C–H Arylation of N‐Heteroarenes under Metal‐Free Conditions and its Application towards the Synthesis of Pentabromo‐ and Pentachloropseudilins

Herein, we are reporting metal‐free conditions for radical initiation and direct C–H arylation of N‐heteroarenes. Starting from aniline, the corresponding arenediazonium salt generated in situ is reduced to an aryl radical in the presence of chloropromazine hydrochloride, a new reagent for this appl...

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Veröffentlicht in:	European journal of organic chemistry 2019-06, Vol.2019 (22), p.3591-3598
Hauptverfasser:	Kumar, Mukesh, Sharma, Shweta, Sil, Parijat, Kushwaha, Manoj, Mayor, Satyajit, Vishwakarma, Ram A., Singh, Parvinder Pal
Format:	Artikel
Sprache:	eng
Schlagworte:	2‐Arylated pyrroles Aniline Aromatic compounds Aryl radicals C–H arylation Depletion Natural products Pentabromopseudilin Pentachloropseudilin Reagents Substrates Synthesis
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