Oxidation reactions in the synthesis of fine and intermediate chemicals using environmentally benign oxidants and the right reactor system
This review outlines several approaches for designing new and environmentally friendly heterogeneously catalyzed oxidation processes for the synthesis of fine and intermediate chemicals. Environmentally benign oxidants such as molecular oxygen, hydrogen peroxide or nitrous oxide can be activated on...
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| Veröffentlicht in: | Pure and applied chemistry 2000-01, Vol.72 (7), p.1273-1287 |
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| container_end_page | 1287 |
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| container_issue | 7 |
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| container_title | Pure and applied chemistry |
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| creator | Hoelderich, Wolfgang F. Kollmer, Felix |
| description | This review outlines several approaches for designing new and environmentally friendly heterogeneously catalyzed oxidation processes for the synthesis of fine and intermediate chemicals. Environmentally benign oxidants such as molecular oxygen, hydrogen peroxide or nitrous oxide can be activated on suitable heterogeneous catalysts showing high activity and selectivity toward the desired oxygenated products. Several examples illustrate that features known from the synthesis of bulk chemicals can successfully be applied for manufacturing intermediate and specialty chemicals applying conventional industrial reactor systems. Direct oxidation of isoprenol, b-picoline, and benzene are chosen as examples for continuous gas-phase processes, oxidation of pinene and propylene as examples for semi-continuous or batchwise processes in the liquid phase. |
| doi_str_mv | 10.1351/pac200072071273 |
| format | Article |
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Direct oxidation of isoprenol, b-picoline, and benzene are chosen as examples for continuous gas-phase processes, oxidation of pinene and propylene as examples for semi-continuous or batchwise processes in the liquid phase.</description><subject>Benzene</subject><subject>Chemical industry</subject><subject>Chemical synthesis</subject><subject>Hydrogen peroxide</subject><subject>Liquid phases</subject><subject>Nitrous oxide</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Oxidizing agents</subject><subject>Oxygen</subject><subject>Propylene</subject><subject>Selectivity</subject><issn>0033-4545</issn><issn>1365-3075</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLAzEUhYMoWB9rtwHXY_OOsxFEfIHgRtdDmty0kU6mJqnav-CvNnUEQXB1L9xzvnM5CJ1Qcka5pNOVsYwQohnRlGm-gyaUK9lwouUumhDCeSOkkPvoIOeXKhStYBP0-fgRnClhiDiBsdsl4xBxWQDOm1hHDhkPHvsQAZvo6rFA6sEFUwDbBfTBmmXG6xziHEN8C2mIPcRilssNnkEM84iHbUgs-RuwRacwX5QxcUg1KBfoj9CeryQ4_pmH6Pnm-unqrnl4vL2_unxobP2_NL5tmZLWUUVnQKhWhGullXNewXnrLTVSkXMQnnrpvNRCUcm8YLMZA2d9yw_R6chdpeF1Dbl0L8M6xRrZMcYJUYIwUVXTUWXTkHMC361S6E3adJR028K7P4VXx8XoeDfLWpGDeVpv6vKL_8ep2Qj4Aq0wim4</recordid><startdate>20000101</startdate><enddate>20000101</enddate><creator>Hoelderich, Wolfgang F.</creator><creator>Kollmer, Felix</creator><general>De Gruyter</general><general>Walter de Gruyter GmbH</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope></search><sort><creationdate>20000101</creationdate><title>Oxidation reactions in the synthesis of fine and intermediate chemicals using environmentally benign oxidants and the right reactor system</title><author>Hoelderich, Wolfgang F. ; Kollmer, Felix</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c454t-f99265cd161be0176037676ddf6e89fc1a5608e4f1f5df5746152f42bb2edcf93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Benzene</topic><topic>Chemical industry</topic><topic>Chemical synthesis</topic><topic>Hydrogen peroxide</topic><topic>Liquid phases</topic><topic>Nitrous oxide</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Oxidizing agents</topic><topic>Oxygen</topic><topic>Propylene</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hoelderich, Wolfgang F.</creatorcontrib><creatorcontrib>Kollmer, Felix</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Pure and applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hoelderich, Wolfgang F.</au><au>Kollmer, Felix</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidation reactions in the synthesis of fine and intermediate chemicals using environmentally benign oxidants and the right reactor system</atitle><jtitle>Pure and applied chemistry</jtitle><date>2000-01-01</date><risdate>2000</risdate><volume>72</volume><issue>7</issue><spage>1273</spage><epage>1287</epage><pages>1273-1287</pages><issn>0033-4545</issn><eissn>1365-3075</eissn><abstract>This review outlines several approaches for designing new and environmentally friendly heterogeneously catalyzed oxidation processes for the synthesis of fine and intermediate chemicals. 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| fulltext | fulltext |
| identifier | ISSN: 0033-4545 |
| ispartof | Pure and applied chemistry, 2000-01, Vol.72 (7), p.1273-1287 |
| issn | 0033-4545 1365-3075 |
| language | eng |
| recordid | cdi_proquest_journals_2230064024 |
| source | EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | Benzene Chemical industry Chemical synthesis Hydrogen peroxide Liquid phases Nitrous oxide Organic chemistry Oxidation Oxidizing agents Oxygen Propylene Selectivity |
| title | Oxidation reactions in the synthesis of fine and intermediate chemicals using environmentally benign oxidants and the right reactor system |
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