Effects of the shapes of BaTiO3 nanofillers on PEO-based electrolytes for all-solid-state lithium-ion batteries
BaTiO 3 nanofillers can improve the electrochemical properties of PEO-based solid polymer electrolytes (SPEs). Therefore, we aimed to elucidate the effects of different shapes of BaTiO 3 nanofillers on PEO-based SPEs. Five weight percent of BaTiO 3 nanowires, nanocubes, and nanospheres were added in...
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| Veröffentlicht in: | Ionics 2019-04, Vol.25 (4), p.1471-1480 |
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| creator | Zhang, Yi Wang, Xiaohui Feng, Wei Zhen, Yichao Zhao, Peiyao Cai, Ziming Li, Longtu |
| description | BaTiO
3
nanofillers can improve the electrochemical properties of PEO-based solid polymer electrolytes (SPEs). Therefore, we aimed to elucidate the effects of different shapes of BaTiO
3
nanofillers on PEO-based SPEs. Five weight percent of BaTiO
3
nanowires, nanocubes, and nanospheres were added into SPEs and membranes were prepared by solution casting method. Different BaTiO
3
nanofillers have different effects on the ionic conductivity and the electrochemical stable window of SPEs. For the SPE with BaTiO
3
nanospheres, it possesses the highest ionic conductivity of 1.8 × 10
−5
S cm
−1
at 25 °C and 1.6 × 10
−3
S cm
−1
at 80 °C. The LiFePO
4
/SPE with BaTiO
3
nanospheres/Li exhibits the highest initial discharge-specific capacity of 135.6 mAh g
−1
at 0.1 C rate and the discharge-specific capacity remains 97.5% after 50 cycles at 80 °C. This work demonstrates that BaTiO
3
nanospheres are ideal nanofillers for SPEs, due to the highest specific surface area. |
| doi_str_mv | 10.1007/s11581-018-2706-0 |
| format | Article |
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3
nanofillers can improve the electrochemical properties of PEO-based solid polymer electrolytes (SPEs). Therefore, we aimed to elucidate the effects of different shapes of BaTiO
3
nanofillers on PEO-based SPEs. Five weight percent of BaTiO
3
nanowires, nanocubes, and nanospheres were added into SPEs and membranes were prepared by solution casting method. Different BaTiO
3
nanofillers have different effects on the ionic conductivity and the electrochemical stable window of SPEs. For the SPE with BaTiO
3
nanospheres, it possesses the highest ionic conductivity of 1.8 × 10
−5
S cm
−1
at 25 °C and 1.6 × 10
−3
S cm
−1
at 80 °C. The LiFePO
4
/SPE with BaTiO
3
nanospheres/Li exhibits the highest initial discharge-specific capacity of 135.6 mAh g
−1
at 0.1 C rate and the discharge-specific capacity remains 97.5% after 50 cycles at 80 °C. This work demonstrates that BaTiO
3
nanospheres are ideal nanofillers for SPEs, due to the highest specific surface area.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-018-2706-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Barium titanates ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Discharge ; Electrochemical analysis ; Electrochemistry ; Electrolytes ; Energy Storage ; Ion currents ; Lithium ; Lithium-ion batteries ; Molten salt electrolytes ; Nanospheres ; Nanowires ; Optical and Electronic Materials ; Original Paper ; Rechargeable batteries ; Renewable and Green Energy ; Solid electrolytes</subject><ispartof>Ionics, 2019-04, Vol.25 (4), p.1471-1480</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-1c918f139a933598136eece1fbf55c81ac9592b548b60f5015b3d06fbd56d8363</citedby><cites>FETCH-LOGICAL-c316t-1c918f139a933598136eece1fbf55c81ac9592b548b60f5015b3d06fbd56d8363</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-018-2706-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-018-2706-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Zhang, Yi</creatorcontrib><creatorcontrib>Wang, Xiaohui</creatorcontrib><creatorcontrib>Feng, Wei</creatorcontrib><creatorcontrib>Zhen, Yichao</creatorcontrib><creatorcontrib>Zhao, Peiyao</creatorcontrib><creatorcontrib>Cai, Ziming</creatorcontrib><creatorcontrib>Li, Longtu</creatorcontrib><title>Effects of the shapes of BaTiO3 nanofillers on PEO-based electrolytes for all-solid-state lithium-ion batteries</title><title>Ionics</title><addtitle>Ionics</addtitle><description>BaTiO
3
nanofillers can improve the electrochemical properties of PEO-based solid polymer electrolytes (SPEs). Therefore, we aimed to elucidate the effects of different shapes of BaTiO
3
nanofillers on PEO-based SPEs. Five weight percent of BaTiO
3
nanowires, nanocubes, and nanospheres were added into SPEs and membranes were prepared by solution casting method. Different BaTiO
3
nanofillers have different effects on the ionic conductivity and the electrochemical stable window of SPEs. For the SPE with BaTiO
3
nanospheres, it possesses the highest ionic conductivity of 1.8 × 10
−5
S cm
−1
at 25 °C and 1.6 × 10
−3
S cm
−1
at 80 °C. The LiFePO
4
/SPE with BaTiO
3
nanospheres/Li exhibits the highest initial discharge-specific capacity of 135.6 mAh g
−1
at 0.1 C rate and the discharge-specific capacity remains 97.5% after 50 cycles at 80 °C. This work demonstrates that BaTiO
3
nanospheres are ideal nanofillers for SPEs, due to the highest specific surface area.</description><subject>Barium titanates</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Discharge</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Ion currents</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Molten salt electrolytes</subject><subject>Nanospheres</subject><subject>Nanowires</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Rechargeable batteries</subject><subject>Renewable and Green Energy</subject><subject>Solid electrolytes</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWKs_wNuC5-hM0mR3j1rqBxTqoZ5DdjexW9JNTdJD_72pK3jyNMzwPO_AS8gtwj0ClA8RUVRIASvKSpAUzsgEK8kolBLOyQTqWUlLmJWX5CrGLYCUyMoJ8QtrTZti4W2RNqaIG703P9uTXvcrXgx68LZ3zoR8HYr3xYo2OpquMC57wbtjyrz1odDO0ehd39GYdDKF69OmP-xon7VGp2RCb-I1ubDaRXPzO6fk43mxnr_S5erlbf64pC1HmSi2NVYWea1rzkVdIZfGtAZtY4VoK9RtLWrWiFnVSLACUDS8A2mbTsiu4pJPyd2Yuw_-62BiUlt_CEN-qRhjnEHJZJ0pHKk2-BiDsWof-p0OR4WgTr2qsVeVe1WnXhVkh41OzOzwacJf8v_SN4HYers</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>Zhang, Yi</creator><creator>Wang, Xiaohui</creator><creator>Feng, Wei</creator><creator>Zhen, Yichao</creator><creator>Zhao, Peiyao</creator><creator>Cai, Ziming</creator><creator>Li, Longtu</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190401</creationdate><title>Effects of the shapes of BaTiO3 nanofillers on PEO-based electrolytes for all-solid-state lithium-ion batteries</title><author>Zhang, Yi ; Wang, Xiaohui ; Feng, Wei ; Zhen, Yichao ; Zhao, Peiyao ; Cai, Ziming ; Li, Longtu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-1c918f139a933598136eece1fbf55c81ac9592b548b60f5015b3d06fbd56d8363</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Barium titanates</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Discharge</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Energy Storage</topic><topic>Ion currents</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Molten salt electrolytes</topic><topic>Nanospheres</topic><topic>Nanowires</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Rechargeable batteries</topic><topic>Renewable and Green Energy</topic><topic>Solid electrolytes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yi</creatorcontrib><creatorcontrib>Wang, Xiaohui</creatorcontrib><creatorcontrib>Feng, Wei</creatorcontrib><creatorcontrib>Zhen, Yichao</creatorcontrib><creatorcontrib>Zhao, Peiyao</creatorcontrib><creatorcontrib>Cai, Ziming</creatorcontrib><creatorcontrib>Li, Longtu</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yi</au><au>Wang, Xiaohui</au><au>Feng, Wei</au><au>Zhen, Yichao</au><au>Zhao, Peiyao</au><au>Cai, Ziming</au><au>Li, Longtu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of the shapes of BaTiO3 nanofillers on PEO-based electrolytes for all-solid-state lithium-ion batteries</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2019-04-01</date><risdate>2019</risdate><volume>25</volume><issue>4</issue><spage>1471</spage><epage>1480</epage><pages>1471-1480</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>BaTiO
3
nanofillers can improve the electrochemical properties of PEO-based solid polymer electrolytes (SPEs). Therefore, we aimed to elucidate the effects of different shapes of BaTiO
3
nanofillers on PEO-based SPEs. Five weight percent of BaTiO
3
nanowires, nanocubes, and nanospheres were added into SPEs and membranes were prepared by solution casting method. Different BaTiO
3
nanofillers have different effects on the ionic conductivity and the electrochemical stable window of SPEs. For the SPE with BaTiO
3
nanospheres, it possesses the highest ionic conductivity of 1.8 × 10
−5
S cm
−1
at 25 °C and 1.6 × 10
−3
S cm
−1
at 80 °C. The LiFePO
4
/SPE with BaTiO
3
nanospheres/Li exhibits the highest initial discharge-specific capacity of 135.6 mAh g
−1
at 0.1 C rate and the discharge-specific capacity remains 97.5% after 50 cycles at 80 °C. This work demonstrates that BaTiO
3
nanospheres are ideal nanofillers for SPEs, due to the highest specific surface area.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-018-2706-0</doi><tpages>10</tpages></addata></record> |
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| subjects | Barium titanates Chemistry Chemistry and Materials Science Condensed Matter Physics Discharge Electrochemical analysis Electrochemistry Electrolytes Energy Storage Ion currents Lithium Lithium-ion batteries Molten salt electrolytes Nanospheres Nanowires Optical and Electronic Materials Original Paper Rechargeable batteries Renewable and Green Energy Solid electrolytes |
| title | Effects of the shapes of BaTiO3 nanofillers on PEO-based electrolytes for all-solid-state lithium-ion batteries |
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