Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review
Ways of synthesizing dichloro-[2,2]-paracyclophane (dichloroPCP), a valuable monomer for the manufacturing of polymeric coating used in radioelectronics, are described. There are currently no plants for its production in Russia. Analysis of the considered methods of synthesis show the Hofmann elimin...
Gespeichert in:
Veröffentlicht in: | Catalysis in industry 2019, Vol.11 (1), p.34-44 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 44 |
---|---|
container_issue | 1 |
container_start_page | 34 |
container_title | Catalysis in industry |
container_volume | 11 |
creator | Gogin, L. L. Yushchenko, D. Yu Konev, V. N. Sergeev, E. E. Zhizhina, E. G. Khlebnikova, T. B. Pai, Z. P. |
description | Ways of synthesizing dichloro-[2,2]-paracyclophane (dichloroPCP), a valuable monomer for the manufacturing of polymeric coating used in radioelectronics, are described. There are currently no plants for its production in Russia. Analysis of the considered methods of synthesis show the Hofmann elimination of quaternary ammonium salts is the best technique for the industrial production of dichloroPCP. A promising way of conducting the four-stage synthesis of this product in practice is to use such catalytic technologies as catalysis with alkalis and Lewis acids. |
doi_str_mv | 10.1134/S2070050419010057 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2226818479</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2226818479</sourcerecordid><originalsourceid>FETCH-LOGICAL-c305t-6abadcd7ef7d58901c4cdf394794160e9a7d0b946d58639507e558746745e3603</originalsourceid><addsrcrecordid>eNp1UE1Lw0AQXUTBUvsDvAW8Gp3d7EdWvJRaP6CgWMWDSNhuNk1KzNbdVIm_3i0RPYhzmcfMe2-Gh9AhhhOME3o6JyAAGFAsAQcgdtBgO4qBMbb7g4Huo5H3KwhFpJQiHaDzJ9X5yBbRvGva0vjqs2qW0UWly9o6Gz-TY_IS3ymndKdruy5VY86icXRv3ivzcYD2ClV7M_ruQ_R4OX2YXMez26ubyXgW6wRYG3O1ULnOhSlEztLwoqY6LxJJhaSYg5FK5LCQlIctTyQDYRhLBeWCMpNwSIboqPddO_u2Mb7NVnbjmnAyI4TwFKfBKrBwz9LOeu9Mka1d9apcl2HItjllf3IKGtJrfOA2S-N-nf8XfQHfOmZj</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2226818479</pqid></control><display><type>article</type><title>Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review</title><source>Springer Online Journals Complete</source><creator>Gogin, L. L. ; Yushchenko, D. Yu ; Konev, V. N. ; Sergeev, E. E. ; Zhizhina, E. G. ; Khlebnikova, T. B. ; Pai, Z. P.</creator><creatorcontrib>Gogin, L. L. ; Yushchenko, D. Yu ; Konev, V. N. ; Sergeev, E. E. ; Zhizhina, E. G. ; Khlebnikova, T. B. ; Pai, Z. P.</creatorcontrib><description>Ways of synthesizing dichloro-[2,2]-paracyclophane (dichloroPCP), a valuable monomer for the manufacturing of polymeric coating used in radioelectronics, are described. There are currently no plants for its production in Russia. Analysis of the considered methods of synthesis show the Hofmann elimination of quaternary ammonium salts is the best technique for the industrial production of dichloroPCP. A promising way of conducting the four-stage synthesis of this product in practice is to use such catalytic technologies as catalysis with alkalis and Lewis acids.</description><identifier>ISSN: 2070-0504</identifier><identifier>EISSN: 2070-0555</identifier><identifier>DOI: 10.1134/S2070050419010057</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Alkalies ; Catalysis ; Catalysis in Chemical and Petrochemical Industry ; Chemistry ; Chemistry and Materials Science ; Polymer coatings ; Quaternary ammonium salts</subject><ispartof>Catalysis in industry, 2019, Vol.11 (1), p.34-44</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c305t-6abadcd7ef7d58901c4cdf394794160e9a7d0b946d58639507e558746745e3603</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S2070050419010057$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S2070050419010057$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Gogin, L. L.</creatorcontrib><creatorcontrib>Yushchenko, D. Yu</creatorcontrib><creatorcontrib>Konev, V. N.</creatorcontrib><creatorcontrib>Sergeev, E. E.</creatorcontrib><creatorcontrib>Zhizhina, E. G.</creatorcontrib><creatorcontrib>Khlebnikova, T. B.</creatorcontrib><creatorcontrib>Pai, Z. P.</creatorcontrib><title>Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review</title><title>Catalysis in industry</title><addtitle>Catal. Ind</addtitle><description>Ways of synthesizing dichloro-[2,2]-paracyclophane (dichloroPCP), a valuable monomer for the manufacturing of polymeric coating used in radioelectronics, are described. There are currently no plants for its production in Russia. Analysis of the considered methods of synthesis show the Hofmann elimination of quaternary ammonium salts is the best technique for the industrial production of dichloroPCP. A promising way of conducting the four-stage synthesis of this product in practice is to use such catalytic technologies as catalysis with alkalis and Lewis acids.</description><subject>Alkalies</subject><subject>Catalysis</subject><subject>Catalysis in Chemical and Petrochemical Industry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Polymer coatings</subject><subject>Quaternary ammonium salts</subject><issn>2070-0504</issn><issn>2070-0555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1UE1Lw0AQXUTBUvsDvAW8Gp3d7EdWvJRaP6CgWMWDSNhuNk1KzNbdVIm_3i0RPYhzmcfMe2-Gh9AhhhOME3o6JyAAGFAsAQcgdtBgO4qBMbb7g4Huo5H3KwhFpJQiHaDzJ9X5yBbRvGva0vjqs2qW0UWly9o6Gz-TY_IS3ymndKdruy5VY86icXRv3ivzcYD2ClV7M_ruQ_R4OX2YXMez26ubyXgW6wRYG3O1ULnOhSlEztLwoqY6LxJJhaSYg5FK5LCQlIctTyQDYRhLBeWCMpNwSIboqPddO_u2Mb7NVnbjmnAyI4TwFKfBKrBwz9LOeu9Mka1d9apcl2HItjllf3IKGtJrfOA2S-N-nf8XfQHfOmZj</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Gogin, L. L.</creator><creator>Yushchenko, D. Yu</creator><creator>Konev, V. N.</creator><creator>Sergeev, E. E.</creator><creator>Zhizhina, E. G.</creator><creator>Khlebnikova, T. B.</creator><creator>Pai, Z. P.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2019</creationdate><title>Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review</title><author>Gogin, L. L. ; Yushchenko, D. Yu ; Konev, V. N. ; Sergeev, E. E. ; Zhizhina, E. G. ; Khlebnikova, T. B. ; Pai, Z. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c305t-6abadcd7ef7d58901c4cdf394794160e9a7d0b946d58639507e558746745e3603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alkalies</topic><topic>Catalysis</topic><topic>Catalysis in Chemical and Petrochemical Industry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Polymer coatings</topic><topic>Quaternary ammonium salts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gogin, L. L.</creatorcontrib><creatorcontrib>Yushchenko, D. Yu</creatorcontrib><creatorcontrib>Konev, V. N.</creatorcontrib><creatorcontrib>Sergeev, E. E.</creatorcontrib><creatorcontrib>Zhizhina, E. G.</creatorcontrib><creatorcontrib>Khlebnikova, T. B.</creatorcontrib><creatorcontrib>Pai, Z. P.</creatorcontrib><collection>CrossRef</collection><jtitle>Catalysis in industry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gogin, L. L.</au><au>Yushchenko, D. Yu</au><au>Konev, V. N.</au><au>Sergeev, E. E.</au><au>Zhizhina, E. G.</au><au>Khlebnikova, T. B.</au><au>Pai, Z. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review</atitle><jtitle>Catalysis in industry</jtitle><stitle>Catal. Ind</stitle><date>2019</date><risdate>2019</risdate><volume>11</volume><issue>1</issue><spage>34</spage><epage>44</epage><pages>34-44</pages><issn>2070-0504</issn><eissn>2070-0555</eissn><abstract>Ways of synthesizing dichloro-[2,2]-paracyclophane (dichloroPCP), a valuable monomer for the manufacturing of polymeric coating used in radioelectronics, are described. There are currently no plants for its production in Russia. Analysis of the considered methods of synthesis show the Hofmann elimination of quaternary ammonium salts is the best technique for the industrial production of dichloroPCP. A promising way of conducting the four-stage synthesis of this product in practice is to use such catalytic technologies as catalysis with alkalis and Lewis acids.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S2070050419010057</doi><tpages>11</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 2070-0504 |
ispartof | Catalysis in industry, 2019, Vol.11 (1), p.34-44 |
issn | 2070-0504 2070-0555 |
language | eng |
recordid | cdi_proquest_journals_2226818479 |
source | Springer Online Journals Complete |
subjects | Alkalies Catalysis Catalysis in Chemical and Petrochemical Industry Chemistry Chemistry and Materials Science Polymer coatings Quaternary ammonium salts |
title | Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-04T23%3A03%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ways%20of%20Synthesizing%20Dichloro-%5B2,2%5D-Paracyclophane:%20A%20Review&rft.jtitle=Catalysis%20in%20industry&rft.au=Gogin,%20L.%20L.&rft.date=2019&rft.volume=11&rft.issue=1&rft.spage=34&rft.epage=44&rft.pages=34-44&rft.issn=2070-0504&rft.eissn=2070-0555&rft_id=info:doi/10.1134/S2070050419010057&rft_dat=%3Cproquest_cross%3E2226818479%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2226818479&rft_id=info:pmid/&rfr_iscdi=true |