High Efficiency Planar p‐i‐n Perovskite Solar Cells Using Low‐Cost Fluorene‐Based Hole Transporting Material

For commercial applications, it is a challenge to find suitable and low‐cost hole‐transporting material (HTM) in perovskite solar cells (PSCs), where high efficiency spiro‐OMeTAD and PTAA are expensive. A HTM based on 9,9‐dihexyl‐9H‐fluorene and N,N‐di‐p‐methylthiophenylamine (denoted as FMT) is des...

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Veröffentlicht in:Advanced functional materials 2019-05, Vol.29 (22), p.n/a
Hauptverfasser: Zhang, Jing, Sun, Quan, Chen, Qiaoyun, Wang, Yikai, Zhou, Yi, Song, Bo, Yuan, Ningyi, Ding, Jianning, Li, Yongfang
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container_issue 22
container_start_page
container_title Advanced functional materials
container_volume 29
creator Zhang, Jing
Sun, Quan
Chen, Qiaoyun
Wang, Yikai
Zhou, Yi
Song, Bo
Yuan, Ningyi
Ding, Jianning
Li, Yongfang
description For commercial applications, it is a challenge to find suitable and low‐cost hole‐transporting material (HTM) in perovskite solar cells (PSCs), where high efficiency spiro‐OMeTAD and PTAA are expensive. A HTM based on 9,9‐dihexyl‐9H‐fluorene and N,N‐di‐p‐methylthiophenylamine (denoted as FMT) is designed and synthesized. High‐yield FMT with a linear structure is synthesized in two steps. The dopant‐free FMT‐based planar p‐i‐n perovskite solar cells (pp‐PSCs) exhibit a high power conversion efficiency (PCE) of 19.06%, which is among the highest PCEs reported for the pp‐PSCs based on organic HTM. For comparison, a PEDOT:PSS HTM‐based pp‐PSC is fabricated under the same conditions, and its PCE is found to be 13.9%. A linear hole‐transporting material (HTM) based on 9,9‐dihexyl‐9H‐fluorene and N,N‐di‐p‐methylthiophenylamine (denoted as FMT) is synthesized. The p‐i‐n perovskite solar cells (pp‐PSCs) with the indium‐doped tin oxide (ITO)/FMT/CH3NH3PbI3 (MAPbI3)/PCBM/Al structure shows a high power conversion efficiency (PCE) of 19.06%. Hence, FMT is one of the simplest HTMs applied in pp‐PSCs, which shows a PCE of over 19% without dopants.
doi_str_mv 10.1002/adfm.201900484
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A HTM based on 9,9‐dihexyl‐9H‐fluorene and N,N‐di‐p‐methylthiophenylamine (denoted as FMT) is designed and synthesized. High‐yield FMT with a linear structure is synthesized in two steps. The dopant‐free FMT‐based planar p‐i‐n perovskite solar cells (pp‐PSCs) exhibit a high power conversion efficiency (PCE) of 19.06%, which is among the highest PCEs reported for the pp‐PSCs based on organic HTM. For comparison, a PEDOT:PSS HTM‐based pp‐PSC is fabricated under the same conditions, and its PCE is found to be 13.9%. A linear hole‐transporting material (HTM) based on 9,9‐dihexyl‐9H‐fluorene and N,N‐di‐p‐methylthiophenylamine (denoted as FMT) is synthesized. The p‐i‐n perovskite solar cells (pp‐PSCs) with the indium‐doped tin oxide (ITO)/FMT/CH3NH3PbI3 (MAPbI3)/PCBM/Al structure shows a high power conversion efficiency (PCE) of 19.06%. 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subjects Efficiency
Energy conversion efficiency
hole‐transporting material
linear structure
Materials science
Perovskites
Photovoltaic cells
planar p‐i‐n perovskite solar cells
Solar cells
Synthesis
Transportation
title High Efficiency Planar p‐i‐n Perovskite Solar Cells Using Low‐Cost Fluorene‐Based Hole Transporting Material
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