Mixed Micellization and Interfacial Properties of Polyoxyethylene Sorbitan Esters with Cetylpyridinium Chloride: A Tensiometric Study
In this work a surface tensiometric method was used to study the effect of the chain length of non-ionic surfactants, viz. ethoxylated sorbitan esters, on micellar composition, critical micellar concentration, mutual interaction parameter ( β 12 ), and activity coefficients of the mixed micelles for...
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| Veröffentlicht in: | Journal of surfactants and detergents 2009-10, Vol.12 (4), p.295-304 |
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| creator | Rehman, Nuzhat Mir, Mohammad Amin Jan, Musarat Amin, Adil Dar, Aijaz Ahmad Rather, Ghulam Mohammad |
| description | In this work a surface tensiometric method was used to study the effect of the chain length of non-ionic surfactants, viz. ethoxylated sorbitan esters, on micellar composition, critical micellar concentration, mutual interaction parameter (
β
12
), and activity coefficients of the mixed micelles formed with the cationic surfactant cetylpyridinium chloride at 25 °C. The micellar characteristics evaluated using the Clint, Rubingh, and Blankschtein models deviated significantly from ideality, and were used to ascertain the validity of these theories. Thermodynamic stability in terms of Maeda’s approach and interfacial properties is also discussed. |
| doi_str_mv | 10.1007/s11743-009-1123-9 |
| format | Article |
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β
12
), and activity coefficients of the mixed micelles formed with the cationic surfactant cetylpyridinium chloride at 25 °C. The micellar characteristics evaluated using the Clint, Rubingh, and Blankschtein models deviated significantly from ideality, and were used to ascertain the validity of these theories. Thermodynamic stability in terms of Maeda’s approach and interfacial properties is also discussed.</description><identifier>ISSN: 1097-3958</identifier><identifier>EISSN: 1558-9293</identifier><identifier>DOI: 10.1007/s11743-009-1123-9</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Activity coefficients ; Aquatic Pollution ; Chemistry ; Chemistry and Materials Science ; Esters ; Ethoxylated sorbitan esters ; Industrial Chemistry/Chemical Engineering ; Interaction parameter ; Interfacial properties ; Mixed micellization ; Original Article ; Physical Chemistry ; Polymer Sciences ; Solvents ; Surface chemistry ; Surface tension ; Surfaces and Interfaces ; Surfactants ; Thin Films ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Journal of surfactants and detergents, 2009-10, Vol.12 (4), p.295-304</ispartof><rights>AOCS 2009</rights><rights>2009 American Oil Chemists' Society (AOCS)</rights><rights>Copyright AOCS Press Oct 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3635-2a48f46bae734fabea073f22577e3440fa7ce864dadb5528fd50e017e7cea6e13</citedby><cites>FETCH-LOGICAL-c3635-2a48f46bae734fabea073f22577e3440fa7ce864dadb5528fd50e017e7cea6e13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1007%2Fs11743-009-1123-9$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1007%2Fs11743-009-1123-9$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Rehman, Nuzhat</creatorcontrib><creatorcontrib>Mir, Mohammad Amin</creatorcontrib><creatorcontrib>Jan, Musarat</creatorcontrib><creatorcontrib>Amin, Adil</creatorcontrib><creatorcontrib>Dar, Aijaz Ahmad</creatorcontrib><creatorcontrib>Rather, Ghulam Mohammad</creatorcontrib><title>Mixed Micellization and Interfacial Properties of Polyoxyethylene Sorbitan Esters with Cetylpyridinium Chloride: A Tensiometric Study</title><title>Journal of surfactants and detergents</title><addtitle>J Surfact Deterg</addtitle><description>In this work a surface tensiometric method was used to study the effect of the chain length of non-ionic surfactants, viz. ethoxylated sorbitan esters, on micellar composition, critical micellar concentration, mutual interaction parameter (
β
12
), and activity coefficients of the mixed micelles formed with the cationic surfactant cetylpyridinium chloride at 25 °C. The micellar characteristics evaluated using the Clint, Rubingh, and Blankschtein models deviated significantly from ideality, and were used to ascertain the validity of these theories. Thermodynamic stability in terms of Maeda’s approach and interfacial properties is also discussed.</description><subject>Activity coefficients</subject><subject>Aquatic Pollution</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Esters</subject><subject>Ethoxylated sorbitan esters</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Interaction parameter</subject><subject>Interfacial properties</subject><subject>Mixed micellization</subject><subject>Original Article</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Solvents</subject><subject>Surface chemistry</subject><subject>Surface tension</subject><subject>Surfaces and Interfaces</subject><subject>Surfactants</subject><subject>Thin Films</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>1097-3958</issn><issn>1558-9293</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqFkEtLxDAQgIso-PwB3oL3ah5N03qTdX2hKKyeQ7aduJFssiZZtN7930YqeBJP82C-meErikOCjwnG4iQSIipWYtyWhFBWthvFDuG8KVvass2c41aUrOXNdrEb4wvGlFSc7xSfd-YdenRnOrDWfKhkvEPK9ejaJQhadUZZ9BD8CkIyEJHX6MHbwb8PkBaDBQdo5sPcJOXQNGYkojeTFmgCabCrIZjeOLNeosnC-lzAKTpDj-Ci8UtIwXRoltb9sF9saWUjHPzEveLpYvo4uSpv7y-vJ2e3ZcdqxkuqqkZX9VyBYJVWc1BYME0pFwJYVWGtRAdNXfWqn3NOG91zDJgIyG1VA2F7xdG4dxX86xpiki9-HVw-KSlltM6yRB4i41AXfIwBtFwFs1RhkATLb9lylC2zbPktW7aZESPzZiwM_wPyZnY-xbTlmaQjGTPkniH8vvT3uS_cb5W1</recordid><startdate>200910</startdate><enddate>200910</enddate><creator>Rehman, Nuzhat</creator><creator>Mir, Mohammad Amin</creator><creator>Jan, Musarat</creator><creator>Amin, Adil</creator><creator>Dar, Aijaz Ahmad</creator><creator>Rather, Ghulam Mohammad</creator><general>Springer-Verlag</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>7QH</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L.G</scope><scope>M2P</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>200910</creationdate><title>Mixed Micellization and Interfacial Properties of Polyoxyethylene Sorbitan Esters with Cetylpyridinium Chloride: A Tensiometric Study</title><author>Rehman, Nuzhat ; 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β
12
), and activity coefficients of the mixed micelles formed with the cationic surfactant cetylpyridinium chloride at 25 °C. The micellar characteristics evaluated using the Clint, Rubingh, and Blankschtein models deviated significantly from ideality, and were used to ascertain the validity of these theories. Thermodynamic stability in terms of Maeda’s approach and interfacial properties is also discussed.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s11743-009-1123-9</doi><tpages>10</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Activity coefficients Aquatic Pollution Chemistry Chemistry and Materials Science Esters Ethoxylated sorbitan esters Industrial Chemistry/Chemical Engineering Interaction parameter Interfacial properties Mixed micellization Original Article Physical Chemistry Polymer Sciences Solvents Surface chemistry Surface tension Surfaces and Interfaces Surfactants Thin Films Waste Water Technology Water Management Water Pollution Control |
| title | Mixed Micellization and Interfacial Properties of Polyoxyethylene Sorbitan Esters with Cetylpyridinium Chloride: A Tensiometric Study |
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