Selective Hydrogenation of Nitriles to Secondary Imines over Rh-PVP Catalyst under Mild Conditions

Various metal nanoparticle catalysts (Ru, Rh, Pd, Ir, and Pt) were prepared via liquid-phase reduction and their activity was studied for selective hydrogenation of benzonitrile to corresponding secondary imine under mild conditions (3 bar H2 and 30 °C). The Rh catalyst with particle size of 2.7 nm...

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Veröffentlicht in:	Chemistry letters 2018-07, Vol.47 (7), p.938-940
Hauptverfasser:	Nishida, Yoshihide, Chaudhari, Chandan, Imatome, Hirotaka, Sato, Katsutoshi, Nagaoka, Katsutoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzonitrile Catalysis Catalysts Hydrogenation Imines Iridium Liquid phases Nanoparticles Nitriles Palladium Platinum Rhodium
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creator	Nishida, Yoshihide Chaudhari, Chandan Imatome, Hirotaka Sato, Katsutoshi Nagaoka, Katsutoshi
description	Various metal nanoparticle catalysts (Ru, Rh, Pd, Ir, and Pt) were prepared via liquid-phase reduction and their activity was studied for selective hydrogenation of benzonitrile to corresponding secondary imine under mild conditions (3 bar H2 and 30 °C). The Rh catalyst with particle size of 2.7 nm exhibited excellent activity for the hydrogenation of benzonitrile to secondary imine. The catalyst was reused and applied to transform various nitriles to corresponding secondary imines.
doi_str_mv	10.1246/cl.180349
format	Article
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Benzonitrile Catalysis Catalysts Hydrogenation Imines Iridium Liquid phases Nanoparticles Nitriles Palladium Platinum Rhodium
title	Selective Hydrogenation of Nitriles to Secondary Imines over Rh-PVP Catalyst under Mild Conditions
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