Correlation between Refractive Index Dispersion Parameters and Cation Coordination Numbers in Fluoride Crystals
— Refractive index dispersion parameters of optical crystals of MF n (M n + = Na + , K + , Ca 2+ , Sr 2+ , Ba 2+ , Cd 2+ , Pb 2+ , La 3+ , Ce 3+ , Pr 3+ , Nd 3+ ) binary fluorides have been shown to correlate with the cation coordination numbers in their structures. Using this correlation, I have de...
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| Veröffentlicht in: | Inorganic materials 2019, Vol.55 (1), p.77-80 |
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| container_title | Inorganic materials |
| container_volume | 55 |
| creator | Sorokin, N. I. |
| description | —
Refractive index dispersion parameters of optical crystals of MF
n
(M
n
+
= Na
+
, K
+
, Ca
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Pb
2+
, La
3+
, Ce
3+
, Pr
3+
, Nd
3+
) binary fluorides have been shown to correlate with the cation coordination numbers in their structures. Using this correlation, I have demonstrated that, with increasing LaF
3
concentration, the cation coordination number in Sr
1 −
x
La
x
F
2 +
x
ternary fluoride crystals (fluorite structure) increases from 8 to 11. |
| doi_str_mv | 10.1134/S0020168519010163 |
| format | Article |
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Refractive index dispersion parameters of optical crystals of MF
n
(M
n
+
= Na
+
, K
+
, Ca
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Pb
2+
, La
3+
, Ce
3+
, Pr
3+
, Nd
3+
) binary fluorides have been shown to correlate with the cation coordination numbers in their structures. Using this correlation, I have demonstrated that, with increasing LaF
3
concentration, the cation coordination number in Sr
1 −
x
La
x
F
2 +
x
ternary fluoride crystals (fluorite structure) increases from 8 to 11.</description><identifier>ISSN: 0020-1685</identifier><identifier>EISSN: 1608-3172</identifier><identifier>DOI: 10.1134/S0020168519010163</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Calcium ions ; Cations ; Cerium ; Chemistry ; Chemistry and Materials Science ; Coordination numbers ; Correlation ; Crystal structure ; Dispersion ; Fluorides ; Fluorite ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Lanthanum fluorides ; Lead ; Materials Science ; Parameters ; Refractivity</subject><ispartof>Inorganic materials, 2019, Vol.55 (1), p.77-80</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-55e57356c69d95d2a85dea7625af9d75ed2b8e4b5ca7d510b71dc549a99b5b573</citedby><cites>FETCH-LOGICAL-c419t-55e57356c69d95d2a85dea7625af9d75ed2b8e4b5ca7d510b71dc549a99b5b573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0020168519010163$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0020168519010163$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Sorokin, N. I.</creatorcontrib><title>Correlation between Refractive Index Dispersion Parameters and Cation Coordination Numbers in Fluoride Crystals</title><title>Inorganic materials</title><addtitle>Inorg Mater</addtitle><description>—
Refractive index dispersion parameters of optical crystals of MF
n
(M
n
+
= Na
+
, K
+
, Ca
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Pb
2+
, La
3+
, Ce
3+
, Pr
3+
, Nd
3+
) binary fluorides have been shown to correlate with the cation coordination numbers in their structures. Using this correlation, I have demonstrated that, with increasing LaF
3
concentration, the cation coordination number in Sr
1 −
x
La
x
F
2 +
x
ternary fluoride crystals (fluorite structure) increases from 8 to 11.</description><subject>Calcium ions</subject><subject>Cations</subject><subject>Cerium</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination numbers</subject><subject>Correlation</subject><subject>Crystal structure</subject><subject>Dispersion</subject><subject>Fluorides</subject><subject>Fluorite</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Lanthanum fluorides</subject><subject>Lead</subject><subject>Materials Science</subject><subject>Parameters</subject><subject>Refractivity</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kM1LxDAQxYMouK7-Ad4CnquZtGmbo9SvhUXFj3NJmql02U3WpFX3vzelggfxNPN47_cGhpBTYOcAaXbxzBhnkJcCJIO4pHtkBjkrkxQKvk9mo52M_iE5CmHFGMtEKWfEVc57XKu-c5Zq7D8RLX3C1qum7z6QLqzBL3rVhS36MGYelVcb7KOiyhpaTWTlnDedncT9sNGj31l6sx6c7wzSyu9Cr9bhmBy0ceDJz5yT15vrl-ouWT7cLqrLZdJkIPtECBRFKvIml0YKw1UpDKoi50K10hQCDdclZlo0qjACmC7ANCKTSkotdETn5Gzq3Xr3PmDo65UbvI0na845SA6MpzEFU6rxLgSPbb313Ub5XQ2sHv9a__lrZPjEhJi1b-h_m_-HvgE5DXse</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Sorokin, N. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2019</creationdate><title>Correlation between Refractive Index Dispersion Parameters and Cation Coordination Numbers in Fluoride Crystals</title><author>Sorokin, N. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-55e57356c69d95d2a85dea7625af9d75ed2b8e4b5ca7d510b71dc549a99b5b573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Calcium ions</topic><topic>Cations</topic><topic>Cerium</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination numbers</topic><topic>Correlation</topic><topic>Crystal structure</topic><topic>Dispersion</topic><topic>Fluorides</topic><topic>Fluorite</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Lanthanum fluorides</topic><topic>Lead</topic><topic>Materials Science</topic><topic>Parameters</topic><topic>Refractivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sorokin, N. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sorokin, N. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Correlation between Refractive Index Dispersion Parameters and Cation Coordination Numbers in Fluoride Crystals</atitle><jtitle>Inorganic materials</jtitle><stitle>Inorg Mater</stitle><date>2019</date><risdate>2019</risdate><volume>55</volume><issue>1</issue><spage>77</spage><epage>80</epage><pages>77-80</pages><issn>0020-1685</issn><eissn>1608-3172</eissn><abstract>—
Refractive index dispersion parameters of optical crystals of MF
n
(M
n
+
= Na
+
, K
+
, Ca
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Pb
2+
, La
3+
, Ce
3+
, Pr
3+
, Nd
3+
) binary fluorides have been shown to correlate with the cation coordination numbers in their structures. Using this correlation, I have demonstrated that, with increasing LaF
3
concentration, the cation coordination number in Sr
1 −
x
La
x
F
2 +
x
ternary fluoride crystals (fluorite structure) increases from 8 to 11.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0020168519010163</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
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| issn | 0020-1685 1608-3172 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Calcium ions Cations Cerium Chemistry Chemistry and Materials Science Coordination numbers Correlation Crystal structure Dispersion Fluorides Fluorite Industrial Chemistry/Chemical Engineering Inorganic Chemistry Lanthanum fluorides Lead Materials Science Parameters Refractivity |
| title | Correlation between Refractive Index Dispersion Parameters and Cation Coordination Numbers in Fluoride Crystals |
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