Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges
A novel one-dimensional polymeric Cu(I) halide complex with iodine bridges between copper atoms and 2-phenylquinoline as an N-donor ligand is prepared. The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be des...
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Veröffentlicht in: | Journal of structural chemistry 2019-03, Vol.60 (3), p.472-476 |
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description | A novel one-dimensional polymeric Cu(I) halide complex with iodine bridges between copper atoms and 2-phenylquinoline as an N-donor ligand is prepared. The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be described as distorted trigonal planar. The I-Cu-I, Cu-I-Cu, and N-Cu-I angles are 115.90(2)°, 116.37(2)°, and 124.80(8)°, respectively. The Cu-I distances range from 2.563(6) Å to 2.569(6) Å, and the Cu-N bond is 2.016(2) Å, being in good agreement with that in the related structures. |
doi_str_mv | 10.1134/S0022476619030168 |
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The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be described as distorted trigonal planar. The I-Cu-I, Cu-I-Cu, and N-Cu-I angles are 115.90(2)°, 116.37(2)°, and 124.80(8)°, respectively. The Cu-I distances range from 2.563(6) Å to 2.569(6) Å, and the Cu-N bond is 2.016(2) Å, being in good agreement with that in the related structures.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476619030168</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Angles (geometry) ; Atomic ; Atomic/Molecular Structure and Spectra ; Bridges ; Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Copper ; Crystallography ; Infrared spectroscopy ; Inorganic Chemistry ; Iodine ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2019-03, Vol.60 (3), p.472-476</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-adee4a5a8e1ec48493c0bc92ee3d41b79a3e74774457f139415fcf6f47f285c63</citedby><cites>FETCH-LOGICAL-c316t-adee4a5a8e1ec48493c0bc92ee3d41b79a3e74774457f139415fcf6f47f285c63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476619030168$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476619030168$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Aguirrechu-Comerón, A.</creatorcontrib><creatorcontrib>Hernández-Molina, R.</creatorcontrib><creatorcontrib>González-Platas, J.</creatorcontrib><title>Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>A novel one-dimensional polymeric Cu(I) halide complex with iodine bridges between copper atoms and 2-phenylquinoline as an N-donor ligand is prepared. The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be described as distorted trigonal planar. The I-Cu-I, Cu-I-Cu, and N-Cu-I angles are 115.90(2)°, 116.37(2)°, and 124.80(8)°, respectively. The Cu-I distances range from 2.563(6) Å to 2.569(6) Å, and the Cu-N bond is 2.016(2) Å, being in good agreement with that in the related structures.</description><subject>Angles (geometry)</subject><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Bridges</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Crystallography</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Iodine</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLw0AUhQdRsFZ_gLsBN7qIzivzWGrro1CoUF2H6eROTWkzcSZB-u9NqOBCXN3F-b7D5SB0ScktpVzcLQlhTCgpqSGcUKmP0IjmimdaKXOMRkOcDfkpOktpQwgx2sgRmi7b2Lm2i4CDxxYvasim1Q7qVIXabvEkNA3E69kNfg3b_Q4i_qraDzwLZVUDfohVuYZ0jk683Sa4-Llj9P70-DZ5yeaL59nkfp45TmWb2RJA2NxqoOCEFoY7snKGAfBS0JUyloMSSgmRK0-5ETT3zksvlGc6d5KP0dWht4nhs4PUFpvQxf7NVDDGiCbM5Lyn6IFyMaQUwRdNrHY27gtKimGs4s9YvcMOTurZeg3xt_l_6Ru5G2nd</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Aguirrechu-Comerón, A.</creator><creator>Hernández-Molina, R.</creator><creator>González-Platas, J.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190301</creationdate><title>Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges</title><author>Aguirrechu-Comerón, A. ; Hernández-Molina, R. ; González-Platas, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-adee4a5a8e1ec48493c0bc92ee3d41b79a3e74774457f139415fcf6f47f285c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Angles (geometry)</topic><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Bridges</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Crystallography</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Iodine</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aguirrechu-Comerón, A.</creatorcontrib><creatorcontrib>Hernández-Molina, R.</creatorcontrib><creatorcontrib>González-Platas, J.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aguirrechu-Comerón, A.</au><au>Hernández-Molina, R.</au><au>González-Platas, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2019-03-01</date><risdate>2019</risdate><volume>60</volume><issue>3</issue><spage>472</spage><epage>476</epage><pages>472-476</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>A novel one-dimensional polymeric Cu(I) halide complex with iodine bridges between copper atoms and 2-phenylquinoline as an N-donor ligand is prepared. The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be described as distorted trigonal planar. The I-Cu-I, Cu-I-Cu, and N-Cu-I angles are 115.90(2)°, 116.37(2)°, and 124.80(8)°, respectively. The Cu-I distances range from 2.563(6) Å to 2.569(6) Å, and the Cu-N bond is 2.016(2) Å, being in good agreement with that in the related structures.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476619030168</doi><tpages>5</tpages></addata></record> |
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subjects | Angles (geometry) Atomic Atomic/Molecular Structure and Spectra Bridges Chemistry Chemistry and Materials Science Coordination compounds Copper Crystallography Infrared spectroscopy Inorganic Chemistry Iodine Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics |
title | Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges |
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