Stereocontrolled construction of conformationally constrained and rigid bis(a-amino acid) derivatives

Cystine is regarded as a four-atom bridged bis(α-amino acid). The bridge between the two glycine moieties in cystine has been replaced with all-carbon C4-bridges between the α-carbon of the glycines. The products are dicarba analogs of cystine. Conformational constraints have been conferred on these...

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Veröffentlicht in:	Pure and applied chemistry 2003-01, Vol.75 (2), p.279-292
Hauptverfasser:	Undheim, K., Efskind, Jon, Hoven, G. B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylidene Amino acids Analogs Carbon Chemical reactions Cystine Derivatives Glycine Insertion Metathesis Ring structures
Online-Zugang:	Volltext
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