Analyzing of Reaction Mechanisms of Cu-Al Intermetallic Compounds in Dipping Experiment of Cu Wire and Cu Plate into Al Melt by Cylindrical Reaction Model and Flat Plate Model —In Order to Analyze the Combustion Synthesis of Cu-Al Intermetallic Compounds

In our previous paper, dipping experiments of Cu wires and Cu plates into molten Al were investigated to analyze the combustion synthesis of Cu-Al intermetallic compounds. From the dipping experiments, it was found that Cu3Al compound layers were formed between the Cu base metal and the molten Al. T...

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Veröffentlicht in:Journal of the Japan Institute of Metals and Materials 2018/08/01, Vol.82(8), pp.297-306
Hauptverfasser: Hashi, Kaichi, Hibino, Atsushi
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description In our previous paper, dipping experiments of Cu wires and Cu plates into molten Al were investigated to analyze the combustion synthesis of Cu-Al intermetallic compounds. From the dipping experiments, it was found that Cu3Al compound layers were formed between the Cu base metal and the molten Al. The compound formation reactions were able to be almost simulated by calculating the cylindrical model and the flat plate reaction model. However, there are a few differences between Cu wire dipping experiment and Cu plate dipping experiment. Al concentration of Cu3Al compound phase formed in the Cu wire are higher than that of Cu plate. For the reaction parameters, diffusion coefficient of Al in Cu plate dipping experiment is also higher than that of Cu wire dipping experiment.For the dipping experiment of Cu wire, the reaction parameters are,For the dipping experiment of Cu plate, the reaction parameters are,From analyzing the cylindrical model and the flat plate reaction model, it is guessed the differences were caused by the contact area of Cu/Cu3Al/Al interface and Al concentration of Cu3Al phase formed in Cu wires and Cu plates.
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From the dipping experiments, it was found that Cu3Al compound layers were formed between the Cu base metal and the molten Al. The compound formation reactions were able to be almost simulated by calculating the cylindrical model and the flat plate reaction model. However, there are a few differences between Cu wire dipping experiment and Cu plate dipping experiment. Al concentration of Cu3Al compound phase formed in the Cu wire are higher than that of Cu plate. For the reaction parameters, diffusion coefficient of Al in Cu plate dipping experiment is also higher than that of Cu wire dipping experiment.For the dipping experiment of Cu wire, the reaction parameters are,For the dipping experiment of Cu plate, the reaction parameters are,From analyzing the cylindrical model and the flat plate reaction model, it is guessed the differences were caused by the contact area of Cu/Cu3Al/Al interface and Al concentration of Cu3Al phase formed in Cu wires and Cu plates.</description><identifier>ISSN: 0021-4876</identifier><identifier>EISSN: 1880-6880</identifier><identifier>DOI: 10.2320/jinstmet.J2017056</identifier><language>jpn</language><publisher>Sendai: The Japan Institute of Metals and Materials</publisher><subject>Aluminum ; Base metal ; Combustion synthesis ; Computer simulation ; Copper ; Cu-Al ; cylindrical reaction model ; Diffusion coefficient ; Dipping ; dipping experiment ; Experiments ; flat plate reaction model ; Flat plates ; intermetallic compound ; Intermetallic compounds ; Mathematical models ; Parameters ; reaction mechanism ; Reaction mechanisms ; Wire</subject><ispartof>Journal of the Japan Institute of Metals and Materials, 2018/08/01, Vol.82(8), pp.297-306</ispartof><rights>2018 The Japan Institute of Metals and Materials</rights><rights>Copyright Japan Science and Technology Agency 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1876,27903,27904</link.rule.ids></links><search><creatorcontrib>Hashi, Kaichi</creatorcontrib><creatorcontrib>Hibino, Atsushi</creatorcontrib><title>Analyzing of Reaction Mechanisms of Cu-Al Intermetallic Compounds in Dipping Experiment of Cu Wire and Cu Plate into Al Melt by Cylindrical Reaction Model and Flat Plate Model —In Order to Analyze the Combustion Synthesis of Cu-Al Intermetallic Compounds</title><title>Journal of the Japan Institute of Metals and Materials</title><addtitle>J. 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For the reaction parameters, diffusion coefficient of Al in Cu plate dipping experiment is also higher than that of Cu wire dipping experiment.For the dipping experiment of Cu wire, the reaction parameters are,For the dipping experiment of Cu plate, the reaction parameters are,From analyzing the cylindrical model and the flat plate reaction model, it is guessed the differences were caused by the contact area of Cu/Cu3Al/Al interface and Al concentration of Cu3Al phase formed in Cu wires and Cu plates.</abstract><cop>Sendai</cop><pub>The Japan Institute of Metals and Materials</pub><doi>10.2320/jinstmet.J2017056</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record>
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subjects Aluminum
Base metal
Combustion synthesis
Computer simulation
Copper
Cu-Al
cylindrical reaction model
Diffusion coefficient
Dipping
dipping experiment
Experiments
flat plate reaction model
Flat plates
intermetallic compound
Intermetallic compounds
Mathematical models
Parameters
reaction mechanism
Reaction mechanisms
Wire
title Analyzing of Reaction Mechanisms of Cu-Al Intermetallic Compounds in Dipping Experiment of Cu Wire and Cu Plate into Al Melt by Cylindrical Reaction Model and Flat Plate Model —In Order to Analyze the Combustion Synthesis of Cu-Al Intermetallic Compounds
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