Selective oxidation of cyclohexane to cyclohexanol by BiOI under visible light: Role of the ratio (1 1 0)/(0 0 1) facet

[Display omitted] •BiOI photocatalysts were synthesized at different pH values and characterized.•Cyclohexane oxofunctionalization was performed under visible light.•All BiOI samples showed higher selectivity for cyclohexanol than cyclohexanone.•Cyclohexanol yield was related to the exposed crystal...

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Veröffentlicht in:	Applied catalysis. B, Environmental Environmental, 2019-08, Vol.251, p.17-24
Hauptverfasser:	Contreras, David, Melin, Victoria, Márquez, Katherine, Pérez-González, Gabriel, Mansilla, Héctor D., Pecchi, Gina, Henríquez, Adolfo
Format:	Artikel
Sprache:	eng
Schlagworte:	BiOX Bismuth Bismuth oxyiodide Catalytic activity Cyclohexane Cyclohexanol Dependence Diffuse reflectance spectroscopy Electronics industry Exposure Facet Free radicals Hydroxyl radicals Levels Light Oxidation Oxofunctionalization Parameter modification Photocatalysis Photocatalyst Photocatalysts Scanning electron microscopy Selectivity Spectroscopy X-ray diffraction
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