Thermodynamic Properties of Cobalt Tri- and Tetrafluorides and Their Negative Ions

The literature data on equilibrium with the participation of cobalt fluorides and their negative ions are analyzed. Enthalpies of formation −∆ f H °(0 K) are determined (kJ/mol): CoF 3 , 568.9 ± 8; , 972.4 ± 10; CoF 4 , 639.4 ± 12; , 1228.0 ± 17.

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2019-02, Vol.93 (2), p.185-191
Hauptverfasser: Osina, E. L., Chilingarov, N. S., Osin, S. B., Skokan, E. V., Nikitin, M. I.
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creator Osina, E. L.
Chilingarov, N. S.
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description The literature data on equilibrium with the participation of cobalt fluorides and their negative ions are analyzed. Enthalpies of formation −∆ f H °(0 K) are determined (kJ/mol): CoF 3 , 568.9 ± 8; , 972.4 ± 10; CoF 4 , 639.4 ± 12; , 1228.0 ± 17.
doi_str_mv 10.1134/S0036024419020195
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subjects Chemical Thermodynamics and Thermochemistry
Chemistry
Chemistry and Materials Science
Cobalt
Enthalpy
Fluorides
Negative ions
Physical Chemistry
Thermodynamic properties
title Thermodynamic Properties of Cobalt Tri- and Tetrafluorides and Their Negative Ions
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