(Epoxidized castor oil – citric acid) copolyester as a candidate polymer for biomedical applications
Vegetable oil-based polymers are attractive regarding environmental concerns to produce polymers through an environmentally friendly process to noble applications, as the biomedical ones. Epoxidized vegetable oils can be used as a comonomer; however, its polymerization processes commonly use toxic r...
Gespeichert in:
| Veröffentlicht in: | Journal of polymer research 2019-06, Vol.26 (6), p.1-10, Article 149 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 10 |
|---|---|
| container_issue | 6 |
| container_start_page | 1 |
| container_title | Journal of polymer research |
| container_volume | 26 |
| creator | Parada Hernandez, Natalia L. Bahú, Juliana O. Schiavon, Maria Ingrid R. B. Bonon, Anderson J. Benites, Cibelem I. Jardini, André L. Maciel Filho, Rubens Wolf Maciel, Maria Regina |
| description | Vegetable oil-based polymers are attractive regarding environmental concerns to produce polymers through an environmentally friendly process to noble applications, as the biomedical ones. Epoxidized vegetable oils can be used as a comonomer; however, its polymerization processes commonly use toxic raw materials which do not enable its use for biomedical application. In this paper is presented the synthesis procedure for a copolyester derived from epoxidized castor oil and citric acid, using a green route approach, with non-toxic solvents and reagents, without the use of catalysts or initiators, and no production of hazardous residues. Fourier transform infrared spectroscopy presented the infrared absorption bands of the copolyester. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) revealed good thermal stability (190 °C) and an elastomeric behavior (T
g
|
| doi_str_mv | 10.1007/s10965-019-1814-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2231976157</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2231976157</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-34a149367c7de18fb3b123d054460ddee3fbcbce279b69a2e55fad414232b1b33</originalsourceid><addsrcrecordid>eNp1kMtKBDEQRYMoOI5-gLuAG11EU0mnH0sZxgcMuNF1yKslQ0-nTXrAceU_-Id-iRlacOWqLlX3VhUHoXOg10BpdZOANqUgFBoCNRREHKAZiIqRuuHiMGvKGGmqkh6jk5TWlApRlfUMtZfLIbx76z-cxUalMUQcfIe_P7-w8WP0Bivj7RU2YQjdzqXRRawSVtncW2_V6PB-sMntNme1DxtnvVEdVsPQZTH60KdTdNSqLrmz3zpHL3fL58UDWT3dPy5uV8RwKEfCCwVFw8vKVNZB3WqugXFLRVGU1FrneKuNNo5VjS4bxZwQrbIFFIwzDZrzObqY9g4xvG3zt3IdtrHPJyVjHDKADCW7YHKZGFKKrpVD9BsVdxKo3OOUE06Zcco9Tilyhk2ZlL39q4t_m_8P_QDWTXmc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2231976157</pqid></control><display><type>article</type><title>(Epoxidized castor oil – citric acid) copolyester as a candidate polymer for biomedical applications</title><source>SpringerLink Journals - AutoHoldings</source><creator>Parada Hernandez, Natalia L. ; Bahú, Juliana O. ; Schiavon, Maria Ingrid R. B. ; Bonon, Anderson J. ; Benites, Cibelem I. ; Jardini, André L. ; Maciel Filho, Rubens ; Wolf Maciel, Maria Regina</creator><creatorcontrib>Parada Hernandez, Natalia L. ; Bahú, Juliana O. ; Schiavon, Maria Ingrid R. B. ; Bonon, Anderson J. ; Benites, Cibelem I. ; Jardini, André L. ; Maciel Filho, Rubens ; Wolf Maciel, Maria Regina</creatorcontrib><description>Vegetable oil-based polymers are attractive regarding environmental concerns to produce polymers through an environmentally friendly process to noble applications, as the biomedical ones. Epoxidized vegetable oils can be used as a comonomer; however, its polymerization processes commonly use toxic raw materials which do not enable its use for biomedical application. In this paper is presented the synthesis procedure for a copolyester derived from epoxidized castor oil and citric acid, using a green route approach, with non-toxic solvents and reagents, without the use of catalysts or initiators, and no production of hazardous residues. Fourier transform infrared spectroscopy presented the infrared absorption bands of the copolyester. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) revealed good thermal stability (190 °C) and an elastomeric behavior (T
g
< 5 °C). Absorption capacity and gel fraction analysis indirectly showed the influence of the citric acid in the degree of reticulation. The cell colonization viability of the copolyester surface was evaluated by scanning electron microscopy (SEM), and the direct toxicity assessment investigated its non-toxic response. These results suggest the potential for biomedical application of the (epoxidized castor oil - citric acid) copolyester.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-019-1814-5</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Absorption spectra ; Acids ; Biocompatibility ; Biomedical materials ; Castor oil ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Citric acid ; Differential scanning calorimetry ; Elastomers ; Fourier transforms ; Industrial Chemistry/Chemical Engineering ; Infrared absorption ; Infrared analysis ; Initiators ; Original Paper ; Polymer Sciences ; Raw materials ; Reagents ; Scanning electron microscopy ; Stability analysis ; Thermal stability ; Thermogravimetric analysis ; Toxicity ; Vegetable oils ; Vegetables ; Viability</subject><ispartof>Journal of polymer research, 2019-06, Vol.26 (6), p.1-10, Article 149</ispartof><rights>The Polymer Society, Taipei 2019. corrected publication 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-34a149367c7de18fb3b123d054460ddee3fbcbce279b69a2e55fad414232b1b33</citedby><cites>FETCH-LOGICAL-c316t-34a149367c7de18fb3b123d054460ddee3fbcbce279b69a2e55fad414232b1b33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-019-1814-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-019-1814-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Parada Hernandez, Natalia L.</creatorcontrib><creatorcontrib>Bahú, Juliana O.</creatorcontrib><creatorcontrib>Schiavon, Maria Ingrid R. B.</creatorcontrib><creatorcontrib>Bonon, Anderson J.</creatorcontrib><creatorcontrib>Benites, Cibelem I.</creatorcontrib><creatorcontrib>Jardini, André L.</creatorcontrib><creatorcontrib>Maciel Filho, Rubens</creatorcontrib><creatorcontrib>Wolf Maciel, Maria Regina</creatorcontrib><title>(Epoxidized castor oil – citric acid) copolyester as a candidate polymer for biomedical applications</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>Vegetable oil-based polymers are attractive regarding environmental concerns to produce polymers through an environmentally friendly process to noble applications, as the biomedical ones. Epoxidized vegetable oils can be used as a comonomer; however, its polymerization processes commonly use toxic raw materials which do not enable its use for biomedical application. In this paper is presented the synthesis procedure for a copolyester derived from epoxidized castor oil and citric acid, using a green route approach, with non-toxic solvents and reagents, without the use of catalysts or initiators, and no production of hazardous residues. Fourier transform infrared spectroscopy presented the infrared absorption bands of the copolyester. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) revealed good thermal stability (190 °C) and an elastomeric behavior (T
g
< 5 °C). Absorption capacity and gel fraction analysis indirectly showed the influence of the citric acid in the degree of reticulation. The cell colonization viability of the copolyester surface was evaluated by scanning electron microscopy (SEM), and the direct toxicity assessment investigated its non-toxic response. These results suggest the potential for biomedical application of the (epoxidized castor oil - citric acid) copolyester.</description><subject>Absorption spectra</subject><subject>Acids</subject><subject>Biocompatibility</subject><subject>Biomedical materials</subject><subject>Castor oil</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Citric acid</subject><subject>Differential scanning calorimetry</subject><subject>Elastomers</subject><subject>Fourier transforms</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared absorption</subject><subject>Infrared analysis</subject><subject>Initiators</subject><subject>Original Paper</subject><subject>Polymer Sciences</subject><subject>Raw materials</subject><subject>Reagents</subject><subject>Scanning electron microscopy</subject><subject>Stability analysis</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><subject>Toxicity</subject><subject>Vegetable oils</subject><subject>Vegetables</subject><subject>Viability</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKBDEQRYMoOI5-gLuAG11EU0mnH0sZxgcMuNF1yKslQ0-nTXrAceU_-Id-iRlacOWqLlX3VhUHoXOg10BpdZOANqUgFBoCNRREHKAZiIqRuuHiMGvKGGmqkh6jk5TWlApRlfUMtZfLIbx76z-cxUalMUQcfIe_P7-w8WP0Bivj7RU2YQjdzqXRRawSVtncW2_V6PB-sMntNme1DxtnvVEdVsPQZTH60KdTdNSqLrmz3zpHL3fL58UDWT3dPy5uV8RwKEfCCwVFw8vKVNZB3WqugXFLRVGU1FrneKuNNo5VjS4bxZwQrbIFFIwzDZrzObqY9g4xvG3zt3IdtrHPJyVjHDKADCW7YHKZGFKKrpVD9BsVdxKo3OOUE06Zcco9Tilyhk2ZlL39q4t_m_8P_QDWTXmc</recordid><startdate>20190601</startdate><enddate>20190601</enddate><creator>Parada Hernandez, Natalia L.</creator><creator>Bahú, Juliana O.</creator><creator>Schiavon, Maria Ingrid R. B.</creator><creator>Bonon, Anderson J.</creator><creator>Benites, Cibelem I.</creator><creator>Jardini, André L.</creator><creator>Maciel Filho, Rubens</creator><creator>Wolf Maciel, Maria Regina</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20190601</creationdate><title>(Epoxidized castor oil – citric acid) copolyester as a candidate polymer for biomedical applications</title><author>Parada Hernandez, Natalia L. ; Bahú, Juliana O. ; Schiavon, Maria Ingrid R. B. ; Bonon, Anderson J. ; Benites, Cibelem I. ; Jardini, André L. ; Maciel Filho, Rubens ; Wolf Maciel, Maria Regina</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-34a149367c7de18fb3b123d054460ddee3fbcbce279b69a2e55fad414232b1b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Absorption spectra</topic><topic>Acids</topic><topic>Biocompatibility</topic><topic>Biomedical materials</topic><topic>Castor oil</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Citric acid</topic><topic>Differential scanning calorimetry</topic><topic>Elastomers</topic><topic>Fourier transforms</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared absorption</topic><topic>Infrared analysis</topic><topic>Initiators</topic><topic>Original Paper</topic><topic>Polymer Sciences</topic><topic>Raw materials</topic><topic>Reagents</topic><topic>Scanning electron microscopy</topic><topic>Stability analysis</topic><topic>Thermal stability</topic><topic>Thermogravimetric analysis</topic><topic>Toxicity</topic><topic>Vegetable oils</topic><topic>Vegetables</topic><topic>Viability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Parada Hernandez, Natalia L.</creatorcontrib><creatorcontrib>Bahú, Juliana O.</creatorcontrib><creatorcontrib>Schiavon, Maria Ingrid R. B.</creatorcontrib><creatorcontrib>Bonon, Anderson J.</creatorcontrib><creatorcontrib>Benites, Cibelem I.</creatorcontrib><creatorcontrib>Jardini, André L.</creatorcontrib><creatorcontrib>Maciel Filho, Rubens</creatorcontrib><creatorcontrib>Wolf Maciel, Maria Regina</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Parada Hernandez, Natalia L.</au><au>Bahú, Juliana O.</au><au>Schiavon, Maria Ingrid R. B.</au><au>Bonon, Anderson J.</au><au>Benites, Cibelem I.</au><au>Jardini, André L.</au><au>Maciel Filho, Rubens</au><au>Wolf Maciel, Maria Regina</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>(Epoxidized castor oil – citric acid) copolyester as a candidate polymer for biomedical applications</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2019-06-01</date><risdate>2019</risdate><volume>26</volume><issue>6</issue><spage>1</spage><epage>10</epage><pages>1-10</pages><artnum>149</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>Vegetable oil-based polymers are attractive regarding environmental concerns to produce polymers through an environmentally friendly process to noble applications, as the biomedical ones. Epoxidized vegetable oils can be used as a comonomer; however, its polymerization processes commonly use toxic raw materials which do not enable its use for biomedical application. In this paper is presented the synthesis procedure for a copolyester derived from epoxidized castor oil and citric acid, using a green route approach, with non-toxic solvents and reagents, without the use of catalysts or initiators, and no production of hazardous residues. Fourier transform infrared spectroscopy presented the infrared absorption bands of the copolyester. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) revealed good thermal stability (190 °C) and an elastomeric behavior (T
g
< 5 °C). Absorption capacity and gel fraction analysis indirectly showed the influence of the citric acid in the degree of reticulation. The cell colonization viability of the copolyester surface was evaluated by scanning electron microscopy (SEM), and the direct toxicity assessment investigated its non-toxic response. These results suggest the potential for biomedical application of the (epoxidized castor oil - citric acid) copolyester.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-019-1814-5</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-9760 |
| ispartof | Journal of polymer research, 2019-06, Vol.26 (6), p.1-10, Article 149 |
| issn | 1022-9760 1572-8935 |
| language | eng |
| recordid | cdi_proquest_journals_2231976157 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Absorption spectra Acids Biocompatibility Biomedical materials Castor oil Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Citric acid Differential scanning calorimetry Elastomers Fourier transforms Industrial Chemistry/Chemical Engineering Infrared absorption Infrared analysis Initiators Original Paper Polymer Sciences Raw materials Reagents Scanning electron microscopy Stability analysis Thermal stability Thermogravimetric analysis Toxicity Vegetable oils Vegetables Viability |
| title | (Epoxidized castor oil – citric acid) copolyester as a candidate polymer for biomedical applications |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T06%3A13%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=(Epoxidized%20castor%20oil%20%E2%80%93%20citric%20acid)%20copolyester%20as%20a%20candidate%20polymer%20for%20biomedical%20applications&rft.jtitle=Journal%20of%20polymer%20research&rft.au=Parada%20Hernandez,%20Natalia%20L.&rft.date=2019-06-01&rft.volume=26&rft.issue=6&rft.spage=1&rft.epage=10&rft.pages=1-10&rft.artnum=149&rft.issn=1022-9760&rft.eissn=1572-8935&rft_id=info:doi/10.1007/s10965-019-1814-5&rft_dat=%3Cproquest_cross%3E2231976157%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2231976157&rft_id=info:pmid/&rfr_iscdi=true |