Intercalation of n-alkylamines and alkylene diamines into carboxyl functionalized lamellar-type silsesquioxane
A sol–gel-derived carboxyl-functionalized lamellar-type silsesquioxane was prepared to investigate its potential for use as a host material for intercalation reactions with n-alkylamines and alkylene diamines. Upon intercalation of n-alkylamines and alkylene diamines, the interlayer distances increa...
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| Veröffentlicht in: | Journal of the Ceramic Society of Japan 2016-10, Vol.124 (10), p.1090-1093 |
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| container_issue | 10 |
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| container_title | Journal of the Ceramic Society of Japan |
| container_volume | 124 |
| creator | OHSHITA, Hironori ITO, Machi IDOTA, Naokazu MEHDI, Ahmad BOURY, Bruno SUGAHARA, Yoshiyuki |
| description | A sol–gel-derived carboxyl-functionalized lamellar-type silsesquioxane was prepared to investigate its potential for use as a host material for intercalation reactions with n-alkylamines and alkylene diamines. Upon intercalation of n-alkylamines and alkylene diamines, the interlayer distances increased as shown by X-ray powder diffraction patterns, and IR spectra showed the presence of absorption bands attributable to ν(COO−) and δ(NH3+) modes. The amounts of intercalated n-alkylamines were determined from n-CnH2n+1NH2/–COOH molar ratios which, based on CHN analysis, exhibited values from 0.76 to 0.88; whereas the values determined for the alkylene diamines were 0.83 (NH2C4H8NH2), 0.45 (NH2C8H16NH2) and 0.33 (NH2C12H24NH2). These results show that intercalation of n-alkylamines and alkylene diamines into lamellar-type silsesquioxane bearing carboxyl groups proceeded successfully via acid-base mechanisms. |
| doi_str_mv | 10.2109/jcersj2.16161 |
| format | Article |
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Upon intercalation of n-alkylamines and alkylene diamines, the interlayer distances increased as shown by X-ray powder diffraction patterns, and IR spectra showed the presence of absorption bands attributable to ν(COO−) and δ(NH3+) modes. The amounts of intercalated n-alkylamines were determined from n-CnH2n+1NH2/–COOH molar ratios which, based on CHN analysis, exhibited values from 0.76 to 0.88; whereas the values determined for the alkylene diamines were 0.83 (NH2C4H8NH2), 0.45 (NH2C8H16NH2) and 0.33 (NH2C12H24NH2). These results show that intercalation of n-alkylamines and alkylene diamines into lamellar-type silsesquioxane bearing carboxyl groups proceeded successfully via acid-base mechanisms.</description><identifier>ISSN: 1882-0743</identifier><identifier>EISSN: 1348-6535</identifier><identifier>DOI: 10.2109/jcersj2.16161</identifier><language>eng</language><publisher>Tokyo: Japan Science and Technology Agency</publisher><subject>Absorption spectra ; Alkylamines ; Ammonia ; Diamines ; Diffraction patterns ; Infrared spectroscopy ; Intercalation ; Interlayers ; Lamellar structure ; Sol-gel processes ; X ray powder diffraction</subject><ispartof>Journal of the Ceramic Society of Japan, 2016-10, Vol.124 (10), p.1090-1093</ispartof><rights>Copyright Japan Science and Technology Agency 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c260t-604aa1312588f57dc96f1d2785ce603e5cb19528637aada2b24375cc1ba47c583</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>OHSHITA, Hironori</creatorcontrib><creatorcontrib>ITO, Machi</creatorcontrib><creatorcontrib>IDOTA, Naokazu</creatorcontrib><creatorcontrib>MEHDI, Ahmad</creatorcontrib><creatorcontrib>BOURY, Bruno</creatorcontrib><creatorcontrib>SUGAHARA, Yoshiyuki</creatorcontrib><title>Intercalation of n-alkylamines and alkylene diamines into carboxyl functionalized lamellar-type silsesquioxane</title><title>Journal of the Ceramic Society of Japan</title><description>A sol–gel-derived carboxyl-functionalized lamellar-type silsesquioxane was prepared to investigate its potential for use as a host material for intercalation reactions with n-alkylamines and alkylene diamines. Upon intercalation of n-alkylamines and alkylene diamines, the interlayer distances increased as shown by X-ray powder diffraction patterns, and IR spectra showed the presence of absorption bands attributable to ν(COO−) and δ(NH3+) modes. The amounts of intercalated n-alkylamines were determined from n-CnH2n+1NH2/–COOH molar ratios which, based on CHN analysis, exhibited values from 0.76 to 0.88; whereas the values determined for the alkylene diamines were 0.83 (NH2C4H8NH2), 0.45 (NH2C8H16NH2) and 0.33 (NH2C12H24NH2). These results show that intercalation of n-alkylamines and alkylene diamines into lamellar-type silsesquioxane bearing carboxyl groups proceeded successfully via acid-base mechanisms.</description><subject>Absorption spectra</subject><subject>Alkylamines</subject><subject>Ammonia</subject><subject>Diamines</subject><subject>Diffraction patterns</subject><subject>Infrared spectroscopy</subject><subject>Intercalation</subject><subject>Interlayers</subject><subject>Lamellar structure</subject><subject>Sol-gel processes</subject><subject>X ray powder diffraction</subject><issn>1882-0743</issn><issn>1348-6535</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNotUMtqwzAQFKWFpmmPvQt6VqqHJcvHEvoIBHppz2YtyyBXkRLJhrhfX6cJe9jdYWbYHYQeGV1xRqvn3tiUe75iaq4rtGCi0ERJIa_nWWtOaFmIW3SXc0-p4oXQCxQ2YbDJgIfBxYBjhwMB_zN52LlgM4bQ4v_dBotbd0FdGCI2kJp4nDzuxmBOavDu17Z4llrvIZFh2lucnc82H0YXjxDsPbrpYAYeLn2Jvt9ev9YfZPv5vlm_bInhig5E0QKACcal1p0sW1OpjrW81NJYRYWVpmGV5FqJEqAF3szPlNIY1kBRGqnFEj2dffcpHkabh7qPY5ovzDXngstKl_zEImeWSTHnZLt6n9wO0lQzWp8irS-R1v-Rij8g9G02</recordid><startdate>20161001</startdate><enddate>20161001</enddate><creator>OHSHITA, Hironori</creator><creator>ITO, Machi</creator><creator>IDOTA, Naokazu</creator><creator>MEHDI, Ahmad</creator><creator>BOURY, Bruno</creator><creator>SUGAHARA, Yoshiyuki</creator><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20161001</creationdate><title>Intercalation of n-alkylamines and alkylene diamines into carboxyl functionalized lamellar-type silsesquioxane</title><author>OHSHITA, Hironori ; ITO, Machi ; IDOTA, Naokazu ; MEHDI, Ahmad ; BOURY, Bruno ; SUGAHARA, Yoshiyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c260t-604aa1312588f57dc96f1d2785ce603e5cb19528637aada2b24375cc1ba47c583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Absorption spectra</topic><topic>Alkylamines</topic><topic>Ammonia</topic><topic>Diamines</topic><topic>Diffraction patterns</topic><topic>Infrared spectroscopy</topic><topic>Intercalation</topic><topic>Interlayers</topic><topic>Lamellar structure</topic><topic>Sol-gel processes</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>OHSHITA, Hironori</creatorcontrib><creatorcontrib>ITO, Machi</creatorcontrib><creatorcontrib>IDOTA, Naokazu</creatorcontrib><creatorcontrib>MEHDI, Ahmad</creatorcontrib><creatorcontrib>BOURY, Bruno</creatorcontrib><creatorcontrib>SUGAHARA, Yoshiyuki</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the Ceramic Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>OHSHITA, Hironori</au><au>ITO, Machi</au><au>IDOTA, Naokazu</au><au>MEHDI, Ahmad</au><au>BOURY, Bruno</au><au>SUGAHARA, Yoshiyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Intercalation of n-alkylamines and alkylene diamines into carboxyl functionalized lamellar-type silsesquioxane</atitle><jtitle>Journal of the Ceramic Society of Japan</jtitle><date>2016-10-01</date><risdate>2016</risdate><volume>124</volume><issue>10</issue><spage>1090</spage><epage>1093</epage><pages>1090-1093</pages><issn>1882-0743</issn><eissn>1348-6535</eissn><abstract>A sol–gel-derived carboxyl-functionalized lamellar-type silsesquioxane was prepared to investigate its potential for use as a host material for intercalation reactions with n-alkylamines and alkylene diamines. Upon intercalation of n-alkylamines and alkylene diamines, the interlayer distances increased as shown by X-ray powder diffraction patterns, and IR spectra showed the presence of absorption bands attributable to ν(COO−) and δ(NH3+) modes. The amounts of intercalated n-alkylamines were determined from n-CnH2n+1NH2/–COOH molar ratios which, based on CHN analysis, exhibited values from 0.76 to 0.88; whereas the values determined for the alkylene diamines were 0.83 (NH2C4H8NH2), 0.45 (NH2C8H16NH2) and 0.33 (NH2C12H24NH2). These results show that intercalation of n-alkylamines and alkylene diamines into lamellar-type silsesquioxane bearing carboxyl groups proceeded successfully via acid-base mechanisms.</abstract><cop>Tokyo</cop><pub>Japan Science and Technology Agency</pub><doi>10.2109/jcersj2.16161</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1882-0743 |
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| issn | 1882-0743 1348-6535 |
| language | eng |
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| source | J-STAGE Free |
| subjects | Absorption spectra Alkylamines Ammonia Diamines Diffraction patterns Infrared spectroscopy Intercalation Interlayers Lamellar structure Sol-gel processes X ray powder diffraction |
| title | Intercalation of n-alkylamines and alkylene diamines into carboxyl functionalized lamellar-type silsesquioxane |
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