Effect of Temperature on K+ and Mg2+ Extracted Desorption of Cs from Vermiculitized Biotite
Sorbed Cs on vermiculitized biotite in saturation amount was desorbed by extractions with 1 M K+ and Mg2+ at varied temperatures. At room temperature, Cs+ was readily desorbed by leaching with K+ (ca. 100%) but not by Mg2+ (ca. 50%). However, the contrary was true for desorption at high temperatures...
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| Veröffentlicht in: | Chemistry letters 2017-01, Vol.46 (9), p.1350-1352 |
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| container_issue | 9 |
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| container_title | Chemistry letters |
| container_volume | 46 |
| creator | Yin, Xiangbiao Zhang, Lijuan Ochiai, Asumi Utsunomiya, Satoshi Takahashi, Hideharu Ohnuki, Toshihiko Takeshita, Kenji |
| description | Sorbed Cs on vermiculitized biotite in saturation amount was desorbed by extractions with 1 M K+ and Mg2+ at varied temperatures. At room temperature, Cs+ was readily desorbed by leaching with K+ (ca. 100%) but not by Mg2+ (ca. 50%). However, the contrary was true for desorption at high temperatures, in which Mg2+ desorbed far more Cs+ (ca. 100%) than K+ (ca. 25%). XRD analysis of Cs-depleted samples suggested that the contrary abilities of K+ and Mg2+ for Cs desorption at low and high temperatures were attributed to their induced interlayer collapse or expansion during extraction. |
| doi_str_mv | 10.1246/cl.170551 |
| format | Article |
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At room temperature, Cs+ was readily desorbed by leaching with K+ (ca. 100%) but not by Mg2+ (ca. 50%). However, the contrary was true for desorption at high temperatures, in which Mg2+ desorbed far more Cs+ (ca. 100%) than K+ (ca. 25%). XRD analysis of Cs-depleted samples suggested that the contrary abilities of K+ and Mg2+ for Cs desorption at low and high temperatures were attributed to their induced interlayer collapse or expansion during extraction.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.170551</identifier><language>eng ; jpn</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Biotite ; Collapse ; Desorption ; Interlayers ; Leaching ; Temperature effects</subject><ispartof>Chemistry letters, 2017-01, Vol.46 (9), p.1350-1352</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Chemical Society of Japan 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Yin, Xiangbiao</creatorcontrib><creatorcontrib>Zhang, Lijuan</creatorcontrib><creatorcontrib>Ochiai, Asumi</creatorcontrib><creatorcontrib>Utsunomiya, Satoshi</creatorcontrib><creatorcontrib>Takahashi, Hideharu</creatorcontrib><creatorcontrib>Ohnuki, Toshihiko</creatorcontrib><creatorcontrib>Takeshita, Kenji</creatorcontrib><title>Effect of Temperature on K+ and Mg2+ Extracted Desorption of Cs from Vermiculitized Biotite</title><title>Chemistry letters</title><description>Sorbed Cs on vermiculitized biotite in saturation amount was desorbed by extractions with 1 M K+ and Mg2+ at varied temperatures. At room temperature, Cs+ was readily desorbed by leaching with K+ (ca. 100%) but not by Mg2+ (ca. 50%). However, the contrary was true for desorption at high temperatures, in which Mg2+ desorbed far more Cs+ (ca. 100%) than K+ (ca. 25%). XRD analysis of Cs-depleted samples suggested that the contrary abilities of K+ and Mg2+ for Cs desorption at low and high temperatures were attributed to their induced interlayer collapse or expansion during extraction.</description><subject>Biotite</subject><subject>Collapse</subject><subject>Desorption</subject><subject>Interlayers</subject><subject>Leaching</subject><subject>Temperature effects</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNpFkMtOwzAQRS0EEqWw4A8ssaxSPH4k8RJKeYgiNoUNi8hxbHCVxsFxJMrXY1QkVrOYc2eOLkLnQOZAeX6p2zkURAg4QBNgvMxIAeIQTQjL86wglB6jk2HYEEJKyegEvS2tNTpib_HabHsTVByDwb7DjzOsugY_vdMZXn7FoHQ0Db4xgw99dAlIkcWAbfBb_GrC1umxddF9J-ja-eiiOUVHVrWDOfubU_Ryu1wv7rPV893D4mqVaUaLmBVMlsmsYACSyKasbWllbRrdAIM65yXlSRVqIUFoULWUnEtNmWCcQiMJm6KL_d0--M_RDLHa-DF06WVFKQcmaCohUfme0h8myaat187E3Ub1qvtPAKl-i6x0W-2LZD8Xz2PV</recordid><startdate>20170101</startdate><enddate>20170101</enddate><creator>Yin, Xiangbiao</creator><creator>Zhang, Lijuan</creator><creator>Ochiai, Asumi</creator><creator>Utsunomiya, Satoshi</creator><creator>Takahashi, Hideharu</creator><creator>Ohnuki, Toshihiko</creator><creator>Takeshita, Kenji</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20170101</creationdate><title>Effect of Temperature on K+ and Mg2+ Extracted Desorption of Cs from Vermiculitized Biotite</title><author>Yin, Xiangbiao ; Zhang, Lijuan ; Ochiai, Asumi ; Utsunomiya, Satoshi ; Takahashi, Hideharu ; Ohnuki, Toshihiko ; Takeshita, Kenji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c327t-73987027311909d8bf8f9bedcd131b648249321b5915c1ab99449c2353421d903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>2017</creationdate><topic>Biotite</topic><topic>Collapse</topic><topic>Desorption</topic><topic>Interlayers</topic><topic>Leaching</topic><topic>Temperature effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yin, Xiangbiao</creatorcontrib><creatorcontrib>Zhang, Lijuan</creatorcontrib><creatorcontrib>Ochiai, Asumi</creatorcontrib><creatorcontrib>Utsunomiya, Satoshi</creatorcontrib><creatorcontrib>Takahashi, Hideharu</creatorcontrib><creatorcontrib>Ohnuki, Toshihiko</creatorcontrib><creatorcontrib>Takeshita, Kenji</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yin, Xiangbiao</au><au>Zhang, Lijuan</au><au>Ochiai, Asumi</au><au>Utsunomiya, Satoshi</au><au>Takahashi, Hideharu</au><au>Ohnuki, Toshihiko</au><au>Takeshita, Kenji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Temperature on K+ and Mg2+ Extracted Desorption of Cs from Vermiculitized Biotite</atitle><jtitle>Chemistry letters</jtitle><date>2017-01-01</date><risdate>2017</risdate><volume>46</volume><issue>9</issue><spage>1350</spage><epage>1352</epage><pages>1350-1352</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Sorbed Cs on vermiculitized biotite in saturation amount was desorbed by extractions with 1 M K+ and Mg2+ at varied temperatures. At room temperature, Cs+ was readily desorbed by leaching with K+ (ca. 100%) but not by Mg2+ (ca. 50%). However, the contrary was true for desorption at high temperatures, in which Mg2+ desorbed far more Cs+ (ca. 100%) than K+ (ca. 25%). XRD analysis of Cs-depleted samples suggested that the contrary abilities of K+ and Mg2+ for Cs desorption at low and high temperatures were attributed to their induced interlayer collapse or expansion during extraction.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.170551</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0366-7022 |
| ispartof | Chemistry letters, 2017-01, Vol.46 (9), p.1350-1352 |
| issn | 0366-7022 1348-0715 |
| language | eng ; jpn |
| recordid | cdi_proquest_journals_2241352071 |
| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Biotite Collapse Desorption Interlayers Leaching Temperature effects |
| title | Effect of Temperature on K+ and Mg2+ Extracted Desorption of Cs from Vermiculitized Biotite |
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