Disappearance of Reflection Color by Photopolymerization of Lyotropic Cholesteric Liquid Crystals from Cellulose Derivatives
In this communication, we report on the disappearance of reflection color by photopolymerization of an acrylate monomer in lyotropic cholesteric liquid crystals from a cellulose derivative for color image applications. When a hydroxypropyl cellulose (HPC) derivative possessing propionyl side chains...
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| Veröffentlicht in: | Journal of Photopolymer Science and Technology 2018/06/25, Vol.31(4), pp.563-567 |
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| container_title | Journal of Photopolymer Science and Technology |
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| creator | Fukawa, Masashi Suzuki, Kana Furumi, Seiichi |
| description | In this communication, we report on the disappearance of reflection color by photopolymerization of an acrylate monomer in lyotropic cholesteric liquid crystals from a cellulose derivative for color image applications. When a hydroxypropyl cellulose (HPC) derivative possessing propionyl side chains (HPC-Pr) was homogeneously dissolved in a liquid monomer of 4-hydroxybutyl acrylate (4HBA), we obtained lyotropic cholesteric liquid crystals (HPC-Pr_4HBA) with a Bragg reflection peak in the visible wavelength range. Such reflection wavelength was controllable by not only temperature, but also concentration of HPC-Pr in 4HBA. We found that Bragg reflection peak of lyotropic HPC-Pr_4HBA mixture disappears by photopolymerization of 4HBA, thereby leading to the fabrication of a photolithographic color image. This report provides promising clues to fabricate intriguing photonic devices adopted with cellulose derivatives by utilizing such Bragg reflection characteristics. |
| doi_str_mv | 10.2494/photopolymer.31.563 |
| format | Article |
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When a hydroxypropyl cellulose (HPC) derivative possessing propionyl side chains (HPC-Pr) was homogeneously dissolved in a liquid monomer of 4-hydroxybutyl acrylate (4HBA), we obtained lyotropic cholesteric liquid crystals (HPC-Pr_4HBA) with a Bragg reflection peak in the visible wavelength range. Such reflection wavelength was controllable by not only temperature, but also concentration of HPC-Pr in 4HBA. We found that Bragg reflection peak of lyotropic HPC-Pr_4HBA mixture disappears by photopolymerization of 4HBA, thereby leading to the fabrication of a photolithographic color image. This report provides promising clues to fabricate intriguing photonic devices adopted with cellulose derivatives by utilizing such Bragg reflection characteristics.</description><identifier>ISSN: 0914-9244</identifier><identifier>EISSN: 1349-6336</identifier><identifier>DOI: 10.2494/photopolymer.31.563</identifier><language>eng</language><publisher>Hiratsuka: The Society of Photopolymer Science and Technology(SPST)</publisher><subject>Bragg reflection ; Cellulose ; Cholesteric liquid crystals ; Color image ; Color imagery ; Crystals ; Derivatives ; Hydroxypropyl cellulose ; Lyotropic liquid crystals ; Monomers ; Photolithography ; Photonics ; Photopolymerization ; Wave reflection</subject><ispartof>Journal of Photopolymer Science and Technology, 2018/06/25, Vol.31(4), pp.563-567</ispartof><rights>2018 The Society of Photopolymer Science and Technology (SPST)</rights><rights>Copyright Japan Science and Technology Agency 2018</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c572t-91989c69ff44224b2d79e711c6e0b0e32c480428952a397758f5264cbf05baaf3</citedby><cites>FETCH-LOGICAL-c572t-91989c69ff44224b2d79e711c6e0b0e32c480428952a397758f5264cbf05baaf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1877,27901,27902</link.rule.ids></links><search><creatorcontrib>Fukawa, Masashi</creatorcontrib><creatorcontrib>Suzuki, Kana</creatorcontrib><creatorcontrib>Furumi, Seiichi</creatorcontrib><title>Disappearance of Reflection Color by Photopolymerization of Lyotropic Cholesteric Liquid Crystals from Cellulose Derivatives</title><title>Journal of Photopolymer Science and Technology</title><addtitle>J. Photopol. Sci. Technol.</addtitle><description>In this communication, we report on the disappearance of reflection color by photopolymerization of an acrylate monomer in lyotropic cholesteric liquid crystals from a cellulose derivative for color image applications. When a hydroxypropyl cellulose (HPC) derivative possessing propionyl side chains (HPC-Pr) was homogeneously dissolved in a liquid monomer of 4-hydroxybutyl acrylate (4HBA), we obtained lyotropic cholesteric liquid crystals (HPC-Pr_4HBA) with a Bragg reflection peak in the visible wavelength range. Such reflection wavelength was controllable by not only temperature, but also concentration of HPC-Pr in 4HBA. We found that Bragg reflection peak of lyotropic HPC-Pr_4HBA mixture disappears by photopolymerization of 4HBA, thereby leading to the fabrication of a photolithographic color image. This report provides promising clues to fabricate intriguing photonic devices adopted with cellulose derivatives by utilizing such Bragg reflection characteristics.</description><subject>Bragg reflection</subject><subject>Cellulose</subject><subject>Cholesteric liquid crystals</subject><subject>Color image</subject><subject>Color imagery</subject><subject>Crystals</subject><subject>Derivatives</subject><subject>Hydroxypropyl cellulose</subject><subject>Lyotropic liquid crystals</subject><subject>Monomers</subject><subject>Photolithography</subject><subject>Photonics</subject><subject>Photopolymerization</subject><subject>Wave reflection</subject><issn>0914-9244</issn><issn>1349-6336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNplkM1KAzEURoMoWKtP4Cbgemp-Z5qljFaFgiK6Dpl4Y6ekzZhMCyM-vNEWEVxlcc_5bu6H0DklEyaUuOwWoQ9d8MMK4oTTiSz5ARpRLlRRcl4eohFRVBSKCXGMTlJaEsK5lGqEPq_bZLoOTDRrCzg4_ATOg-3bsMZ18CHiZsCPf_LbD_MzzOh8CH0MXWtxvQgeUp-nFs_b9037ius4pN74hF0MK1yD9xsfEuDrDG1zxBbSKTpymYCz_TtGL7Ob5_qumD_c3tdX88LKivWFomqqbKmcE4Ix0bDXSkFFqS2BNAQ4s2JKBJsqyQxXVSWnTrJS2MYR2Rjj-Bhd7HK7GN43-Z96GTZxnVdqxjiTqqxIlSm-o2wMKUVwuovtysRBU6K_a9Z_a9ac6lxztmY7a5mvfYNfx8S-tR7-OWIv_gJ2YaKGNf8CMPSRrw</recordid><startdate>20180625</startdate><enddate>20180625</enddate><creator>Fukawa, Masashi</creator><creator>Suzuki, Kana</creator><creator>Furumi, Seiichi</creator><general>The Society of Photopolymer Science and Technology(SPST)</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20180625</creationdate><title>Disappearance of Reflection Color by Photopolymerization of Lyotropic Cholesteric Liquid Crystals from Cellulose Derivatives</title><author>Fukawa, Masashi ; Suzuki, Kana ; Furumi, Seiichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c572t-91989c69ff44224b2d79e711c6e0b0e32c480428952a397758f5264cbf05baaf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Bragg reflection</topic><topic>Cellulose</topic><topic>Cholesteric liquid crystals</topic><topic>Color image</topic><topic>Color imagery</topic><topic>Crystals</topic><topic>Derivatives</topic><topic>Hydroxypropyl cellulose</topic><topic>Lyotropic liquid crystals</topic><topic>Monomers</topic><topic>Photolithography</topic><topic>Photonics</topic><topic>Photopolymerization</topic><topic>Wave reflection</topic><toplevel>online_resources</toplevel><creatorcontrib>Fukawa, Masashi</creatorcontrib><creatorcontrib>Suzuki, Kana</creatorcontrib><creatorcontrib>Furumi, Seiichi</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of Photopolymer Science and Technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fukawa, Masashi</au><au>Suzuki, Kana</au><au>Furumi, Seiichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Disappearance of Reflection Color by Photopolymerization of Lyotropic Cholesteric Liquid Crystals from Cellulose Derivatives</atitle><jtitle>Journal of Photopolymer Science and Technology</jtitle><addtitle>J. Photopol. Sci. Technol.</addtitle><date>2018-06-25</date><risdate>2018</risdate><volume>31</volume><issue>4</issue><spage>563</spage><epage>567</epage><pages>563-567</pages><issn>0914-9244</issn><eissn>1349-6336</eissn><abstract>In this communication, we report on the disappearance of reflection color by photopolymerization of an acrylate monomer in lyotropic cholesteric liquid crystals from a cellulose derivative for color image applications. When a hydroxypropyl cellulose (HPC) derivative possessing propionyl side chains (HPC-Pr) was homogeneously dissolved in a liquid monomer of 4-hydroxybutyl acrylate (4HBA), we obtained lyotropic cholesteric liquid crystals (HPC-Pr_4HBA) with a Bragg reflection peak in the visible wavelength range. Such reflection wavelength was controllable by not only temperature, but also concentration of HPC-Pr in 4HBA. We found that Bragg reflection peak of lyotropic HPC-Pr_4HBA mixture disappears by photopolymerization of 4HBA, thereby leading to the fabrication of a photolithographic color image. This report provides promising clues to fabricate intriguing photonic devices adopted with cellulose derivatives by utilizing such Bragg reflection characteristics.</abstract><cop>Hiratsuka</cop><pub>The Society of Photopolymer Science and Technology(SPST)</pub><doi>10.2494/photopolymer.31.563</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Bragg reflection Cellulose Cholesteric liquid crystals Color image Color imagery Crystals Derivatives Hydroxypropyl cellulose Lyotropic liquid crystals Monomers Photolithography Photonics Photopolymerization Wave reflection |
| title | Disappearance of Reflection Color by Photopolymerization of Lyotropic Cholesteric Liquid Crystals from Cellulose Derivatives |
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