A series of tetranuclear [2 × 2] grid complexes derived from an asymmetric ligand: Structural differences based on metal ion affinities

A series of tetranuclear grid-type complexes were prepared by the reaction of the asymmetric multidentate ligand HL (HL = 2-[3-(2-hydroxyphenyl)-1 -pyrazol-5-yl]-6-pyridine carboxylic acid ethylester) with different metal sources. The tetranuclear copper complex, [Cu (L1) (NO (H O) ]·Et O·2MeOH ( ,...

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Veröffentlicht in:	Pure and applied chemistry 2011-08, Vol.83 (9), p.1721-1729
Hauptverfasser:	Shiga, Takuya, Noguchi, Mao, Matsumoto, Takuto, Sato, Hiroki, Tahira, Hirotaka, Newton, Graham N., Oshio, Hiroki
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric multidentate ligands cobalt Cobalt compounds Coordination compounds Copper Copper compounds grid Ligands magnetism Metal ions Molecular structure Nickel self-assembly Temperature dependence Water chemistry
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