Produced Water Treatment Using Self-assembled Organic Nanotubes as Adsorbents

A novel treatment technique for produced water was developed using organic nanotubes (ONTs) as adsorbents. ONTs formed by the self-assembly of peptide lipids are known to adsorb heavy metals and hydrophobic molecules. Preferential adsorption of heavy metals against alkali- and alkali-earth metals ab...

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Veröffentlicht in:Journal of the Japan Petroleum Institute 2018/01/01, Vol.61(1), pp.44-49
Hauptverfasser: Kogiso, Masaki, Aoyagi, Masaru
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container_title Journal of the Japan Petroleum Institute
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creator Kogiso, Masaki
Aoyagi, Masaru
description A novel treatment technique for produced water was developed using organic nanotubes (ONTs) as adsorbents. ONTs formed by the self-assembly of peptide lipids are known to adsorb heavy metals and hydrophobic molecules. Preferential adsorption of heavy metals against alkali- and alkali-earth metals above pH 6 was confirmed. Pb2+ in high-salinity model produced water was reduced to 0.04 ppm by treatment with ONTs, compared to 0.84 ppm without ONTs. The selectivity of Pb2+ against alkali-earth metals was over 3000. Design of the molecular structures of peptide lipids reduced the content of ​p-cresol in model produced water from 13 to less than 1 ppm. To improve separation from wastewater, ONTs hybridized with magnetic nanoparticles (MNPs) were obtained through the pH adjusting method. Hybrids maintained the hybridized state over a wide pH range (1-9). Adsorption tests using real produced water indicated that ONTs could adsorb heavy metals, suspended solids, oil, and some organic compounds in produced water in a one-step process, without pre-treatment.
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subjects Adsorbent
Adsorbents
Adsorption
Alkali metals
Cresols
Earth
Heavy metals
Hybrids
Lead
Lipids
Metals
Nanoparticles
Nanotechnology
Nanotubes
Organic compounds
Organic nanotube
Peptides
pH
Pretreatment
Produced water
Selectivity
Self-assembly
Solid suspensions
Suspended particulate matter
Suspended solids
Wastewater
Wastewater treatment
Water treatment
title Produced Water Treatment Using Self-assembled Organic Nanotubes as Adsorbents
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