Self-assembling Properties of an N-Heterocyclic Carbene-based Metallosurfactant: Pd-Coordination Induced Formation of Reactive Interfaces in Water

In this study, an N-heterocyclic carbene (NHC)-based metallosurfactant (MS), NHC-PdMS, was synthesized, where Pd(II) was bound to the NHC framework via a robust Pd–carbene bond with NEt3 as a co-ligand. Surface tension measurements revealed that the critical micelle concentration (CMC) of NHC-PdMS (...

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Veröffentlicht in:	Journal of Oleo Science 2018, Vol.67(9), pp.1107-1115
Hauptverfasser:	Taira, Toshiaki, Yanagimoto, Takaya, Sakai, Kenichi, Sakai, Hideki, Endo, Akira, Imura, Tomohiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalysis Coordination Iodides liquid crystal Liquid crystals metallosurfactant Micelles Mizoroki-Heck reaction N-heterocyclic carbene Organic chemistry palladium Precursors Small angle X ray scattering Surface tension
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