Synthesis and Characterization of Lauryl Trimethyl Ammonium Surfactants with New Counteranion Types
A new family of lauryl trimethyl ammonium surfactants of the general formula CH 3 (CH 2 ) 11 N + (CH 3 ) 3 X − (X = CH 3 OCOO, HCOO, CH 3 COO, CH 3 CHOHCOO) were prepared and characterized both structurally and as aqueous surfactants. Lauryl trimethyl ammonium mono-methyl carbonate was synthesized...
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| Veröffentlicht in: | Journal of surfactants and detergents 2009-10, Vol.12 (4), p.351-354 |
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| creator | Xu, Bao-cai Han, Fu Shui, Jin-huan Zhou, Ya-wen |
| description | A new family of lauryl trimethyl ammonium surfactants of the general formula CH
3
(CH
2
)
11
N
+
(CH
3
)
3
X
−
(X = CH
3
OCOO, HCOO, CH
3
COO, CH
3
CHOHCOO) were prepared and characterized both structurally and as aqueous surfactants. Lauryl trimethyl ammonium mono-methyl carbonate was synthesized by using dimethyl carbonate (DMC) as the alkylating agent and lauryl dimethyl amine as the starting material. The latter compound was reacted with formic acid, acetic acid, and lactic acid, respectively, to give the corresponding quaternary ammonium salts with other counteranions. They were structurally characterized by IR,
1
H NMR, MS. Members of this family reduced the surface tension of water to 32–38 mN/m at concentration levels of 10
−2
mol/L. |
| doi_str_mv | 10.1007/s11743-009-1129-3 |
| format | Article |
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3
(CH
2
)
11
N
+
(CH
3
)
3
X
−
(X = CH
3
OCOO, HCOO, CH
3
COO, CH
3
CHOHCOO) were prepared and characterized both structurally and as aqueous surfactants. Lauryl trimethyl ammonium mono-methyl carbonate was synthesized by using dimethyl carbonate (DMC) as the alkylating agent and lauryl dimethyl amine as the starting material. The latter compound was reacted with formic acid, acetic acid, and lactic acid, respectively, to give the corresponding quaternary ammonium salts with other counteranions. They were structurally characterized by IR,
1
H NMR, MS. Members of this family reduced the surface tension of water to 32–38 mN/m at concentration levels of 10
−2
mol/L.</description><identifier>ISSN: 1097-3958</identifier><identifier>EISSN: 1558-9293</identifier><identifier>DOI: 10.1007/s11743-009-1129-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Acetic acid ; Ammonia ; Ammonium ; Ammonium salts ; Aquatic Pollution ; Aqueous chemistry ; Characterization ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Dimethyl carbonate ; Industrial Chemistry/Chemical Engineering ; Original Article ; Physical Chemistry ; Polymer Sciences ; Quaternary ammonium salt ; Surface tension ; Surfaces and Interfaces ; Surfactants ; Synthesis ; Thin Films ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Journal of surfactants and detergents, 2009-10, Vol.12 (4), p.351-354</ispartof><rights>AOCS 2009</rights><rights>2009 American Oil Chemists' Society (AOCS)</rights><rights>Copyright AOCS Press Oct 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3631-74516f51cc7d9489279e7f4a8a3ea02c5d93cd243096418f69bd6ff59f7d85d13</citedby><cites>FETCH-LOGICAL-c3631-74516f51cc7d9489279e7f4a8a3ea02c5d93cd243096418f69bd6ff59f7d85d13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1007%2Fs11743-009-1129-3$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1007%2Fs11743-009-1129-3$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids></links><search><creatorcontrib>Xu, Bao-cai</creatorcontrib><creatorcontrib>Han, Fu</creatorcontrib><creatorcontrib>Shui, Jin-huan</creatorcontrib><creatorcontrib>Zhou, Ya-wen</creatorcontrib><title>Synthesis and Characterization of Lauryl Trimethyl Ammonium Surfactants with New Counteranion Types</title><title>Journal of surfactants and detergents</title><addtitle>J Surfact Deterg</addtitle><description>A new family of lauryl trimethyl ammonium surfactants of the general formula CH
3
(CH
2
)
11
N
+
(CH
3
)
3
X
−
(X = CH
3
OCOO, HCOO, CH
3
COO, CH
3
CHOHCOO) were prepared and characterized both structurally and as aqueous surfactants. Lauryl trimethyl ammonium mono-methyl carbonate was synthesized by using dimethyl carbonate (DMC) as the alkylating agent and lauryl dimethyl amine as the starting material. The latter compound was reacted with formic acid, acetic acid, and lactic acid, respectively, to give the corresponding quaternary ammonium salts with other counteranions. They were structurally characterized by IR,
1
H NMR, MS. Members of this family reduced the surface tension of water to 32–38 mN/m at concentration levels of 10
−2
mol/L.</description><subject>Acetic acid</subject><subject>Ammonia</subject><subject>Ammonium</subject><subject>Ammonium salts</subject><subject>Aquatic Pollution</subject><subject>Aqueous chemistry</subject><subject>Characterization</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dimethyl carbonate</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Original Article</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Quaternary ammonium salt</subject><subject>Surface tension</subject><subject>Surfaces and Interfaces</subject><subject>Surfactants</subject><subject>Synthesis</subject><subject>Thin Films</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>1097-3958</issn><issn>1558-9293</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFkEtPwzAQhC0EEqXwA7hZ3A1-xLF9rMpbFRxazpZJbJKqcYqdqAq_HkdB4oQ47R7m25kdAC4JviYYi5tIiMgYwlghQqhC7AjMCOcSKarYcdqxEogpLk_BWYxbjCnJOJ-BYj34rrKxjtD4Ei4rE0zR2VB_ma5uPWwdXJk-DDu4CXVjuypti6Zpfd03cN0Hl9TGdxEe6q6CL_YAl23v0wHjR3wz7G08ByfO7KK9-Jlz8HZ_t1k-otXrw9NysUIFyxlBIuMkd5wUhShVJhUVygqXGWmYNZgWvFSsKGnGsMozIl2u3svcOa6cKCUvCZuDq-nuPrSfvY2d3rZ98MlSU8poLqTkSUQmURHaGIN1ep8eM2HQBOuxSj1VqVOVeqxSs8SIiTnUOzv8D-jn9e0dZnyMRCcyJsh_2PAb6W-7byMdh90</recordid><startdate>200910</startdate><enddate>200910</enddate><creator>Xu, Bao-cai</creator><creator>Han, Fu</creator><creator>Shui, Jin-huan</creator><creator>Zhou, Ya-wen</creator><general>Springer-Verlag</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>4T-</scope><scope>7QH</scope><scope>7UA</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>H97</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L.G</scope><scope>M2P</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>200910</creationdate><title>Synthesis and Characterization of Lauryl Trimethyl Ammonium Surfactants with New Counteranion Types</title><author>Xu, Bao-cai ; Han, Fu ; Shui, Jin-huan ; Zhou, Ya-wen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3631-74516f51cc7d9489279e7f4a8a3ea02c5d93cd243096418f69bd6ff59f7d85d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Acetic acid</topic><topic>Ammonia</topic><topic>Ammonium</topic><topic>Ammonium salts</topic><topic>Aquatic Pollution</topic><topic>Aqueous chemistry</topic><topic>Characterization</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dimethyl carbonate</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Original Article</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Quaternary ammonium salt</topic><topic>Surface tension</topic><topic>Surfaces and Interfaces</topic><topic>Surfactants</topic><topic>Synthesis</topic><topic>Thin Films</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Bao-cai</creatorcontrib><creatorcontrib>Han, Fu</creatorcontrib><creatorcontrib>Shui, Jin-huan</creatorcontrib><creatorcontrib>Zhou, Ya-wen</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Docstoc</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of surfactants and detergents</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Bao-cai</au><au>Han, Fu</au><au>Shui, Jin-huan</au><au>Zhou, Ya-wen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of Lauryl Trimethyl Ammonium Surfactants with New Counteranion Types</atitle><jtitle>Journal of surfactants and detergents</jtitle><stitle>J Surfact Deterg</stitle><date>2009-10</date><risdate>2009</risdate><volume>12</volume><issue>4</issue><spage>351</spage><epage>354</epage><pages>351-354</pages><issn>1097-3958</issn><eissn>1558-9293</eissn><abstract>A new family of lauryl trimethyl ammonium surfactants of the general formula CH
3
(CH
2
)
11
N
+
(CH
3
)
3
X
−
(X = CH
3
OCOO, HCOO, CH
3
COO, CH
3
CHOHCOO) were prepared and characterized both structurally and as aqueous surfactants. Lauryl trimethyl ammonium mono-methyl carbonate was synthesized by using dimethyl carbonate (DMC) as the alkylating agent and lauryl dimethyl amine as the starting material. The latter compound was reacted with formic acid, acetic acid, and lactic acid, respectively, to give the corresponding quaternary ammonium salts with other counteranions. They were structurally characterized by IR,
1
H NMR, MS. Members of this family reduced the surface tension of water to 32–38 mN/m at concentration levels of 10
−2
mol/L.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s11743-009-1129-3</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of surfactants and detergents, 2009-10, Vol.12 (4), p.351-354 |
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| source | Wiley Online Library All Journals |
| subjects | Acetic acid Ammonia Ammonium Ammonium salts Aquatic Pollution Aqueous chemistry Characterization Chemical synthesis Chemistry Chemistry and Materials Science Dimethyl carbonate Industrial Chemistry/Chemical Engineering Original Article Physical Chemistry Polymer Sciences Quaternary ammonium salt Surface tension Surfaces and Interfaces Surfactants Synthesis Thin Films Waste Water Technology Water Management Water Pollution Control |
| title | Synthesis and Characterization of Lauryl Trimethyl Ammonium Surfactants with New Counteranion Types |
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