Inhibitory Effect of Dihydrosphingosine with α-Tocopherol on Volatile Formation during the Autoxidation of Polyunsaturated Triacylglycerols

The effect of dihydrosphingosine (d18:0) on triacylglycerol (TAG) oxidation was examined with and without α-tocopherol. Three types of TAG from fish, linseed, and soybean oil were oxidized at 50°C to determine the effect of dihydrosphingosine (d18:0) with or without α-tocopherol on triacylglycerol (...

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Veröffentlicht in:Journal of Oleo Science 2016/09/01, Vol.65(9), pp.713-722
Hauptverfasser: Uemura, Mariko, Shibata, Ako, Hosokawa, Masashi, Iwashima-Suzuki, Ai, Shiota, Makoto, Miyashita, Kazuo
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container_issue 9
container_start_page 713
container_title Journal of Oleo Science
container_volume 65
creator Uemura, Mariko
Shibata, Ako
Hosokawa, Masashi
Iwashima-Suzuki, Ai
Shiota, Makoto
Miyashita, Kazuo
description The effect of dihydrosphingosine (d18:0) on triacylglycerol (TAG) oxidation was examined with and without α-tocopherol. Three types of TAG from fish, linseed, and soybean oil were oxidized at 50°C to determine the effect of dihydrosphingosine (d18:0) with or without α-tocopherol on triacylglycerol (TAG) oxidation. The analysis of oxygen consumption and total volatile formation demonstrated a small effect of d18:0 on TAG oxidation in the absence of α-tocopherol. On the other hand, the combination of d18:0 with α-tocopherol showed strong antioxidant activity and completely inhibited volatile formation within 1400 h for soybean oil TAG, 650 h for linseed oil TAG, and 380 h for fish oil TAG.
doi_str_mv 10.5650/jos.ess16071
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subjects acrolein
alpha-Tocopherol - chemistry
Antioxidants
Antioxidants - chemistry
Autoxidation
dihydrosphingosine
fish oil oxidation
Fish oils
flavor deterioration
Linseed oil
Molecular Conformation
Oxidation
Oxidation-Reduction
oxidative stability
Oxygen consumption
Soybean oil
Soybeans
Sphingosine - analogs & derivatives
Sphingosine - chemistry
Tocopherol
Triglycerides
Triglycerides - chemistry
Vitamin E
Volatile Organic Compounds - chemical synthesis
Volatile Organic Compounds - chemistry
volatiles
α-tocopherol
title Inhibitory Effect of Dihydrosphingosine with α-Tocopherol on Volatile Formation during the Autoxidation of Polyunsaturated Triacylglycerols
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