Influence of native oxide film age on the passivation of carbon steel in neutral aqueous solutions with a dicarboxylic acid
•Increasing exposure in air produced more hydroxylated native oxide films on steel.•The passive film became increasingly more protective with age of native oxide film.•The passive films consist of a inner Fe(II)-rich layer and an outer FeOOH layer.•A kinetic model was reasonably optimized on the exp...
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| Veröffentlicht in: | Corrosion science 2019-06, Vol.153, p.19-31 |
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| creator | Chan-Rosado, G. Pech-Canul, M.A. |
| description | •Increasing exposure in air produced more hydroxylated native oxide films on steel.•The passive film became increasingly more protective with age of native oxide film.•The passive films consist of a inner Fe(II)-rich layer and an outer FeOOH layer.•A kinetic model was reasonably optimized on the experimental impedance spectra.
Electrochemical impedance spectroscopy (EIS), open circuit potential (Eoc) measurements and angle-resolved X-ray photoelectron spectroscopy (AR-XPS) were used to investigate the effect of exposure in air on the passivation of carbon steel electrodes in a neutral aerated glutarate solution. The electrochemical measurements showed that for native oxide films aged between 4 h and 120 h the passive films became increasingly more protective. Analysis of the XPS revealed a bilayer structure of the passive film (inner Fe(II)-rich, outer Fe oxyhydroxide), with increasing values of the Fe(III)/Fe(II) intensity ratio, and gave evidence that passivation was favored by progressively hydroxylated native oxide films. |
| doi_str_mv | 10.1016/j.corsci.2019.03.033 |
| format | Article |
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Electrochemical impedance spectroscopy (EIS), open circuit potential (Eoc) measurements and angle-resolved X-ray photoelectron spectroscopy (AR-XPS) were used to investigate the effect of exposure in air on the passivation of carbon steel electrodes in a neutral aerated glutarate solution. The electrochemical measurements showed that for native oxide films aged between 4 h and 120 h the passive films became increasingly more protective. Analysis of the XPS revealed a bilayer structure of the passive film (inner Fe(II)-rich, outer Fe oxyhydroxide), with increasing values of the Fe(III)/Fe(II) intensity ratio, and gave evidence that passivation was favored by progressively hydroxylated native oxide films.</description><identifier>ISSN: 0010-938X</identifier><identifier>EISSN: 1879-0496</identifier><identifier>DOI: 10.1016/j.corsci.2019.03.033</identifier><language>eng</language><publisher>Amsterdam: Elsevier Ltd</publisher><subject>A. Carbon steel ; Aeration ; Aqueous solutions ; B. EIS ; B. XPS ; C. Kinetic parameters ; C. Neutral inhibition ; Carbon steel ; Carbon steels ; Electrochemical impedance spectroscopy ; Open circuit voltage ; Oxide coatings ; Passivity ; Photoelectrons ; Protective coatings ; Spectrum analysis ; X ray photoelectron spectroscopy</subject><ispartof>Corrosion science, 2019-06, Vol.153, p.19-31</ispartof><rights>2019 Elsevier Ltd</rights><rights>Copyright Elsevier BV Jun 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-81f0eeb253265a7844b201cb728e5dbff4af5e2940e4480458d2c134074f9b053</citedby><cites>FETCH-LOGICAL-c334t-81f0eeb253265a7844b201cb728e5dbff4af5e2940e4480458d2c134074f9b053</cites><orcidid>0000-0003-0212-3453</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0010938X18318237$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Chan-Rosado, G.</creatorcontrib><creatorcontrib>Pech-Canul, M.A.</creatorcontrib><title>Influence of native oxide film age on the passivation of carbon steel in neutral aqueous solutions with a dicarboxylic acid</title><title>Corrosion science</title><description>•Increasing exposure in air produced more hydroxylated native oxide films on steel.•The passive film became increasingly more protective with age of native oxide film.•The passive films consist of a inner Fe(II)-rich layer and an outer FeOOH layer.•A kinetic model was reasonably optimized on the experimental impedance spectra.
Electrochemical impedance spectroscopy (EIS), open circuit potential (Eoc) measurements and angle-resolved X-ray photoelectron spectroscopy (AR-XPS) were used to investigate the effect of exposure in air on the passivation of carbon steel electrodes in a neutral aerated glutarate solution. The electrochemical measurements showed that for native oxide films aged between 4 h and 120 h the passive films became increasingly more protective. Analysis of the XPS revealed a bilayer structure of the passive film (inner Fe(II)-rich, outer Fe oxyhydroxide), with increasing values of the Fe(III)/Fe(II) intensity ratio, and gave evidence that passivation was favored by progressively hydroxylated native oxide films.</description><subject>A. Carbon steel</subject><subject>Aeration</subject><subject>Aqueous solutions</subject><subject>B. EIS</subject><subject>B. XPS</subject><subject>C. Kinetic parameters</subject><subject>C. Neutral inhibition</subject><subject>Carbon steel</subject><subject>Carbon steels</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Open circuit voltage</subject><subject>Oxide coatings</subject><subject>Passivity</subject><subject>Photoelectrons</subject><subject>Protective coatings</subject><subject>Spectrum analysis</subject><subject>X ray photoelectron spectroscopy</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEQx4MoWB_fwEPA89bJY9vsRRDxBYIXBW8hm53YlHW3JrvV4pd3aj0LAzMDv_88_oydCZgKELOL5dT3Kfs4lSCqKSgKtccmwsyrAnQ122cTAAFFpczrITvKeQkAxMKEfT90oR2x88j7wDs3xDVVX7FBHmL7zt0btR0fFshXLue4JoJ6Yr1LNVV5QGx57HiH45Bcy93HiP2Yee7bcctm_hmHBXe8ib-Sr00bPXc-NifsILg24-lfPmYvtzfP1_fF49Pdw_XVY-GV0kNhRADEWpZKzko3N1rXdLuv59Jg2dQhaBdKlJUG1NqALk0jvVAa5jpUNZTqmJ3v5q5ST8flwS77MXW00kopK2MqEhGld5RPfc4Jg12l-O7SxgqwW5vt0u5stlubLSgKRbLLnQzpg3XEZInY-tnEhH6wTR__H_ADD2OJVA</recordid><startdate>201906</startdate><enddate>201906</enddate><creator>Chan-Rosado, G.</creator><creator>Pech-Canul, M.A.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-0212-3453</orcidid></search><sort><creationdate>201906</creationdate><title>Influence of native oxide film age on the passivation of carbon steel in neutral aqueous solutions with a dicarboxylic acid</title><author>Chan-Rosado, G. ; Pech-Canul, M.A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-81f0eeb253265a7844b201cb728e5dbff4af5e2940e4480458d2c134074f9b053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>A. Carbon steel</topic><topic>Aeration</topic><topic>Aqueous solutions</topic><topic>B. EIS</topic><topic>B. XPS</topic><topic>C. Kinetic parameters</topic><topic>C. Neutral inhibition</topic><topic>Carbon steel</topic><topic>Carbon steels</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Open circuit voltage</topic><topic>Oxide coatings</topic><topic>Passivity</topic><topic>Photoelectrons</topic><topic>Protective coatings</topic><topic>Spectrum analysis</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chan-Rosado, G.</creatorcontrib><creatorcontrib>Pech-Canul, M.A.</creatorcontrib><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chan-Rosado, G.</au><au>Pech-Canul, M.A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of native oxide film age on the passivation of carbon steel in neutral aqueous solutions with a dicarboxylic acid</atitle><jtitle>Corrosion science</jtitle><date>2019-06</date><risdate>2019</risdate><volume>153</volume><spage>19</spage><epage>31</epage><pages>19-31</pages><issn>0010-938X</issn><eissn>1879-0496</eissn><abstract>•Increasing exposure in air produced more hydroxylated native oxide films on steel.•The passive film became increasingly more protective with age of native oxide film.•The passive films consist of a inner Fe(II)-rich layer and an outer FeOOH layer.•A kinetic model was reasonably optimized on the experimental impedance spectra.
Electrochemical impedance spectroscopy (EIS), open circuit potential (Eoc) measurements and angle-resolved X-ray photoelectron spectroscopy (AR-XPS) were used to investigate the effect of exposure in air on the passivation of carbon steel electrodes in a neutral aerated glutarate solution. The electrochemical measurements showed that for native oxide films aged between 4 h and 120 h the passive films became increasingly more protective. Analysis of the XPS revealed a bilayer structure of the passive film (inner Fe(II)-rich, outer Fe oxyhydroxide), with increasing values of the Fe(III)/Fe(II) intensity ratio, and gave evidence that passivation was favored by progressively hydroxylated native oxide films.</abstract><cop>Amsterdam</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.corsci.2019.03.033</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-0212-3453</orcidid></addata></record> |
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| ispartof | Corrosion science, 2019-06, Vol.153, p.19-31 |
| issn | 0010-938X 1879-0496 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | A. Carbon steel Aeration Aqueous solutions B. EIS B. XPS C. Kinetic parameters C. Neutral inhibition Carbon steel Carbon steels Electrochemical impedance spectroscopy Open circuit voltage Oxide coatings Passivity Photoelectrons Protective coatings Spectrum analysis X ray photoelectron spectroscopy |
| title | Influence of native oxide film age on the passivation of carbon steel in neutral aqueous solutions with a dicarboxylic acid |
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