Facile Synthesis of Functional Graphene Quantum Dots and Their Application to Cu(II) Ion Sensing
Functional graphene quantum dots (IL-GQDs) are synthesized by electrochemical exfoliation in a one-pot process. Ionic liquid in the mixed solution (water/acetonitrile) is used as the electrolyte, which can be bonded to the surface of GQDs. The method just needs a very low concentration of ionic liqu...
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Veröffentlicht in: | Chemistry letters 2019-01, Vol.48 (4), p.309 |
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creator | Wang, Jingwei Zheng, Yongji Teng, Qiaoqiao Wu, Datong |
description | Functional graphene quantum dots (IL-GQDs) are synthesized by electrochemical exfoliation in a one-pot process. Ionic liquid in the mixed solution (water/acetonitrile) is used as the electrolyte, which can be bonded to the surface of GQDs. The method just needs a very low concentration of ionic liquid. Fluorescent spectra indicate that the maximum emission intensity is achieved at 465 nm. Further, the obtained IL-GQDs exhibit selective fluorescence quenching towards Cu(II) ion, with a detection limit of ppb level. |
doi_str_mv | 10.1246/cl.180967 |
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Ionic liquid in the mixed solution (water/acetonitrile) is used as the electrolyte, which can be bonded to the surface of GQDs. The method just needs a very low concentration of ionic liquid. Fluorescent spectra indicate that the maximum emission intensity is achieved at 465 nm. Further, the obtained IL-GQDs exhibit selective fluorescence quenching towards Cu(II) ion, with a detection limit of ppb level.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.180967</identifier><language>eng ; fre ; ger ; jpn</language><publisher>Tokyo: Chemical Society of Japan</publisher><subject>Acetonitrile ; Emission spectra ; Fluorescence ; Graphene ; Ionic liquids ; Ions ; Quantum dots</subject><ispartof>Chemistry letters, 2019-01, Vol.48 (4), p.309</ispartof><rights>Copyright Chemical Society of Japan 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Wang, Jingwei</creatorcontrib><creatorcontrib>Zheng, Yongji</creatorcontrib><creatorcontrib>Teng, Qiaoqiao</creatorcontrib><creatorcontrib>Wu, Datong</creatorcontrib><title>Facile Synthesis of Functional Graphene Quantum Dots and Their Application to Cu(II) Ion Sensing</title><title>Chemistry letters</title><description>Functional graphene quantum dots (IL-GQDs) are synthesized by electrochemical exfoliation in a one-pot process. Ionic liquid in the mixed solution (water/acetonitrile) is used as the electrolyte, which can be bonded to the surface of GQDs. The method just needs a very low concentration of ionic liquid. Fluorescent spectra indicate that the maximum emission intensity is achieved at 465 nm. Further, the obtained IL-GQDs exhibit selective fluorescence quenching towards Cu(II) ion, with a detection limit of ppb level.</description><subject>Acetonitrile</subject><subject>Emission spectra</subject><subject>Fluorescence</subject><subject>Graphene</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Quantum dots</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNotj01Lw0AURQdRsNQu_AcDbnSR-uYjM8myRFsDBZHWdX3JzNgpcRIzycJ_34guLpcDlwOXkFsGS8aleqybJcsgV_qCzJiQWQKapZdkBkKpRAPn12QRo68ApNASRDYjH2usfWPp7icMRxt9pK2j6zHUg28DNnTTY3e0wdK3EcMwftGndogUg6H7o_U9XXVd42v8XdOhpcV4X5YPtJxoZ0P04fOGXDlsol3895y8r5_3xUuyfd2UxWqbnJjIdGIMmFwaVGllsHLSAXBAJxgamxqZoq5zK4xFqWSqHTcOhcrBpHWVCT1lTu7-vF3ffo82DodTO_bThXjgXDKhheZanAGw4FZN</recordid><startdate>20190101</startdate><enddate>20190101</enddate><creator>Wang, Jingwei</creator><creator>Zheng, Yongji</creator><creator>Teng, Qiaoqiao</creator><creator>Wu, Datong</creator><general>Chemical Society of Japan</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20190101</creationdate><title>Facile Synthesis of Functional Graphene Quantum Dots and Their Application to Cu(II) Ion Sensing</title><author>Wang, Jingwei ; Zheng, Yongji ; Teng, Qiaoqiao ; Wu, Datong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j1387-dd0d94da65bdabf4f0020af31ade5d45a7c9e3dea46457f2dfa3690d5cb837b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; fre ; ger ; jpn</language><creationdate>2019</creationdate><topic>Acetonitrile</topic><topic>Emission spectra</topic><topic>Fluorescence</topic><topic>Graphene</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Quantum dots</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Jingwei</creatorcontrib><creatorcontrib>Zheng, Yongji</creatorcontrib><creatorcontrib>Teng, Qiaoqiao</creatorcontrib><creatorcontrib>Wu, Datong</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Jingwei</au><au>Zheng, Yongji</au><au>Teng, Qiaoqiao</au><au>Wu, Datong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile Synthesis of Functional Graphene Quantum Dots and Their Application to Cu(II) Ion Sensing</atitle><jtitle>Chemistry letters</jtitle><date>2019-01-01</date><risdate>2019</risdate><volume>48</volume><issue>4</issue><spage>309</spage><pages>309-</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Functional graphene quantum dots (IL-GQDs) are synthesized by electrochemical exfoliation in a one-pot process. Ionic liquid in the mixed solution (water/acetonitrile) is used as the electrolyte, which can be bonded to the surface of GQDs. The method just needs a very low concentration of ionic liquid. Fluorescent spectra indicate that the maximum emission intensity is achieved at 465 nm. Further, the obtained IL-GQDs exhibit selective fluorescence quenching towards Cu(II) ion, with a detection limit of ppb level.</abstract><cop>Tokyo</cop><pub>Chemical Society of Japan</pub><doi>10.1246/cl.180967</doi></addata></record> |
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source | Oxford University Press Journals All Titles (1996-Current) |
subjects | Acetonitrile Emission spectra Fluorescence Graphene Ionic liquids Ions Quantum dots |
title | Facile Synthesis of Functional Graphene Quantum Dots and Their Application to Cu(II) Ion Sensing |
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