Gas-phase Ligation of Cr^sup +^/Fe^sup +^/Ni^sup +^ Ions with Iodine

Gas-phase Ligation of Cr^sup +^/Fe^sup +^/Ni^sup +^ Ions with Iodine

The gas-phase reaction products of Cr^sup +^, Fe^sup +^ and Ni^sup +^ ions produced by laser desorption ionization (LDI) of a stainless steel sample with iodine molecules in a Fourier transform ion cyclotron resonance mass spectrometer (FT ICR MS) uncover differences in the behavior of individual me...

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Veröffentlicht in:Croatica chemica acta 2009-10, Vol.82 (4), p.841
Hauptverfasser: Kazazic, Sasa, Kazazic, Snjezana P, Srzic, Dunja
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Sprache:eng
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Chemical reactions
Ions
Molecules
Stainless steel
Studies
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Kazazic, Snjezana P
Srzic, Dunja
description The gas-phase reaction products of Cr^sup +^, Fe^sup +^ and Ni^sup +^ ions produced by laser desorption ionization (LDI) of a stainless steel sample with iodine molecules in a Fourier transform ion cyclotron resonance mass spectrometer (FT ICR MS) uncover differences in the behavior of individual metal ions in the ligation process as well as in the reactions with ubiquitous water: Fe^sup +^ being prone to ligation of two (but also to hydrolysis and disappearance), Ni^sup +^ to ligation of three and Cr^sup +^ preferring to ligate four iodine atoms. The surplus energy of metal ions produced in the excited states enables them to dissociate I^sub 2^ and exchange charge with the I^sub 2^ molecules and I atoms forming I^sub 2^^sup +^ and I^sub 3^^sup +^ ions. [PUBLICATION ABSTRACT]
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subjects Chemical reactions
Ions
Molecules
Stainless steel
Studies
title Gas-phase Ligation of Cr^sup +^/Fe^sup +^/Ni^sup +^ Ions with Iodine
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