Br (C12mSAc, m = 4, 11, 12), yielded thiol surfactants via thiol-thioester exchange upon addition of dithiothreitol in aqueous solution. The thiolthioester exchange reaction was enhanced in a micellar system owing to the concentration effect. The en...

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Veröffentlicht in:	Journal of Oleo Science 2019, Vol.68(6), pp.573-580
Hauptverfasser:	Asakawa, Tsuyoshi, Fujii, Akina, Yoneda, Nodoka, Ohta, Akio, Asakawa, Hitoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Agglomeration Aqueous solutions Chains enhanced aggregation esterolytic reaction Exchanging Hydrogen peroxide Micelles Oxidation Photon correlation spectroscopy stimuli responsive surfactant Surfactants thiol-thioester exchange
Online-Zugang:	Volltext
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