Highly active organosilane-based N-heterocyclic carbene-palladium complex immobilized on silica particles for the Suzuki reaction

1-Methyl-3-(3-trimethoxysilylpropyl)imidazolium chloride, [TMSPIM][Cl ], was synthesized as a precursor of -heterocyclic carbene (NHC), which can be coordinated with palladium to give an organosilane-based bidentic NHC-Pd complex. The organosilane-based NHC-Pd complex was immobilized covalently on s...

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Veröffentlicht in:	Pure and applied chemistry 2007-09, Vol.79 (9), p.1553-1559
Hauptverfasser:	Lee, Sang-Myung, Yoon, Hyo-Jin, Kim, Jong-Ho, Chung, Woo-Jae, Lee, Yoon-Sik
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Atomic beam spectroscopy Catalysis Catalytic activity Chemical reactions Derivatives Field emission microscopy Fourier transforms Inductively coupled plasma Microscopes Microscopy N-heterocyclic carbene organosilane Palladium Reaction time Scanning electron microscopy silica Silicon dioxide Spectrum analysis Suzuki reaction Transmission electron microscopy
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