Trinuclear and Mononuclear Lanthanoid Complexes Containing 2‐Methyl‐8‐quinolinolate: Synthesis, Structures, and Magnetic Properties

Two series of new lanthanoid complexes containing 2‐methyl‐8‐quinolinolate (MQ–) have been prepared at elevated temperatures. Lighter elements yield trinuclear complexes [Ln3(MQ)9(HMQ)]·5H2O·3MeOH (1Ln, where Ln = Pr, Eu, Gd, Tb, Dy and Ho) by solvothermal reactions, and heavier lanthanoids yield th...

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Veröffentlicht in:	European journal of inorganic chemistry 2019-06, Vol.2019 (20), p.2549-2557
Hauptverfasser:	Ghazali, Nurul F., Phonsri, Wasinee, Murray, Keith S., Junk, Peter C., Deacon, Glen B., Turner, David R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Antiferromagnetism Dysprosium Erbium Gadolinium High temperature Inorganic chemistry Lanthanide contraction Lanthanides Magnetic induction Magnetic properties Magnetic relaxation Magnetism Quinaldinolate Structure elucidation Ytterbium
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