Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges

A novel one-dimensional polymeric Cu(I) halide complex with iodine bridges between copper atoms and 2-phenylquinoline as an N-donor ligand is prepared. The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be des...

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Veröffentlicht in:Journal of structural chemistry 2019-03, Vol.60 (3), p.472-476
Hauptverfasser: Aguirrechu-Comerón, A., Hernández-Molina, R., González-Platas, J.
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Hernández-Molina, R.
González-Platas, J.
description A novel one-dimensional polymeric Cu(I) halide complex with iodine bridges between copper atoms and 2-phenylquinoline as an N-donor ligand is prepared. The complex is characterized by elemental analyses, IR spectroscopy, and crystallographic studies.The coordination geometry around copper may be described as distorted trigonal planar. The I-Cu-I, Cu-I-Cu, and N-Cu-I angles are 115.90(2)°, 116.37(2)°, and 124.80(8)°, respectively. The Cu-I distances range from 2.563(6) Å to 2.569(6) Å, and the Cu-N bond is 2.016(2) Å, being in good agreement with that in the related structures.
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subjects Angles (geometry)
Atomic
Atomic/Molecular Structure and Spectra
Bridges
Chemistry
Chemistry and Materials Science
Coordination compounds
Copper
Crystallography
Infrared spectroscopy
Inorganic Chemistry
Iodine
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
title Structure of a One-Dimensional Copper(I) Polymer with Iodine Bridges
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